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Pozzolana
Pozzolana or pozzuolana ( , ), also known as pozzolanic ash ( la, pulvis puteolanus), is a natural siliceous or siliceous- aluminous material which reacts with calcium hydroxide in the presence of water at room temperature (cf. pozzolanic reaction). In this reaction insoluble calcium silicate hydrate and calcium aluminate hydrate compounds are formed possessing cementitious properties. The designation pozzolana is derived from one of the primary deposits of volcanic ash used by the Romans in Italy, at Pozzuoli. The modern definition of pozzolana encompasses any volcanic material (pumice or volcanic ash), predominantly composed of fine volcanic glass, that is used as a pozzolan. Note the difference with the term pozzolan, which exerts no bearing on the specific origin of the material, as opposed to pozzolana, which can only be used for pozzolans of volcanic origin, primarily composed of volcanic glass. Historical use Pozzolanas such as Santorin earth were used in the Eastern Me ...
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Pozzolanic Activity
The pozzolanic activity is a measure for the degree of reaction over time or the reaction rate between a pozzolan and Ca2+ or calcium hydroxide (Ca(OH)2) in the presence of water. The rate of the pozzolanic reaction is dependent on the intrinsic characteristics of the pozzolan such as the specific surface area, the chemical composition and the active phase content. Physical surface adsorption is not considered as being part of the pozzolanic activity, because no irreversible molecular bonds are formed in the process. Reaction The pozzolanic reaction is the chemical reaction that occurs in portland cement upon the addition of pozzolans. It is the main reaction involved in the Roman concrete invented in Ancient Rome and used to build, for example, the Pantheon. The pozzolanic reaction converts a silica-rich precursor with no cementing properties, to a calcium silicate, with good cementing properties. In chemical terms, the pozzolanic reaction occurs between calcium hydroxide, also ...
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Pozzolanic Reaction
The pozzolanic activity is a measure for the degree of reaction over time or the reaction rate between a pozzolan and Ca2+ or calcium hydroxide (Ca(OH)2) in the presence of water. The rate of the pozzolanic reaction is dependent on the intrinsic characteristics of the pozzolan such as the specific surface area, the chemical composition and the active phase content. Physical surface adsorption is not considered as being part of the pozzolanic activity, because no irreversible molecular bonds are formed in the process. Reaction The pozzolanic reaction is the chemical reaction that occurs in portland cement upon the addition of pozzolans. It is the main reaction involved in the Roman concrete invented in Ancient Rome and used to build, for example, the Pantheon. The pozzolanic reaction converts a silica-rich precursor with no cementing properties, to a calcium silicate, with good cementing properties. In chemical terms, the pozzolanic reaction occurs between calcium hydroxide, also ...
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Pozzolan
Pozzolans are a broad class of Silicon_dioxide, siliceous and aluminium oxide, aluminous materials which, in themselves, possess little or no cementitious value but which will, in finely divided form and in the presence of water, react chemically with calcium hydroxide (Ca(OH)2) at ordinary temperature to form compounds possessing cementitious properties. The quantification of the capacity of a pozzolan to react with calcium hydroxide and water is given by measuring its pozzolanic activity. ''Pozzolana'' are naturally occurring pozzolans of volcanic origin. History Mixtures of Calcination, calcined lime and finely ground, active aluminosilicate materials were pioneered and developed as inorganic binders in the Ancient world. Architectural remains of the Minoan civilization on Crete have shown evidence of the combined use of Calcium hydroxide, slaked lime and additions of finely ground potsherds for waterproof Cement render, renderings in baths, cisterns and aqueducts. Evidence o ...
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Roman Concrete
Roman concrete, also called , is a material that was used in construction in ancient Rome. Roman concrete was based on a hydraulic-setting cement. It is durable due to its incorporation of pozzolanic ash, which prevents cracks from spreading. By the middle of the 1st century the material was used frequently, often brick-faced, although variations in aggregate allowed different arrangements of materials. Further innovative developments in the material, called the concrete revolution, contributed to structurally complicated forms, such as the Pantheon dome, the world's largest and oldest unreinforced concrete dome. Roman concrete was normally faced with stone or brick, and interiors might be further decorated by stucco, fresco paintings, or thin slabs of fancy colored marbles. Made up of aggregate and a two-part cementitious system it differs significantly from modern concrete. The aggregates were typically far larger than in modern concrete as well, often amounting to rubble, a ...
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Cosa
Cosa was a Latin colony founded in southwestern Tuscany in 273 BC, on land confiscated from the Etruscans, to solidify the control of the Romans and offer the Republic a protected port. The Etruscan site (called ''Cusi'' or ''Cosia'') may have been where modern Orbetello stands; a fortification wall in polygonal masonry at Orbetello's lagoon may be in phase with the walls of Cosa. The position of Cosa is distinct, rising some 113 metres above sea level and is sited 140 km northwest of Rome on the Tyrrhenian Sea coast, on a hill near the small town of Ansedonia. The town experienced a hard life and was never truly a prosperous Roman city, although it has assumed a position of prominence in Roman archaeology owing to the circumstances of its excavation (cf. Dyson 2005, below). After the foundation, wars of the 3rd century BC affected the town. New colonists arrived in 197 BC. Cosa seems to have prospered until it was sacked in the 60s BC, perhaps by pirates - although an ea ...
