Photoionization Cross Section
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Photoionization Cross Section
Photoionization is the physical process in which an ion is formed from the interaction of a photon with an atom or molecule. Cross section Not every interaction between a photon and an atom, or molecule, will result in photoionization. The probability of photoionization is related to the photoionization cross section of the species -- the probability of an ionization event conceptualized as a hypothetical cross-sectional area. This cross section depends on the energy of the photon (proportional to its wavenumber) and the species being considered i.e. it depends on the structure of the molecular species. In the case of molecules, the photoionization cross-section can be estimated by examination of Franck-Condon factors between a ground-state molecule and the target ion. This can be initialized by computing the vibrations of a molecule and associated cation (post ionization) using quantum chemical software e.g. QChem. For photon energies below the ionization threshold, the photoion ...
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Hubble Green Filaments 20150402
The Hubble Space Telescope (often referred to as HST or Hubble) is a space telescope that was launched into low Earth orbit in 1990 and remains in operation. It was not the first space telescope, but it is one of the largest and most versatile, renowned both as a vital research tool and as a public relations boon for astronomy. The Hubble telescope is named after astronomer Edwin Hubble and is one of NASA's Great Observatories. The Space Telescope Science Institute (STScI) selects Hubble's targets and processes the resulting data, while the Goddard Space Flight Center (GSFC) controls the spacecraft. Hubble features a mirror, and its five main instruments observe in the ultraviolet, visible, and near-infrared regions of the electromagnetic spectrum. Hubble's orbit outside the distortion of Earth's atmosphere allows it to capture extremely high-resolution images with substantially lower background light than ground-based telescopes. It has recorded some of the most detailed ...
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Above-threshold Ionization
In atomic, molecular, and optical physics, above-threshold ionization (ATI) is a multi-photon effect where an atom is ionized with more than the energetically required number of photons. It was first observed in 1979. Photoelectrons In the case of ATI the photoelectron peaks should appear at : E_s = (n + s) \hbar \omega - W, where the integer ''n'' represents the minimal number of photons absorbed, and the integer ''s'' represents the number of additional photons absorbed. ''W'' is the ionization energy, and E_s is the electron kinetic energy of the peak corresponding to ''s'' additional photons being absorbed. Structure It typically has a strong maximum at the minimal number of photons to ionize the system, with successive peaks (known as ATI peaks) separated by the photon energy and thus corresponding to higher numbers of photons being absorbed. In the non-perturbative regime the bound states are dressed with the electric field, shifting the ionization energy. If the ...
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Academic Press
Academic Press (AP) is an academic book publisher founded in 1941. It was acquired by Harcourt, Brace & World in 1969. Reed Elsevier bought Harcourt in 2000, and Academic Press is now an imprint of Elsevier. Academic Press publishes reference books, serials and online products in the subject areas of: * Communications engineering * Economics * Environmental science * Finance * Food science and nutrition * Geophysics * Life sciences * Mathematics and statistics * Neuroscience * Physical sciences * Psychology Well-known products include the ''Methods in Enzymology'' series and encyclopedias such as ''The International Encyclopedia of Public Health'' and the ''Encyclopedia of Neuroscience''. See also * Akademische Verlagsgesellschaft (AVG) — the German predecessor, founded in 1906 by Leo Jolowicz (1868–1940), the father of Walter Jolowicz Walter may refer to: People * Walter (name), both a surname and a given name * Little Walter, American blues harmonica player Marion Wa ...
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World Scientific
World Scientific Publishing is an academic publisher of scientific, technical, and medical books and journals headquartered in Singapore. The company was founded in 1981. It publishes about 600 books annually, along with 135 journals in various fields. In 1995, World Scientific co-founded the London-based Imperial College Press together with the Imperial College of Science, Technology and Medicine. Company structure The company head office is in Singapore. The Chairman and Editor-in-Chief is Dr Phua Kok Khoo, while the Managing Director is Doreen Liu. The company was co-founded by them in 1981. Imperial College Press In 1995 the company co-founded Imperial College Press, specializing in engineering, medicine and information technology, with Imperial College London. In 2006, World Scientific assumed full ownership of Imperial College Press, under a license granted by the university. Finally, in August 2016, ICP was fully incorporated into World Scientific under the new imprint ...
