Pterobilin
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Pterobilin
''Graphium sarpedon'' which contains pterobilin Pterobilin is a blue bile pigment found in '' Nessaea'' spp., ''Graphium agamemnon'', '' G. antiphates'', '' G. doson'', and '' G. sarpedon''. It is one of only a few blue pigments found in any animal species, as most animals use iridescence to create blue coloration. Other blue pigments of animal origin include phorcabilin, used by other butterflies in '' Graphium'' and '' Papilio'' (specifically '' P. phorcas'' and '' P. weiskei''), and sarpedobilin, which is used by ''Graphium sarpedon''. Synthetic pathways Pterobilin 1 is a chemical precursor to sarpedobilin 3 in the larvae of the fourth instar of ''G. sarpedon'' through a double cyclisation of the central vinyl groups of the adjacent nitrogens. In the butterfly species ''Pieris brassicae'', it is produced starting with acetate and then proceeding to glycin, then δ-aminolevulinic acid, then coproporphyrinogen III, to protoporphyrin IX and finally into pterobilin. Pterobil ...
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Nessaea
''Nessaea'' is a genus of nymphalid butterflies found in the Neotropical realm. Unlike virtually all other butterflies with blue coloration, the blue colors in this genus are due to pigmentation terobilin (biliverdin IXγ)ref>Doug Taron"It's all in the structure" ''Gossamer Tapestry'', Retrieved January 25, 2017 rather than iridescence (e.g., ''Morpho'' species). Species Accepted species: *'' Nessaea aglaura'' Doubleday 848/small> – common olivewing, northern nessaea or Aglaura olivewing *'' Nessaea ecuadorensis'' Talbot 1932 *'' Nessaea batesii'' C. & R. Felder 1860 – Bates olivewing *'' Nessaea magniplaga'' Röber 1928 *'' Nessaea hewitsonii'' C. & R. Felder 1859 – Hewitson's olivewing *'' Nessaea obrinus'' Linnaeus 1758 – obrina olivewing *'' Nessaea faventia'' Fruhstorfer 1910 *'' Nessaea latifascia'' Röber 1928 *'' Nessaea romani'' Bryk 1953 *'' Nessaea regina'' Salvin 1869 *'' Nessaea thalia'' Bargmann 1928 Unaccepted species: *'' Nessaea margaretha'' ...
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Common Bluebottle Graphium Sarpedon UP By Dr
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Cyclisation
A cyclic compound (or ring compound) is a term for a compound in the field of chemistry in which one or more series of atoms in the compound is connected to form a ring. Rings may vary in size from three to many atoms, and include examples where all the atoms are carbon (i.e., are carbocycles), none of the atoms are carbon (inorganic cyclic compounds), or where both carbon and non-carbon atoms are present (heterocyclic compounds). Depending on the ring size, the bond order of the individual links between ring atoms, and their arrangements within the rings, carbocyclic and heterocyclic compounds may be aromatic or non-aromatic; in the latter case, they may vary from being fully saturated to having varying numbers of multiple bonds between the ring atoms. Because of the tremendous diversity allowed, in combination, by the valences of common atoms and their ability to form rings, the number of possible cyclic structures, even of small size (e.g., < 17 total atoms) numbers in the many b ...
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Wing Scale
Scales are present on the bodies of various insects. A notable example are Lepidoptera, the insect order comprising moths and butterflies, which has scales on their wings and also on the head, parts of the thorax and abdomen as well as parts of the genitalia. The name is derived from Ancient Greek λεπίδος (scale) and πτερόν (wing).Scoble, M.J. (2005). ''The Lepidoptera: Form, Function, and Diversity''. Page 63. Accessed through Google books on 21 Aug 200/ref> The Trichoptera (caddisflies) which are a sister group of the Lepidoptera have scales, but also possess caudal cerci on the abdomen, a feature absent in the Lepidoptera.Powell, Jerry A. Lepidoptera (pp. 631-664) in Resh, V. H. & R. T. Cardé (Editors) 2003. Encyclopedia of Insects. Academic Press. Beetles of family Dermestidae also commonly have scales.Byrd, Jason. Castner, James (2001)Forensic Entomology: The Utility of Arthropods in Legal Investigations/ref> Morphology The morphology of scales has been stu ...
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Heat Transfer
Heat transfer is a discipline of thermal engineering that concerns the generation, use, conversion, and exchange of thermal energy (heat) between physical systems. Heat transfer is classified into various mechanisms, such as thermal conduction, Convection (heat transfer), thermal convection, thermal radiation, and transfer of energy by phase changes. Engineers also consider the transfer of mass of differing chemical species (mass transfer in the form of advection), either cold or hot, to achieve heat transfer. While these mechanisms have distinct characteristics, they often occur simultaneously in the same system. Heat conduction, also called diffusion, is the direct microscopic exchanges of kinetic energy of particles (such as molecules) or quasiparticles (such as lattice waves) through the boundary between two systems. When an object is at a different temperature from another body or its surroundings, heat flows so that the body and the surroundings reach the same temperature, ...