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Pumice
Pumice (), called pumicite in its powdered or dust form, is a volcanic rock that consists of highly vesicular rough-textured volcanic glass, which may or may not contain crystals. It is typically light-colored. Scoria is another vesicular volcanic rock that differs from pumice in having larger vesicles, thicker vesicle walls, and being dark colored and denser.Jackson, J.A., J. Mehl, and K. Neuendorf (2005) ''Glossary of Geology'' American Geological Institute, Alexandria, Virginia. 800 pp. McPhie, J., M. Doyle, and R. Allen (1993) ''Volcanic Textures A guide to the interpretation of textures in volcanic rocks'' Centre for Ore Deposit and Exploration Studies, University of Tasmania, Hobart, Tasmania..198 pp. Pumice is created when super-heated, highly pressurized rock is violently ejected from a volcano. The unusual foamy configuration of pumice happens because of simultaneous rapid cooling and rapid depressurization. The depressurization creates bubbles by lowering the solubi ...
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Cement
A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel ( aggregate) together. Cement mixed with fine aggregate produces mortar for masonry, or with sand and gravel, produces concrete. Concrete is the most widely used material in existence and is behind only water as the planet's most-consumed resource. Cements used in construction are usually inorganic, often lime or calcium silicate based, which can be characterized as hydraulic or the less common non-hydraulic, depending on the ability of the cement to set in the presence of water (see hydraulic and non-hydraulic lime plaster). Hydraulic cements (e.g., Portland cement) set and become adhesive through a chemical reaction between the dry ingredients and water. The chemical reaction results in mineral hydrates that are not very water-soluble and so are quite durable in wa ...
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Trass
Trass is the local name of a volcanic tuff occurring in the Eifel, where it is worked for hydraulic mortar. It is a grey or cream-coloured fragmental rock, largely composed of pumiceous dust, and may be regarded as a trachytic tuff. It much resembles the Italian pozzolana and is applied to like purposes. Mixed with lime and sand, or with Portland cement, it is extensively employed for hydraulic work, especially in the Netherlands; while the compact varieties have been used as a building material and as a fire-stone in ovens. Trass was formerly worked extensively in the Brohl valley and is now obtained from the valley of the Nette, near Andernach. See also *Pozzolan *Pozzolana *Pozzolanic reaction *Pumice Pumice (), called pumicite in its powdered or dust form, is a volcanic rock that consists of highly vesicular rough-textured volcanic glass, which may or may not contain crystals. It is typically light-colored. Scoria is another vesicular vol ... References Natural m ...
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Mineral Hydration
In chemistry, mineral hydration is an inorganic chemical reaction which adds water to the crystal structure of a mineral, usually creating a new mineral, usually called a ''hydrate''. In geological terms, the process of mineral hydration is known as ''retrograde alteration'' and is a process occurring in retrograde metamorphism. It commonly accompanies metasomatism and is often a feature of wall rock alteration around ore bodies. Hydration of minerals occurs generally in concert with hydrothermal circulation which may be driven by tectonic or igneous activity. Processes There are two main ways in which minerals hydrate. One is conversion of an oxide to a double hydroxide, as with the hydration of calcium oxide—CaO—to calcium hydroxide—Ca(OH)2, the other is with the incorporation of water molecules directly into the crystalline structure of a new mineral. The later process is exhibited in the hydration of feldspars to clay minerals, garnet to chlorite, or kyanite to m ...
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IUGS
The International Union of Geological Sciences (IUGS) is an international non-governmental organization devoted to international cooperation in the field of geology. About The IUGS was founded in 1961 and is a Scientific Union member of the International Science Council (ISC), formerly the International Council for Science (ICSU), which it recognizes as the co-ordinating body for the international organization of science. Currently geologists from 121 countries (and regions) are represented in the IUGS. A broad range of scientific topics are covered by its commission, task groups, joint programmes and affiliated organizations. IUGS promotes and encourages the study of geological problems, especially those of worldwide significance, and supports and facilitates international and inter-disciplinary co-operation in the earth sciences. The Union's Secretariat is currently located at the Chinese Academy of Geological Sciences in Beijing, China. Activities IUGS is a joint partner with ...
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Volcanism
Volcanism, vulcanism or volcanicity is the phenomenon of eruption of molten rock (magma) onto the surface of the Earth or a solid-surface planet or moon, where lava, pyroclastics, and volcanic gases erupt through a break in the surface called a vent. It includes all phenomena resulting from and causing magma within the crust or mantle of the body, to rise through the crust and form volcanic rocks on the surface. Magmas, that reach the surface and solidify, form extrusive landforms. Volcanic processes Magma from the mantle or lower crust rises through the crust towards the surface. If magma reaches the surface, its behavior depends on the viscosity of the molten constituent rock. Viscous (thick) magma produces volcanoes characterised by explosive eruptions, while non-viscous (runny) magma produce volcanoes characterised by effusive eruptions pouring large amounts of lava onto the surface. In some cases, rising magma can cool and solidify without reaching the surface. Inste ...
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