Radium Sulfate
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Radium Sulfate
Radium sulfate (or radium sulphate) is an inorganic compound with the formula RaSO4 and an average molecular mass of 322.088 g/mol. This salt is the least soluble of all known sulfate salts. It was formerly used in radiotherapy and smoke detectors, but this has been phased out in favor of less hazardous alternatives. Properties Radium sulfate crystallises in a solid in the same structure as barium sulfate. It forms crystals in the orthorhombic crystal system, with a unit cell of dimensions ''a'' = 9.07 ''b''=5.52 and ''c'' = 7.28 Å. The unit cell volume is 364 Å3. Distance from the radium ion to oxygen is 2.96  Å and the sulfur to oxygen bond length in the sulfate ion is 1.485  Å. In this compound the ionic radius of the radium ion is 1.66 Å, and it is in ten coordination. Radium sulfate can form solid solutions with the sulfates of strontium, barium or lead. References

{{radium compounds Radium compounds Sulfates ...
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Strontium Sulfate
Strontium sulfate (SrSO4) is the sulfuric acid, sulfate salt of strontium. It is a white crystalline powder and occurs in nature as the mineral Celestine (mineral), celestine. It is poorly soluble in water to the extent of 1 part in 8,800. It is more soluble in dilute hydrochloric acid, HCl and nitric acid and appreciably soluble in alkali chloride solutions (e.g. sodium chloride). Structure Strontium sulfate is a polymeric material, isostructural with barium sulfate. Crystallized strontium sulfate is utilized by a small group of radiolarian protozoa, called the Acantharea, as a main constituent of their skeleton. Applications and chemistry Strontium sulfate is of interest as a naturally occurring precursor to other strontium compounds, which are more useful. In industry it is converted to strontium carbonate, the carbonate for use as ceramic precursor and strontium nitrate, the nitrate for use in pyrotechnics. The low aqueous solubility of strontium sulfate can lead to fouling, ...
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Barium Sulfate
Barium sulfate (or sulphate) is the inorganic compound with the chemical formula Ba SO4. It is a white crystalline solid that is odorless and insoluble in water. It occurs as the mineral barite, which is the main commercial source of barium and materials prepared from it. The white opaque appearance and its high density are exploited in its main applications.Holleman, A. F. and Wiberg, E. (2001) ''Inorganic Chemistry'', San Diego, CA : Academic Press, . Uses Drilling fluids About 80% of the world's barium sulfate production, mostly purified mineral, is consumed as a component of oil well drilling fluid. It increases the density of the fluid, increasing the hydrostatic pressure in the well and reducing the chance of a blowout. Radiocontrast agent Barium sulfate in suspension is often used medically as a radiocontrast agent for X-ray imaging and other diagnostic procedures. It is most often used in imaging of the GI tract during what is colloquially known as a "barium meal". ...
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Lead(II) Sulfate
Lead(II) sulfate (PbSO4) is a white solid, which appears white in microcrystalline form. It is also known as ''fast white'', ''milk white'', ''sulfuric acid lead salt'' or ''anglesite''. It is often seen in the plates/electrodes of car batteries, as it is formed when the battery is discharged (when the battery is recharged, then the lead sulfate is transformed back to metallic lead and sulfuric acid on the negative terminal or lead dioxide and sulfuric acid on the positive terminal). Lead sulfate is poorly soluble in water. Manufacturing Lead(II) sulfate is prepared by treating lead oxide, hydroxide or carbonate with warm sulfuric acid or by treating a soluble lead salt with sulfuric acid. Alternatively, it can be made by the interaction of solutions of lead nitrate and sodium sulfate. Toxicology Lead sulfate is toxic by inhalation, ingestion and skin contact. It is a cumulative poison, and repeated exposure may lead to anemia, kidney damage, eyesight damage or damage to the cen ...
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Sulfate
The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many are prepared from that acid. Spelling "Sulfate" is the spelling recommended by IUPAC, but "sulphate" was traditionally used in British English. Structure The sulfate anion consists of a central sulfur atom surrounded by four equivalent oxygen atoms in a tetrahedral arrangement. The symmetry is the same as that of methane. The sulfur atom is in the +6 oxidation state while the four oxygen atoms are each in the −2 state. The sulfate ion carries an overall charge of −2 and it is the conjugate base of the bisulfate (or hydrogensulfate) ion, , which is in turn the conjugate base of , sulfuric acid. Organic sulfate esters, such as dimethyl sulfate, are covalent compounds and esters of sulfuric acid. The tetrahedral molecular geometry of th ...
