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Robinetinidin
Robinetinidin is an anthocyanidin, a type of flavonoid. Prorobinetinidins, condensed tannins oligomers containing robinetinidol, can be found in '' Stryphnodendron adstringens''. They yield robinetinidin when depolymerized under oxidative conditions. References See also * Robinetinidol, the corresponding flavan-3ol * Leucorobinetinidin, the corresponding leucoanthocyanidin Leucoanthocyanidin (flavan-3,4-diols) are colorless chemical compounds related to anthocyanidins and anthocyanins. Leucoanthocyanins can be found in '' Anadenanthera peregrina'' and in several species of '' Nepenthes'' including '' N. burbidg ... Anthocyanidins Pyrogallols {{aromatic-stub ...
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Robinetinidol
Robinetinidol is a flavanol, a type of flavonoids. Prorobinetinidins, flavanols oligomers containing robinetinidol, can be found in ''Stryphnodendron adstringens ''Stryphnodendron adstringens'' ( pt, barbatimão) is a species of legume in the genus ''Stryphnodendron'' found in Brazil. ''Holcocera cerradicola'' is a moth, whose larvae feed on ''S. adstringens''. Chemistry ''Stryphnodendron adstringens'' ...''. See also * Robinetinidin, the corresponding anthocyanidin References External links Robinetinidol on metabolomics.jp Flavanols Pyrogallols {{Aromatic-stub ...
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Anthocyanidin
Anthocyanidins are common plant pigments, the sugar-free counterparts of anthocyanins. They are based on the flavylium cation, an oxonium ion, with various groups substituted for its hydrogen atoms. They generally change color from red through purple, blue, and bluish green as a function of pH. Anthocyanidins are an important subclass of the polymethine dyes and flavonoids. The flavylium cation is a chromenylium cation with a phenyl group substituted in position 2; and chromenylium (also called benzopyrylium) is a bicyclic version of pyrylium. The positive charge can move around the molecule. At least 31 monomeric anthocyanidins have been properly identified in living organisms, mostly as the core components of anthocyanins. The latter are responsible for the red, purple, blue, or black color of many fruits (like grapes and blueberries), flowers (like roses), leaves (like purple cabbage), and even tubers (like radishes and purple yams). They are also found in some animals ...
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Prorobinetinidin
Prorobinetidins are a type of condensed tannins formed from robinetinidol. They form robinetinidin when depolymerized under oxidative conditions. ''Mimosa'' and quebracho tannins are, according to a comparative 13C NMR study of polyflavonoids, found to be predominantly profisetinidin/prorobinetidin-type tannins. ''Stryphnodendron adstringens ''Stryphnodendron adstringens'' ( pt, barbatimão) is a species of legume in the genus ''Stryphnodendron'' found in Brazil. ''Holcocera cerradicola'' is a moth, whose larvae feed on ''S. adstringens''. Chemistry ''Stryphnodendron adstringens'' ...'' ( the barbatimão), a species of legume found in Brazil, produces prorobinetinidins in its stem bark. These are robinetinidol-(4β → 8)-epigallocatechin, robinetinidol-(4α → 8)-epigallocatechin, robinetinidol-(4β → 8)-epigallocatechin 3-O-gallate, robinetinidol-(4α → 8)-epigallocatechin 3-O-gallate, robinetinidol-(4α → 6)-gallocatechin and robinetinidol-(4α → 6)-epigall ...
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Stryphnodendron Adstringens
''Stryphnodendron adstringens'' ( pt, barbatimão) is a species of legume in the genus ''Stryphnodendron'' found in Brazil. ''Holcocera cerradicola'' is a moth, whose larvae feed on ''S. adstringens''. Chemistry ''Stryphnodendron adstringens'' stem bark is used to produce tannins of the prorobinetinidins (flavanols oligomers containing robinetinidol) or prodelphinidins type. These are robinetinidol-(4β → 8)-epigallocatechin, robinetinidol-(4α → 8)-epigallocatechin, robinetinidol-(4β → 8)-epigallocatechin 3-O-gallate, robinetinidol-(4α → 8)-epigallocatechin 3-O-gallate, robinetinidol-(4α → 6)-gallocatechin and robinetinidol-(4α → 6)-epigallocatechin, in addition to the tentatively characterized, robinetinidol β → 6(8)gallocatechin and robinetinidol-(4α → 8)-gallocatechin.
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Leucoanthocyanidin
Leucoanthocyanidin (flavan-3,4-diols) are colorless chemical compounds related to anthocyanidins and anthocyanins. Leucoanthocyanins can be found in '' Anadenanthera peregrina'' and in several species of '' Nepenthes'' including '' N. burbidgeae'', '' N. muluensis'', '' N. rajah'', '' N. tentaculata'', and '' N. × alisaputrana''. Such compounds include: * Leucocyanidin * Leucodelphinidin * Leucofisetinidin * Leucomalvidin * Leucopelargonidin * Leucopeonidin * Leucorobinetinidin * Melacacidin * Teracacidin from '' Acacia obtusifolia'' and '' Acacia maidenii'' heartwoods Leucoanthocyanidins have been demonstrated to be intermediates in anthocyanidin biosynthesis in flowers of ''Matthiola incana''. Bate-smith recommended in 1954 the use of the Forestal solvent for the isolation of leuco-anthocyanins. Metabolism Leucoanthocyanidin dioxygenase uses flavan-3,4-diols to produce 3-hydroxyanthocyanidins. The gene encoding the enzyme (PpLDOX) ha ...
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Anthocyanidins
Anthocyanidins are common plant pigments, the sugar-free counterparts of anthocyanins. They are based on the flavylium cation, an oxonium ion, with various groups substituted for its hydrogen atoms. They generally change color from red through purple, blue, and bluish green as a function of pH. Anthocyanidins are an important subclass of the polymethine dyes and flavonoids. The flavylium cation is a chromenylium cation with a phenyl group substituted in position 2; and chromenylium (also called benzopyrylium) is a bicyclic version of pyrylium. The positive charge can move around the molecule. At least 31 monomeric anthocyanidins have been properly identified in living organisms, mostly as the core components of anthocyanins. The latter are responsible for the red, purple, blue, or black color of many fruits (like grapes and blueberries), flowers (like roses), leaves (like purple cabbage), and even tubers (like radishes and purple yams). They are also found in some animals. ...
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