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Siegenite
Siegenite (also called grimmite, or nickel cobalt sulfide) is a ternary transition metal dichalcogenide compound with the chemical formula (Ni,Co)3S4. It has been actively studied as a promising material system for electrodes in electrochemical energy applications due to its better conductivity, greater mechanical and thermal stability, and higher performance compared to metal oxides currently in use. Potential applications of this material system include supercapacitors, batteries, electrocatalysis, dye-sensitized solar cells, photocatalysis, glucose sensors, and microwave absorption. In synthetic chemistry, a range of chemical compositions with the formula NixCo3-xS4 (0 < x < 3) are often referred to as the siegenite system. However, according to the new IMA list of minerals (updated November 2022), the normal spinel NiCo2S ...
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Sulfide Mineral
The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the arsenides, the antimonides, the bismuthinides, the sulfarsenides and the sulfosalts.http://www.minerals.net/mineral/sort-met.hod/group/sulfgrp.htm Minerals.net Dana Classification, SulfidesKlein, Cornelis and Cornelius S. Hurlbut, Jr., 1986, ''Manual of Mineralogy'', Wiley, 20th ed., pp 269-293 Sulfide minerals are inorganic compounds. Minerals Common or important examples include: * Acanthite *Chalcocite *Bornite * Galena * Sphalerite *Chalcopyrite *Pyrrhotite *Millerite *Pentlandite *Covellite *Cinnabar *Realgar *Orpiment *Stibnite *Pyrite *Marcasite *Molybdenite Sulfarsenides: *Cobaltite *Arsenopyrite *Gersdorffite Sulfosalts: *Pyrargyrite *Proustite *Tetrahedrite *Tennantite *Enargite *Bournonite * ...
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Thiospinel Group
The thiospinel group is a group of sulfide minerals with a general formula where A is nominally a +2 metal, B is a +3 metal and X is -2 sulfide or similar anion (selenide or telluride). ''Thio'' refers to sulfur and ''spinel'' indicates their isometric spinel-like structure. As the chalcogens S, Se and Te are less electronegative than oxygen, the bonding in these materials is generally more covalent than in the oxospinels. Some are (magnetic) semiconductors but others display, at times complicated, metallic behavior, often coupled with equally complicated magnetic properties. The assignment of oxidation states is also not always as straightforward as in the more ionic oxocompounds, as is shown in the case of carrollite. Group members include: * Cadmoindite – * Carrollite – * Fletcherite – * Greigite – * Indite – * Kalininite – * Linnaeite – * Polydymite - * Siegenite – * Tyrrellite – * Violarite Violarite ( Fe2+ Ni23+ S4) is a supergene sulfide min ...
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Bosnian Mountains
Bosnian may refer to: *Anything related to the state of Bosnia and Herzegovina or its inhabitants *Anything related to Bosnia (region) or its inhabitants * Bosniaks, an ethnic group mainly inhabiting Bosnia and Herzegovina and one of three constitutive nations of Bosnia and Herzegovina * Bosnians, people who live in, or come from, Bosnia and Herzegovina * Bosnian Croats, an ethnic group and one of three constitutive nations of Bosnia and Herzegovina * Bosnian Serbs, an ethnic group and one of the three constitutive nations of Bosnia and Herzegovina * ''Bošnjani'', the name of inhabitants of Bosnia during the Middle Ages * Bosnian language See also *Bosniaks (other) *Bošnjak (other) * List of Bosnians and Herzegovinians * Languages of Bosnia and Herzegovina * Demographics of Bosnia and Herzegovina This article is about the demographic features of the population of Bosnia and Herzegovina, including population density, ethnicity, education level, health o ...
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Ullmannite
Ullmannite is a nickel antimony sulfide mineral with formula: NiSbS. Considerable substitution occurs with cobalt and iron in the nickel site along with bismuth and arsenic in the antimony site. A solid solution series exists with the high cobalt willyamite. Physical properties Ullmannite is steel-gray to tin white in color with a metallic luster, has a Mohs hardness of 5 to 5.5 and a specific gravity of 6.65. Initially thought to be of two species, tetrahedral and cubic, it was later confirmed that both samples conformed to the 23 point group of the isometric crystal class and typically exhibits cubic, octahedral, or pyritohedral forms although euhedral crystals are rare. Variance in its chemical composition has been shown to be responsible for loss of symmetry and variations in striation patterns. Ullmannite crystals are usually less than 2 mm, however larger have been identified in especially antimony rich environments. Ullmannite commonly displays interpenetration tw ...
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Gersdorffite
Gersdorffite is a nickel arsenic sulfide mineral with formula NiAsS. It crystallizes in the isometric system showing diploidal symmetry. It occurs as euhedral to massive opaque, metallic grey-black to silver white forms. Gersdorffite belongs to a solid solution series with cobaltite, CoAsS. Antimony freely substitutes also leading to ullmannite, NiSbS. It has a Mohs hardness of 5.5 and a specific gravity of 5.9 to 6.33. Gersdorffite has three crystallisation forms: Gersdorffite-P213 (NiAsS), Gersdorffite-Pa3 (Ni(As,S)2) and Gersdorffite-Pca21 (NiAsS).Bayliss P (1982) ''A further crystal structure refinement of gersdorffite'', American Mineralogist 67, 1058-1064 Gersdorffite occurs as a hydrothermal vein mineral along with other nickel sulfides. Associated minerals include nickeline, nickel-skutterudite, cobaltite, ullmannite, maucherite, löllingite, platinum-group minerals, millerite, pyrite, marcasite, and chalcopyrite. Gersdorffite was first described in 1843 and named for Jo ...