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Diapause
In animal dormancy, diapause is the delay in development in response to regular and recurring periods of adverse environmental conditions.Tauber, M.J., Tauber, C.A., Masaki, S. (1986) ''Seasonal Adaptations of Insects''. Oxford University Press It is a physiological state with very specific initiating and inhibiting conditions. The mechanism is a means of surviving predictable, unfavorable environmental conditions, such as temperature extremes, drought, or reduced food availability. Diapause is observed in all the life stages of arthropods, especially insects. Embryonic diapause, a somewhat similar phenomenon, occurs in over 130 species of mammals, possibly even in humans, and in the embryos of many of the oviparous species of fish in the order Cyprinodontiformes. Activity levels of diapausing stages can vary considerably among species. Diapause may occur in a completely immobile stage, such as the pupae and eggs, or it may occur in very active stages that undergo extensive migrat ...
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Photoreception
A photoreceptor cell is a specialized type of neuroepithelial cell found in the retina that is capable of visual phototransduction. The great biological importance of photoreceptors is that they convert light (visible electromagnetic radiation) into signals that can stimulate biological processes. To be more specific, photoreceptor proteins in the cell absorb photons, triggering a change in the cell's membrane potential. There are currently three known types of photoreceptor cells in mammalian eyes: rods, cones, and intrinsically photosensitive retinal ganglion cells. The two classic photoreceptor cells are rods and cones, each contributing information used by the visual system to form an image of the environment, sight. Rods primarily mediate scotopic vision (dim conditions) whereas cones primarily mediate to photopic vision (bright conditions), but the processes in each that supports phototransduction is similar. A third class of mammalian photoreceptor cell was discovered ...
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Phototransform
A chemical reaction is a process that leads to the chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the positions of electrons in the forming and breaking of chemical bonds between atoms, with no change to the nuclei (no change to the elements present), and can often be described by a chemical equation. Nuclear chemistry is a sub-discipline of chemistry that involves the chemical reactions of unstable and radioactive elements where both electronic and nuclear changes can occur. The substance (or substances) initially involved in a chemical reaction are called reactants or reagents. Chemical reactions are usually characterized by a chemical change, and they yield one or more products, which usually have properties different from the reactants. Reactions often consist of a sequence of individual sub-steps, the so-called elementary reactions, and the information on the precise course of acti ...
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Protoporphyrin IX
Protoporphyrin IX is an organic compound, classified as a porphyrin, that plays an important role in living organisms as a precursor to other critical compounds like heme (hemoglobin) and chlorophyll. It is a deeply colored solid that is not soluble in water. The name is often abbreviated as PPIX. Protoporphyrin IX contains a porphine core, a tetrapyrrole macrocycle with a marked aromatic character. Protoporphyrin IX is essentially planar, except for the N-H bonds that are bent out of the plane of the rings, in opposite (trans) directions. Nomenclature The general term protoporphyrin refers to porphine derivatives that have the outer hydrogen atoms in the four pyrrole rings replaced by other functional groups. The prefix proto often means 'first' in science nomenclature (such as carbon protoxide), hence Hans Fischer is thought to have coined the name protoporphyrin as the first class of porphyrins. Fischer described iron-deprived heme becoming the "proto-" porphyrin, particu ...
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Coproporphyrinogen III
Coproporphyrinogen III is a metabolic intermediate in the biosynthesis of many compounds that are critical for living organisms, such as hemoglobin and chlorophyll. It is a colorless solid. The compound is a porphyrinogen, a class of compounds characterized by a hexahydroporphine core with various side chains. The coproporphyrinogens have the outermost hydrogen atoms of the core replaced by four methyl groups (M) and four propionic acid Propionic acid (, from the Greek words πρῶτος : ''prōtos'', meaning "first", and πίων : ''píōn'', meaning "fat"; also known as propanoic acid) is a naturally occurring carboxylic acid with chemical formula CH3CH2CO2H. It is a liq ... groups (P). In coproporphyrogen III, the order around the outer ring is MP-MP-MP-PM. For comparison, coproporphyrinogen I has them in the sequence MP-MP-MP-MP. heme. Biosynthesis and metabolism In the main Porphyrin#Synthesis, porphyrin biosynthesis pathway, coproporphyrinogen III is derived f ...
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δ-aminolevulinic Acid
δ-Aminolevulinic acid (also dALA, δ-ALA, 5ALA or 5-aminolevulinic acid), an endogenous non-proteinogenic amino acid, is the first compound in the porphyrin synthesis pathway, the pathway that leads to heme in mammals, as well as chlorophyll in plants. 5ALA is used in photodynamic detection and surgery of cancer.Wagnières, G.., Jichlinski, P., Lange, N., Kucera, P., Van den Bergh, H. (2014). Detection of Bladder Cancer by Fluorescence Cystoscopy: From Bench to Bedside - the Hexvix Story. Handbook of Photomedicine, 411-426. Medical uses As a precursor of a photosensitizer, 5ALA is also used as an add-on agent for photodynamic therapy. In contrast to larger photosensitizer molecules, it is predicted by computer simulations to be able to penetrate tumor cell membranes. Cancer diagnosis Photodynamic detection is the use of photosensitive drugs with a light source of the right wavelength for the detection of cancer, using fluorescence of the drug. 5ALA, or derivatives thereof, can ...
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