Proton-exchange Membrane Fuel Cell
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Proton-exchange Membrane Fuel Cell
Proton-exchange membrane fuel cells (PEMFC), also known as proton-exchange membrane, polymer electrolyte membrane (PEM) fuel cells, are a type of fuel cell being developed mainly for transport applications, as well as for stationary fuel-cell applications and Fuel cell#Portable power systems, portable fuel-cell applications. Their distinguishing features include lower temperature/pressure ranges (50 to 100 °C) and a special proton-conducting polymer electrolyte membrane. PEMFCs generate electricity and operate on the opposite principle to PEM electrolysis, which consumes electricity. They are a leading candidate to replace the aging Alkaline fuel cell, alkaline fuel-cell technology, which was used in the Space Shuttle. Science PEMFCs are built out of Membrane electrode assembly, membrane electrode assemblies (MEA) which include the electrodes, electrolyte, catalyst, and gas diffusion layers. An ink of catalyst, carbon, and electrode are sprayed or painted onto the solid ele ...
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Proton Exchange Fuel Cell Diagram
A proton is a stable subatomic particle, symbol , H+, or 1H+ with a positive electric charge of +1 ''e'' elementary charge. Its mass is slightly less than that of a neutron and 1,836 times the mass of an electron (the proton–electron mass ratio). Protons and neutrons, each with masses of approximately one atomic mass unit, are jointly referred to as "nucleons" (particles present in atomic nuclei). One or more protons are present in the Atomic nucleus, nucleus of every atom. They provide the attractive electrostatic central force which binds the atomic electrons. The number of protons in the nucleus is the defining property of an element, and is referred to as the atomic number (represented by the symbol ''Z''). Since each chemical element, element has a unique number of protons, each element has its own unique atomic number, which determines the number of atomic electrons and consequently the chemical characteristics of the element. The word ''proton'' is Greek language, G ...
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Electron
The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no known components or substructure. The electron's mass is approximately 1/1836 that of the proton. Quantum mechanical properties of the electron include an intrinsic angular momentum ( spin) of a half-integer value, expressed in units of the reduced Planck constant, . Being fermions, no two electrons can occupy the same quantum state, in accordance with the Pauli exclusion principle. Like all elementary particles, electrons exhibit properties of both particles and waves: They can collide with other particles and can be diffracted like light. The wave properties of electrons are easier to observe with experiments than those of other particles like neutrons and protons because electrons have a lower mass and hence a longer de Broglie wavele ...
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Water Gas Shift Reaction
Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a solvent). It is vital for all known forms of life, despite not providing food, energy or organic micronutrients. Its chemical formula, H2O, indicates that each of its molecules contains one oxygen and two hydrogen atoms, connected by covalent bonds. The hydrogen atoms are attached to the oxygen atom at an angle of 104.45°. "Water" is also the name of the liquid state of H2O at standard temperature and pressure. A number of natural states of water exist. It forms precipitation in the form of rain and aerosols in the form of fog. Clouds consist of suspended droplets of water and ice, its solid state. When finely divided, crystalline ice may precipitate in the form of snow. The gaseous state of water is steam or water vapor. Water covers a ...
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Electroosmotic Pump
An electroosmotic pump (EOP), or EO pump, is used for generating flow or pressure by use of an electric field. One application of this is removing liquid flooding water from channels and gas diffusion layers and direct hydration of the proton exchange membrane in the membrane electrode assembly (MEA) of the proton exchange membrane fuel cells. Principle Electroosmotic pumps are fabricated from silica nanospheres or hydrophilic porous glass, the pumping mechanism is generated by an external electric field applied on an electric double layer (EDL), generates high pressures (e.g., more than 340 atm (34 MPa) at 12 kV applied potentials) and high flow rates (e.g., 40 ml/min at 100 V in a pumping structure less than 1 cm³ in volume). EO pumps are compact, have no moving parts, and scale favorably with fuel cell design. The EO pump might drop the parasitic load of water management in fuel cells from 20% to 0.5% of the fuel cell power. Types Cascaded electroosmotic pumps Hig ...
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Platinum
Platinum is a chemical element with the symbol Pt and atomic number 78. It is a dense, malleable, ductile, highly unreactive, precious, silverish-white transition metal. Its name originates from Spanish , a diminutive of "silver". Platinum is a member of the platinum group of elements and group 10 of the periodic table of elements. It has six naturally occurring isotopes. It is one of the rarer elements in Earth's crust, with an average abundance of approximately 5  μg/kg. It occurs in some nickel and copper ores along with some native deposits, mostly in South Africa, which accounts for ~80% of the world production. Because of its scarcity in Earth's crust, only a few hundred tonnes are produced annually, and given its important uses, it is highly valuable and is a major precious metal commodity. Platinum is one of the least reactive metals. It has remarkable resistance to corrosion, even at high temperatures, and is therefore considered a noble metal. Consequent ...
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Molecule
A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and ''molecule'' is often used when referring to polyatomic ions. A molecule may be homonuclear, that is, it consists of atoms of one chemical element, e.g. two atoms in the oxygen molecule (O2); or it may be heteronuclear, a chemical compound composed of more than one element, e.g. water (two hydrogen atoms and one oxygen atom; H2O). In the kinetic theory of gases, the term ''molecule'' is often used for any gaseous particle regardless of its composition. This relaxes the requirement that a molecule contains two or more atoms, since the noble gases are individual atoms. Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are typically not consid ...