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Millerite
Millerite is a nickel sulfide mineral, Ni S. It is brassy in colour and has an acicular habit, often forming radiating masses and furry aggregates. It can be distinguished from pentlandite by crystal habit, its duller colour, and general lack of association with pyrite or pyrrhotite. Paragenesis Millerite is a common metamorphic mineral replacing pentlandite within serpentinite ultramafics. It is formed in this way by removal of sulfur from pentlandite or other nickeliferous sulfide minerals during metamorphism or metasomatism. Millerite is also formed from sulfur poor olivine cumulates by nucleation. Millerite is thought to form from sulfur and nickel which exist in pristine olivine in trace amounts, and which are driven out of the olivine during metamorphic processes. Magmatic olivine generally has up to ~4000 ppm Ni and up to 2500 ppm S within the crystal lattice, as contaminants and substituting for other transition metals with similar ionic radii (Fe2+ an ...
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Pyrite
The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Iron, FeSulfur, S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic Luster (mineralogy), luster and pale brass-yellow hue give it a superficial resemblance to gold, hence the well-known nickname of ''fool's gold''. The color has also led to the nicknames ''brass'', ''brazzle'', and ''Brazil'', primarily used to refer to pyrite found in coal. The name ''pyrite'' is derived from the Greek language, Greek (), 'stone or mineral which strikes fire', in turn from (), 'fire'. In ancient Roman times, this name was applied to several types of stone that would create sparks when struck against steel; Pliny the Elder described one of them as being brassy, almost certainly a reference to what we now call pyrite. By Georgius Agricola's time, , the term had become a generic term for all of the pyrite group, sulfide minerals. Pyrite is usua ...
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Sphalerite
Sphalerite (sometimes spelled sphaelerite) is a sulfide mineral with the chemical formula . It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in Sedimentary exhalative deposits, sedimentary exhalative, Carbonate-hosted lead-zinc ore deposits, Mississippi-Valley type, and Volcanogenic massive sulfide ore deposit, volcanogenic massive sulfide deposits. It is found in association with galena, chalcopyrite, pyrite (and other sulfide mineral, sulfides), calcite, dolomite (mineral), dolomite, quartz, rhodochrosite, and fluorite. German geologist Ernst Friedrich Glocker discovered sphalerite in 1847, naming it based on the Greek word ''sphaleros'', meaning "deceiving", due to the difficulty of identifying the mineral. In addition to zinc, sphalerite is an ore of cadmium, gallium, germanium, and indium. Miners have been known to refer to sphalerite as ''zinc blende'', ''black-jack'', and ''ruby blende''. Marmatite is an opaque ...
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Galena
Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver. Galena is one of the most abundant and widely distributed sulfide minerals. It crystallizes in the cubic crystal system often showing octahedral forms. It is often associated with the minerals sphalerite, calcite and fluorite. Occurrence Galena is the main ore of lead, used since ancient times, since lead can be smelted from galena in an ordinary wood fire. Galena typically is found in hydrothermal veins in association with sphalerite, marcasite, chalcopyrite, cerussite, anglesite, dolomite, calcite, quartz, barite, and fluorite. It is also found in association with sphalerite in low-temperature lead-zinc deposits within limestone beds. Minor amounts are found in contact metamorphic zones, in pegmatites, and disseminated in sedimentary rock. In some deposits the galena contains up to 0.5% silver, a byproduct that ...
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Pyrrhotite
Pyrrhotite is an iron sulfide mineral with the formula Fe(1-x)S (x = 0 to 0.2). It is a nonstoichiometric variant of FeS, the mineral known as troilite. Pyrrhotite is also called magnetic pyrite, because the color is similar to pyrite and it is weakly magnetic. The magnetism decreases as the iron content increases, and troilite is non-magnetic.Vaughan, D. J.; Craig, J. R. "Mineral Chemistry of Metal Sulfides" Cambridge University Press, Cambridge: 1978. . Structure Pyrrhotite exists as a number of polytypes of hexagonal or monoclinic crystal symmetry; several polytypes often occur within the same specimen. Their structure is based on the NiAs unit cell. As such, Fe occupies an octahedral site and the sulfide centers occupy trigonal prismatic sites. Materials with the NiAs structure often are non-stoichiometric because they lack up to 1/8th fraction of the metal ions, creating vacancies. One of such structures is pyrrhotite-4C (Fe7S8). Here "4" indicates that iron vacancies ...
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Chalcopyrite
Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green-tinged black. On exposure to air, chalcopyrite tarnishes to a variety of oxides, hydroxides, and sulfates. Associated copper minerals include the sulfides bornite (Cu5FeS4), chalcocite (Cu2S), covellite (CuS), digenite (Cu9S5); carbonates such as malachite and azurite, and rarely oxides such as cuprite (Cu2O). Is rarely found in association with native copper. Chalcopyrite is a conductor of electricity. Etymology The name chalcopyrite comes from the Greek words , which means copper, and ', which means striking fire. It was sometimes historically referred to as "yellow copper". Identification Chalcopyrite is often confused with pyrite and gold since all three of these minerals have a yell ...
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