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Planar Chirality
Planar chirality, also known as 2D chirality, is the special case of chirality for two dimensions. Most fundamentally, planar chirality is a mathematical term, finding use in chemistry, physics and related physical sciences, for example, in astronomy, optics and metamaterials. Recent occurrences in latter two fields are dominated by microwave and terahertz applications as well as micro- and nanostructured planar interfaces for infrared and visible light. In chemistry This term is used in chemistry contexts, e.g., for a chiral molecule lacking an asymmetric carbon atom, but possessing two non-coplanar rings that are each dissymmetric and which cannot easily rotate about the chemical bond connecting them: 2,2'-dimethylbiphenyl is perhaps the simplest example of this case. Planar chirality is also exhibited by molecules like (''E'')- cyclooctene, some di- or poly-substituted metallocenes, and certain monosubstituted paracyclophanes. Nature rarely provides planar chiral molecules ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chirality (mathematics)
In geometry, a figure is chiral (and said to have chirality) if it is not identical to its mirror image, or, more precisely, if it cannot be mapped to its mirror image by Rotation (mathematics), rotations and Translation (geometry), translations alone. An object that is not chiral is said to be ''achiral''. A chiral object and its mirror image are said to be enantiomorphs. The word ''chirality'' is derived from the Greek (cheir), the hand, the most familiar chiral object; the word ''enantiomorph'' stems from the Greek (enantios) 'opposite' + (morphe) 'form'. Examples Some chiral three-dimensional objects, such as the helix, can be assigned a right or left handedness, according to the right-hand rule. Many other familiar objects exhibit the same chiral symmetry of the human body, such as gloves and shoes. Right shoes differ from left shoes only by being mirror images of each other. In contrast thin gloves may not be considered chiral if you can wear them wiktionary:inside ou ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molecule
A molecule is a group of two or more atoms that are held together by Force, attractive forces known as chemical bonds; depending on context, the term may or may not include ions that satisfy this criterion. In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and ''molecule'' is often used when referring to polyatomic ions. A molecule may be homonuclear, that is, it consists of atoms of one chemical element, e.g. two atoms in the oxygen molecule (O2); or it may be heteronuclear, a chemical compound composed of more than one element, e.g. water (molecule), water (two hydrogen atoms and one oxygen atom; H2O). In the kinetic theory of gases, the term ''molecule'' is often used for any gaseous particle regardless of its composition. This relaxes the requirement that a molecule contains two or more atoms, since the noble gases are individual atoms. Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chirality (electromagnetism)
300px, The direction of current flow and induced magnetic flux follow a "handness" relationship The term chiral describes an object, especially a molecule, which has or produces a non-superposable mirror image of itself. In chemistry, such a molecule is called an ''enantiomer'' or is said to exhibit ''chirality'' or enantiomerism. The term "chiral" comes from the Greek word for the human hand, which itself exhibits such non-superimposeability of the left hand precisely over the right. Due to the opposition of the fingers and thumbs, no matter how the two hands are oriented, it is impossible for both hands to exactly coincide. Helices, chiral characteristics (properties), chiral media, order, and symmetry all relate to the concept of left- and right-handedness. Types of chirality Chirality describes that something is different from its mirror image. Chirality can be defined in two or three dimensions. It can be an intrinsic property of an object, such as a molecule, crystal or ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Metamaterial
A metamaterial (from the Greek word μετά ''meta'', meaning "beyond" or "after", and the Latin word ''materia'', meaning "matter" or "material") is a type of material engineered to have a property, typically rarely observed in naturally occurring materials, that is derived not from the properties of the base materials but from their newly designed structures. Metamaterials are usually fashioned from multiple materials, such as metals and plastics, and are usually arranged in repeating patterns, at scales that are smaller than the wavelengths of the phenomena they influence. Their precise shape, geometry, size, orientation, and arrangement give them their "smart" properties of manipulating electromagnetic, acoustic, or even seismic waves: by blocking, absorbing, enhancing, or bending waves, to achieve benefits that go beyond what is possible with conventional materials. Appropriately designed metamaterials can affect waves of electromagnetic radiation or sound in a manner n ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Circular Polarization
In electrodynamics, circular polarization of an electromagnetic wave is a polarization state in which, at each point, the electromagnetic field of the wave has a constant magnitude and is rotating at a constant rate in a plane perpendicular to the direction of the wave. In electrodynamics, the strength and direction of an electric field is defined by its electric field vector. In the case of a circularly polarized wave, the tip of the electric field vector, at a given point in space, relates to the phase of the light as it travels through time and space. At any instant of time, the electric field vector of the wave indicates a point on a helix oriented along the direction of propagation. A circularly polarized wave can rotate in one of two possible senses: ''right-handed circular polarization (RHCP)'' in which the electric field vector rotates in a right-hand sense with respect to the direction of propagation, and ''left-handed circular polarization (LHCP)'' in which the vecto ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Metamaterial