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Short Circuit
A short circuit (sometimes abbreviated to short or s/c) is an electrical circuit that allows a current to travel along an unintended path with no or very low electrical impedance. This results in an excessive current flowing through the circuit. The opposite of a short circuit is an "open circuit", which is an infinite resistance between two nodes. Definition A short circuit is an abnormal connection between two nodes of an electric circuit intended to be at different voltages. This results in an electric current limited only by the Thévenin equivalent resistance of the rest of the network which can cause circuit damage, overheating, fire or explosion. Although usually the result of a fault, there are cases where short circuits are caused intentionally, for example, for the purpose of voltage-sensing crowbar circuit protectors. In circuit analysis, a ''short circuit'' is defined as a connection between two nodes that forces them to be at the same voltage. In an 'ideal' ...
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MEA Fabrication Methods
MEA or Mea may refer to: Education * Minnesota Education Association * MEA Engineering College, Perinthalmanna * Michigan Education Association Fictional characters * Mea (''Popotan''), a maid for three sisters in the visual novel ''Popotan'' * Mea Kurosaki, a transformation weapon in the manga series ''To Love Ru Darkness'' * Mea 3, a representative of planet Eminiar VII in the ''Star Trek'' episode " A Taste of Armageddon" Organizations * Manx Electricity Authority * ME Association, a British organization providing information and support on ME/CFS * Metropolitan Electricity Authority, responsible for supplying the Bangkok Metropolitan Region * Middle East Airlines, the flag carrier airline of Lebanon * Municipal Employees' Association, former British trade union Politics * Multilateral Environmental Agreement * Ministry of External Affairs (other), several Science * ''Mea'' (moth), a genus of moths * Mean electrical axis, in electrocardiography * Mean ...
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SEM Micrograph Of An MEA Cross Section
SEM can refer to: Computing * Search engine marketing, promoting websites by increasing their visibility in search engine results * Security event manager, a security log tool used on data networks Economics and management * Stock Exchange of Mauritius, the principal stock exchange of the island country of Mauritius * Strategic enrollment management, an element of planning for new growth at a university or college Energy * Single Electricity Market, the integration of the electricity sectors of the Republic of Ireland and Northern Ireland in a single market * Strategic energy management, continuous improvement process for energy efficiency based on behavioral change Mathematics and statistics * Structural equation modeling, in data analysis * Simultaneous equations model, in econometrics * Standard error of the mean in statistics Places * Craig Field (Alabama), US airport, IATA code * Sem, Ariège, France * Sem, Norway Science and technology * Scanning ...
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Standard Hydrogen Electrode
The standard hydrogen electrode (abbreviated SHE), is a redox electrode which forms the basis of the thermodynamic scale of oxidation-reduction potentials. Its absolute electrode potential is estimated to be at 25 °C, but to form a basis for comparison with all other electrochemical reactions, hydrogen's standard electrode potential (''E''°) is declared to be zero volts at any temperature. Potentials of all other electrodes are compared with that of the standard hydrogen electrode at the same temperature. Nernst equation for SHE The hydrogen electrode is based on the redox half cell corresponding to the reduction of two hydrated protons, 2 H+(aq), into one gaseous hydrogen molecule, H2(g). General equation for a reduction reaction: : \text + z~e^ \rightleftharpoons \text The reaction quotient (') of the half-reaction is the ratio between the chemical activities (''a'') of the reduced form (the reductant, ) and the oxidized form (the oxidant, ). : Q_r = \frac ...
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Oxygen Reduction Reaction
In chemistry, the oxygen reduction reaction refers to the reduction half reaction whereby O2 is reduced to water or hydrogen peroxide. In fuel cells, the reduction to water is preferred because the current is higher. The oxygen reduction reaction is well demonstrated and highly efficient in nature. Stoichiometry The stoichiometries of the oxygen reduction reaction, which depends on the medium, are shown: 4e− pathway in acid medium: O2 + 4 e- + 4H+ -> 2 H2O 2e− pathway in acid medium: O2 + 2e- + 2H+ -> H2O2 4e− pathway in alkaline medium: O2 + 4e- + 2H2O -> 4 OH- 2e− pathway in alkaline medium: O2 + 2e- + H2O -> HO2- + OH- 4e- pathway in solid oxide: O2 + 4e- -> 2 O^2- The 4e− pathway reaction is the cathode reaction in fuel cell especially in proton-exchange membrane fuel cells, alkaline fuel cell and solid oxide fuel cell. While the 2e− pathway reaction is often the side reaction of 4e- pathway or can be used in synthesis of H2O2. Catalysts Biocatalysts The oxyg ...
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Current (electricity)
An electric current is a stream of charged particles, such as electrons or ions, moving through an electrical conductor or space. It is measured as the net rate of flow of electric charge through a surface or into a control volume. The moving particles are called charge carriers, which may be one of several types of particles, depending on the conductor. In electric circuits the charge carriers are often electrons moving through a wire. In semiconductors they can be electrons or holes. In an electrolyte the charge carriers are ions, while in plasma, an ionized gas, they are ions and electrons. The SI unit of electric current is the ampere, or ''amp'', which is the flow of electric charge across a surface at the rate of one coulomb per second. The ampere (symbol: A) is an SI base unit. Electric current is measured using a device called an ammeter. Electric currents create magnetic fields, which are used in motors, generators, inductors, and transformers. In ordinary conduct ...
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