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Smokeless Powder
Finnish smokeless powderSmokeless powder is a type of propellant used in firearms and artillery that produces less smoke and less fouling when fired compared to gunpowder ("black powder"). The combustion products are mainly gaseous, compared to around 55% solid products (mostly potassium carbonate, potassium sulfate, and potassium sulfide) for black powder. In addition, smokeless powder does not leave the thick, heavy fouling of hygroscopic material associated with black powder that causes rusting of the barrel. Despite its name, smokeless powder is not completely free of smoke; while there may be little noticeable smoke from small-arms ammunition, smoke from artillery fire can be substantial. Originally invented in 1884 by Paul Vieille, the most common formulations are based on nitrocellulose, but the term was also used to describe various picrate mixtures with nitrate, chlorate, or dichromate oxidizers during the late 19th century, before the advantages of nitrocellulose beca ...
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N110 Ruuti
N11 or N-11 may refer to: Roads * N11 (South Africa) * N11 highway, Philippines * N11 motorway (Netherlands) * N11 road (Ghana) * N11 road (Ireland) * Nebraska Highway 11, United States * Route nationale 11, France Other uses * N11 (emission nebula) * , a submarine of the Royal Navy * Intel i860 XP, a microprocessor * Interstitial nephritis * LNER Class N11, a British steam locomotive * London Buses route N11 * N11 code, special telephone numbers in the North American Numbering Plan * Next eleven, a group of emerging economies proposed by Goldman Sachs * Nieuport 11, a French World War I fighter * Nissan Pulsar (N11), a Japanese car * Nitrogen-11, an isotope of nitrogen * North Springs station, a MARTA station in Sandy Springs, Georgia * N11, a postcode district in the N postcode area N, or n, is the fourteenth letter in the Latin alphabet, used in the modern English alphabet, the alphabets of other western European languages and others worldwide. Its name in English is ' ...
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Chlorate
The chlorate anion has the formula ClO3-. In this case, the chlorine atom is in the +5 oxidation state. "Chlorate" can also refer to chemical compounds containing this anion; chlorates are the salts of chloric acid. "Chlorate", when followed by a Roman numeral in parentheses, e.g. chlorate (VII), refers to a particular oxyanion of chlorine. As predicted by valence shell electron pair repulsion theory, chlorate anions have trigonal pyramidal structures. Chlorates are powerful oxidizers and should be kept away from organics or easily oxidized materials. Mixtures of chlorate salts with virtually any combustible material (sugar, sawdust, charcoal, organic solvents, metals, etc.) will readily deflagrate. Chlorates were once widely used in pyrotechnics for this reason, though their use has fallen due to their instability. Most pyrotechnic applications that formerly used chlorates now use the more stable perchlorates instead. Structure and bonding The chlorate ion cannot be satisf ...
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Christian Friedrich Schönbein
Christian Friedrich Schönbein H FRSE(18 October 1799 – 29 August 1868) was a German-Swiss chemist who is best known for inventing the fuel cell (1838) at the same time as William Robert Grove and his discoveries of guncotton and ozone. Life Schönbein (Schoenbein) related to Michael Schoenbein was born at Metzingen in the Duchy of Württemberg. Around the age of 13 he was apprenticed to a chemical and pharmaceutical firm at Böblingen. Through his own efforts, he acquired sufficient scientific skills and knowledge to ask for, and receive, an examination by the professor of chemistry at Tübingen. Schönbein passed the exam and, after a series of moves and university studies, eventually acquired a position at the University of Basel in 1828, becoming a full professor in 1835. He remained there until his death in 1868, and was buried in Basel. Fuel cell In 1839, Schönbein published the principle of the fuel cell in the "Philosophical Magazine". Ozone It was wh ...
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Guncotton
Nitrocellulose (also known as cellulose nitrate, flash paper, flash cotton, guncotton, pyroxylin and flash string, depending on form) is a highly flammable compound formed by nitrating cellulose through exposure to a mixture of nitric acid and sulfuric acid. One of its first major uses was as guncotton, a replacement for gunpowder as propellant in firearms. It was also used to replace gunpowder as a low-order explosive in mining and other applications. In the form of collodion it was also a critical component in an early photographic emulsion, the use of which revolutionized photography in the 1860s. Production The process uses a mixture of nitric acid and sulfuric acid to convert cellulose into nitrocellulose. The quality of the cellulose is important. Hemicellulose, lignin, pentosans, and mineral salts give inferior nitrocelluloses. In precise chemical terms, nitrocellulose is not a nitro compound, but a nitrate ester. The glucose repeat unit (anhydroglucose) within the ce ...
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Ascanio Sobrero
Ascanio Sobrero (12 October 1812 – 26 May 1888) was an Italian chemist, born in Casale Monferrato. He was studying under Théophile-Jules Pelouze at the University of Turin, who had worked with the explosive material guncotton. He studied medicine in Turin and Paris and then chemistry at the University of Gießen with Justus Liebig, and earned his doctorate in 1832. In 1845 he became professor at the University of Turin During his research he discovered, in 1847, nitroglycerine. He initially called it "pyroglycerine", and warned vigorously against its use in his private letters and in a journal article, stating that it was extremely dangerous and impossible to handle. In fact, he was so frightened by what he created that he kept it a secret for over a year. Another of Pelouze's students was the young Alfred Nobel, who returned to the Nobel family's defunct armaments factory and began experimenting with the material around 1860; it did, indeed prove to be very difficult to ...