A metamaterial (from the Greek word μετά ''meta'', meaning "beyond" or "after", and the Latin word ''materia'', meaning "matter" or "material") is a type of material engineered to have a property, typically rarely observed in naturally occurring materials, that is derived not from the properties of the base materials but from their newly designed structures. Metamaterials are usually fashioned from multiple materials, such as metals and plastics, and are usually arranged in repeating patterns, at scales that are smaller than the wavelengths of the phenomena they influence. Their precise shape, geometry, size, orientation, and arrangement give them their "smart" properties of manipulating electromagnetic, acoustic, or even seismic waves: by blocking, absorbing, enhancing, or bending waves, to achieve benefits that go beyond what is possible with conventional materials. Appropriately designed metamaterials can affect waves of electromagnetic radiation or sound in a manner n ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cahn–Ingold–Prelog Priority Rules
In organic chemistry, the Cahn–Ingold–Prelog (CIP) sequence rules (also the CIP priority convention; named after Robert Sidney Cahn, Christopher Kelk Ingold, and Vladimir Prelog) are a standard process to completely and unequivocally name a stereoisomer of a molecule. The purpose of the CIP system is to assign an ''R'' or ''S'' descriptor to each stereocenter and an ''E'' or ''Z'' descriptor to each double bond so that the configuration of the entire molecule can be specified uniquely by including the descriptors in its systematic name. A molecule may contain any number of stereocenters and any number of double bonds, and each usually gives rise to two possible isomers. A molecule with an integer describing the number of stereocenters will usually have stereoisomers, and diastereomers each having an associated pair of enantiomers. The CIP sequence rules contribute to the precise naming of every stereoisomer of every organic molecule with all atoms of ligancy of fewe ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cavicularin
Cavicularin is a natural phenolic secondary metabolite isolated from the liverwort '' Cavicularia densa''. This macrocycle is unusual because it was the first compound isolated from nature displaying optical activity solely due to the presence of planar chirality and axial chirality. The specific rotation for (+)-cavicularin is +168.2°. It is also a very strained molecule. The ''para''-substituted phenol ring is bent about 15° out of planarity, adopting a somewhat boat-like geometry. This type of angle strain in aromatic compounds is normally reserved for synthetic cyclophanes. The liverwort was obtained from Mount Ishizuchi in the district of Shikoku. The material was dried for one day, ground to a powder and 5 grams were refluxed in methanol for 4 months to yield 2.5 mg (0.049%) of cavicularin after column chromatography and preparative TLC. Total synthesis In 2005 and again in 2011, the compound was prepared by total synthesis Total synthesis, a sp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Paracyclophane
In organic chemistry, a cyclophane is a hydrocarbon consisting of an aromatic unit (typically a benzene ring) and a chain that forms a bridge between two non-adjacent positions of the aromatic ring. More complex derivatives with multiple aromatic units and bridges forming cagelike structures are also known. Cyclophanes are well-studied examples of strained organic compounds. Cyclophanes Structures Paracyclophanes adopt the boat conformation normally observed in cyclohexanes. Smaller value of n lead to greater distortions. X-ray crystallography on ' aracyclophane' shows that the aromatic bridgehead carbon atom makes an angle of 20.5° with the plane. The benzyl carbons deviate by another 20.2°. The carbon-to-carbon bond length alternation has increased from 0 for benzene to 39 pm. Despite their distorted structures, cyclophanes retain their aromaticity, as determined by UV-vis spectroscopy. Reactivity With regards to their reactivity, cyclophanes often exhibit diene-like b ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Metallocene
A metallocene is a compound typically consisting of two cyclopentadienyl anions (, abbreviated Cp) bound to a metallic element, metal center (M) in the oxidation state II, with the resulting general formula Closely related to the metallocenes are the metallocene derivatives, e.g. titanocene dichloride or vanadocene dichloride. Certain metallocenes and their derivatives exhibit catalysis, catalytic properties, although metallocenes are rarely used industrially. Cationic group 4 metallocene derivatives related to [Cp2ZrCH3]+ catalyze Ziegler–Natta catalyst, olefin polymerization. Some metallocenes consist of metal plus two cyclooctatetraenide anions (, abbreviated cot2−), namely the lanthanocenes and the actinocenes (uranocene and others). Metallocenes are a subset of a broader class of compounds called sandwich compounds. In the structure shown at right, the two pentagons are the cyclopentadienyl anions with circles inside them indicating they are aromaticity, aromatically ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cyclooctene
Cyclooctene is the cycloalkene with a formula . Its molecule has a ring of 8 carbon atoms, connected by seven single bonds and one double bond. Cyclooctene is notable because it is the smallest cycloalkene that can exist stably as either the ''cis'' or ''trans'' stereoisomer, with ''cis''-cyclooctene being the most common. Theoretical analysis implies a total of 16 conformational and configurational isomers, all chiral, forming 8 enantiomeric pairs. The ''cis'' isomer can adopt various conformations, the most stable one being shaped like a ribbon. The most stable conformation of ''trans''-cyclooctene is shaped like the 8-carbon equivalent of the chair conformation of cyclohexane Cyclohexane is a cycloalkane with the molecular formula . Cyclohexane is non-polar. Cyclohexane is a colourless, flammable liquid with a distinctive detergent-like odor, reminiscent of cleaning products (in which it is sometimes used). Cyclohexan .... Longer cycloalkene rings such as the ten-c ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Bond
A chemical bond is the association of atoms or ions to form molecules, crystals, and other structures. The bond may result from the electrostatic force between oppositely charged ions as in ionic bonds or through the sharing of electrons as in covalent bonds, or some combination of these effects. Chemical bonds are described as having different strengths: there are "strong bonds" or "primary bonds" such as covalent, ionic and metallic bonds, and "weak bonds" or "secondary bonds" such as dipole–dipole interactions, the London dispersion force, and hydrogen bonding. Since opposite electric charges attract, the negatively charged electrons surrounding the nucleus and the positively charged protons within a nucleus attract each other. Electrons shared between two nuclei will be attracted to both of them. "Constructive quantum mechanical wavefunction interference" stabilizes the paired nuclei (see Theories of chemical bonding). Bonded nuclei maintain an optima ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