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Radiotherapy
Radiation therapy or radiotherapy, often abbreviated RT, RTx, or XRT, is a therapy using ionizing radiation, generally provided as part of cancer treatment to control or kill malignant cells and normally delivered by a linear accelerator. Radiation therapy may be curative in a number of types of cancer if they are localized to one area of the body. It may also be used as part of adjuvant therapy, to prevent tumor recurrence after surgery to remove a primary malignant tumor (for example, early stages of breast cancer). Radiation therapy is synergistic with chemotherapy, and has been used before, during, and after chemotherapy in susceptible cancers. The subspecialty of oncology concerned with radiotherapy is called radiation oncology. A physician who practices in this subspecialty is a radiation oncologist. Radiation therapy is commonly applied to the cancerous tumor because of its ability to control cell growth. Ionizing radiation works by damaging the DNA of cancerous tissue l ...
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Smoke Detectors
A smoke detector is a device that senses smoke, typically as an indicator of fire. Smoke detectors are usually housed in plastic enclosures, typically shaped like a disk about in diameter and thick, but shape and size vary. Smoke can be detected either optically (photoelectric) or by physical process (ionization). Detectors may use one or both sensing methods. Sensitive alarms can be used to detect and deter smoking in banned areas. Smoke detectors in large commercial and industrial buildings are usually connected to a central fire alarm system. Household smoke detectors, also known as ''smoke alarms'', generally issue an audible or visual alarm from the detector itself or several detectors if there are multiple devices interlinked. Household smoke detectors range from individual battery-powered units to several interlinked units with battery backup. With interlinked units, if any unit detects smoke, alarms will trigger at all of the units. This happens even if household power h ...
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Orthorhombic
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a rectangular base (''a'' by ''b'') and height (''c''), such that ''a'', ''b'', and ''c'' are distinct. All three bases intersect at 90° angles, so the three lattice vectors remain mutually orthogonal. Bravais lattices There are four orthorhombic Bravais lattices: primitive orthorhombic, base-centered orthorhombic, body-centered orthorhombic, and face-centered orthorhombic. For the base-centered orthorhombic lattice, the primitive cell has the shape of a right rhombic prism;See , row oC, column Primitive, where the cell parameters are given as a1 = a2, α = β = 90° it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. Note that the length a of the primit ...
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Solid Solution
A solid solution, a term popularly used for metals, is a homogenous mixture of two different kinds of atoms in solid state and have a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The word "solution" is used to describe the intimate mixing of components at the atomic level and distinguishes these homogeneous materials from physical mixtures of components. Two terms are mainly associated with solid solutions - ''solvents'' and ''solutes,'' depending on the relative abundance of the atomic species. In general if two compounds are isostructural then a solid solution will exist between the end members (also known as parents). For example sodium chloride and potassium chloride have the same cubic crystal structure so it is possible to make a pure compound with any ratio of sodium to potassium (Na1-xKx)Cl by dissolving that ratio of NaCl and KCl in water and then evaporating the solution. A member of this family is sold under t ...
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Radium Compounds
Radium compounds are compounds containing the element radium (Ra). Due to radium's radioactivity, not many compounds have been well characterized. Solid radium compounds are white as radium ions provide no specific coloring, but they gradually turn yellow and then dark over time due to self-radiolysis from radium's alpha decay.Kirby et al., p. 4 Insoluble radium compounds coprecipitate with all barium, most strontium, and most lead compounds.Kirby et al., p. 8 Oxides and hydroxides Radium oxide (RaO) has not been characterized well past its existence, despite oxides being common compounds for the other alkaline earth metals. Radium hydroxide (Ra(OH)2) is the most readily soluble among the alkaline earth hydroxides and is a stronger base than its barium congener, barium hydroxide.Kirby et al., pp. 4–8 It is also more soluble than actinium hydroxide and thorium hydroxide: these three adjacent hydroxides may be separated by precipitating them with ammonia. Halides Radium fluo ...
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