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Chemist
A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a scientist trained in the study of chemistry. Chemists study the composition of matter and its properties. Chemists carefully describe the properties they study in terms of quantities, with detail on the level of molecules and their component atoms. Chemists carefully measure substance proportions, chemical reaction rates, and other chemical properties. In Commonwealth English, pharmacists are often called chemists. Chemists use their knowledge to learn the composition and properties of unfamiliar substances, as well as to reproduce and synthesize large quantities of useful naturally occurring substances and create new artificial substances and useful processes. Chemists may specialize in any number of subdisciplines of chemistry. Materials scientists and metallurgists share much of the same education and skills with chemists. The work of chemists is often related to the ...
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Nitroglycerine
Nitroglycerin (NG), (alternative spelling of nitroglycerine) also known as trinitroglycerin (TNG), nitro, glyceryl trinitrate (GTN), or 1,2,3-trinitroxypropane, is a dense, colorless, oily, explosive liquid most commonly produced by nitrating glycerol with white fuming nitric acid under conditions appropriate to the formation of the nitric acid ester. Chemically, the substance is an organic nitrate compound rather than a nitro compound, but the traditional name is retained. Invented in 1847 by Ascanio Sobrero, nitroglycerin has been used ever since as an active ingredient in the manufacture of explosives, namely dynamite, and as such it is employed in the construction, demolition, and mining industries. Since the 1880s, it has been used by militaries as an active ingredient and gelatinizer for nitrocellulose in some solid propellants such as cordite and ballistite. It is a major component in double-based smokeless propellants used by reloaders. Combined with nitrocellulo ...
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Sniper
A sniper is a military/paramilitary marksman who engages targets from positions of concealment or at distances exceeding the target's detection capabilities. Snipers generally have specialized training and are equipped with high-precision rifles and high-magnification optics, and often also serve as scouts/observers feeding tactical information back to their units or command headquarters. In addition to long-range and high-grade marksmanship, military snipers are trained in a variety of special operation techniques: detection, stalking, target range estimation methods, camouflage, tracking, bushcraft, field craft, infiltration, special reconnaissance and observation, surveillance and target acquisition. Etymology The name "sniper" comes from the verb "to snipe", which originated in the 1770s among soldiers in British India in reference to shooting snipes, a wader that was considered an extremely challenging game bird for hunters due to its alertness, camouflaging color ...
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Napoleonic Wars
The Napoleonic Wars (1803–1815) were a series of major global conflicts pitting the French Empire and its allies, led by Napoleon I, against a fluctuating array of European states formed into various coalitions. It produced a period of French domination over most of continental Europe. The wars stemmed from the unresolved disputes associated with the French Revolution and the French Revolutionary Wars consisting of the War of the First Coalition (1792–1797) and the War of the Second Coalition (1798–1802). The Napoleonic Wars are often described as five conflicts, each termed after the coalition that fought Napoleon: the Third Coalition (1803–1806), the Fourth (1806–1807), the Fifth (1809), the Sixth (1813–1814), and the Seventh (1815) plus the Peninsular War (1807–1814) and the French invasion of Russia (1812). Napoleon, upon ascending to First Consul of France in 1799, had inherited a republic in chaos; he subsequently created a state with stable financ ...
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Detonation
Detonation () is a type of combustion involving a supersonic exothermic front accelerating through a medium that eventually drives a shock front propagating directly in front of it. Detonations propagate supersonically through shock waves with speeds in the range of 1 km/sec and differ from deflagrations which have subsonic flame speeds in the range of 1 m/sec. Detonations occur in both conventional solid and liquid explosives, as well as in reactive gases. The velocity of detonation in solid and liquid explosives is much higher than that in gaseous ones, which allows the wave system to be observed with greater detail (higher resolution). A very wide variety of fuels may occur as gases (e.g. hydrogen), droplet fogs, or dust suspensions. In addition to dioxygen, oxidants can include halogen compounds, ozone, hydrogen peroxide and oxides of nitrogen. Gaseous detonations are often associated with a mixture of fuel and oxidant in a composition somewhat below conventional flammabil ...
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Deflagration
Deflagration (Lat: ''de + flagrare'', "to burn down") is subsonic combustion in which a pre-mixed flame propagates through a mixture of fuel and oxidizer. Deflagrations can only occur in pre-mixed fuels. Most fires found in daily life are diffusion flames. Deflagrations with flame speeds in the range of 1 m/sec differ from detonations which propagate supersonically through shock waves with speeds in the range of 1 km/sec. Applications Deflagrations are often used in engineering applications when the goal is to move an object such as a bullet in a firearm, or a piston in an internal combustion engine with the force of the expanding gas. Deflagration systems and products can also be used in mining, demolition and stone quarrying via gas pressure blasting as a beneficial alternative to high explosives. Flame physics The underlying flame physics can be understood with the help of an idealized model consisting of a uniform one-dimensional tube of unburnt and burned gaseous fuel, sep ...
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Propellant
A propellant (or propellent) is a mass that is expelled or expanded in such a way as to create a thrust or other motive force in accordance with Newton's third law of motion, and "propel" a vehicle, projectile, or fluid payload. In vehicles, the engine that expels the propellant is called a reaction engine. Although technically a propellant is the reaction mass used to create thrust, the term "propellant" is often used to describe a substance which is contains both the reaction mass and the fuel that holds the energy used to accelerate the reaction mass. For example, the term "propellant" is often used in chemical rocket design to describe a combined fuel/propellant, although the propellants should not be confused with the fuel that is used by an engine to produce the energy that expels the propellant. Even though the byproducts of substances used as fuel are also often used as a reaction mass to create the thrust, such as with a chemical rocket engine, propellant and fuel are two ...
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