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Radiolysis
Radiolysis is the dissociation of molecules by ionizing radiation. It is the cleavage of one or several chemical bonds resulting from exposure to high-energy flux. The radiation in this context is associated with ionizing radiation; radiolysis is therefore distinguished from, for example, photolysis of the Cl2 molecule into two Cl- radicals, where (ultraviolet or visible spectrum) light is used. For example, water dissociates under alpha radiation into a hydrogen radical and a hydroxyl radical, unlike ionization of water which produces a hydrogen ion and a hydroxide ion. The chemistry of concentrated solutions under ionizing radiation is extremely complex. Radiolysis can locally modify redox conditions, and therefore the speciation and the solubility of the compounds. Water decomposition Of all the radiation-based chemical reactions that have been studied, the most important is the decomposition of water. When exposed to radiation, water undergoes a breakdown sequence into hydrog ...
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Ion Source
An ion source is a device that creates atomic and molecular ions. Ion sources are used to form ions for mass spectrometers, optical emission spectrometers, particle accelerators, ion implanters and ion engines. Electron ionization Electron ionization is widely used in mass spectrometry, particularly for organic molecules. The gas phase reaction producing electron ionization is :M + e^- -> M^ + 2e^- where M is the atom or molecule being ionized, e^- is the electron, and M^ is the resulting ion. The electrons may be created by an arc discharge between a cathode and an anode. An electron beam ion source (EBIS) is used in atomic physics to produce highly charged ions by bombarding atoms with a powerful electron beam. Its principle of operation is shared by the electron beam ion trap. Electron capture ionization Electron capture ionization (ECI) is the ionization of a gas phase atom or molecule by attachment of an electron to create an ion of the form A−•. The reaction ...
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Tunnel Ionization
Tunnel ionization is a process in which electrons in an atom (or a molecule) pass through the potential barrier and escape from the atom (or molecule). In an intense electric field, the potential barrier of an atom (molecule) is distorted drastically. Therefore, as the length of the barrier that electrons have to pass decreases, the electrons can escape from the atom's potential more easily. Tunneling Ionization is a quantum mechanical phenomenon, since in the classical picture an electron does not have sufficient energy to overcome the potential barrier of the atom. When the atom is in a DC external field, the Coulomb potential barrier is lowered and the electron has an increased, non-zero probability of tunnelling through the potential barrier. In the case of an alternating electric field, the direction of the electric field reverses after the half period of the field. The ionized electron may come back to its parent ion. The electron may recombine with the nucleus (nuclei) and it ...
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Quantum Tunnelling
Quantum tunnelling, also known as tunneling ( US) is a quantum mechanical phenomenon whereby a wavefunction can propagate through a potential barrier. The transmission through the barrier can be finite and depends exponentially on the barrier height and barrier width. The wavefunction may disappear on one side and reappear on the other side. The wavefunction and its first derivative are continuous. In steady-state, the probability flux in the forward direction is spatially uniform. No particle or wave is lost. Tunneling occurs with barriers of thickness around 1–3 nm and smaller. Some authors also identify the mere penetration of the wavefunction into the barrier, without transmission on the other side as a tunneling effect. Quantum tunneling is not predicted by the laws of classical mechanics where surmounting a potential barrier requires sufficient kinetic energy. Quantum tunneling plays an essential role in physical phenomena such as nuclear fusion and alpha radioact ...
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Bound State
Bound or bounds may refer to: Mathematics * Bound variable * Upper and lower bounds, observed limits of mathematical functions Physics * Bound state, a particle that has a tendency to remain localized in one or more regions of space Geography *Bound Brook (Raritan River), a tributary of the Raritan River in New Jersey * Bound Brook, New Jersey, a borough in Somerset County People *Bound (surname) *Bounds (surname) Arts, entertainment, and media Films * ''Bound'' (1996 film), an American neo-noir film by the Wachowskis * ''Bound'' (2015 film), an American erotic thriller film by Jared Cohn * ''Bound'' (2018 film), a Nigerian romantic drama film by Frank Rajah Arase Television * "Bound" (''Fringe''), an episode of ''Fringe'' * "Bound" (''The Secret Circle''), an episode of ''The Secret Circle'' * "Bound" (''Star Trek: Enterprise''), an episode of ''Star Trek: Enterprise'' Other arts, entertainment, and media * ''Bound'' (video game), a PlayStation 4 game * "Bound", a song ...
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Photoelectron Spectrum
Photoemission spectroscopy (PES), also known as photoelectron spectroscopy, refers to energy measurement of electrons emitted from solids, gases or liquids by the photoelectric effect, in order to determine the binding energies of electrons in the substance. The term refers to various techniques, depending on whether the ionization energy is provided by X-ray, XUV or UV photons. Regardless of the incident photon beam, however, all photoelectron spectroscopy revolves around the general theme of surface analysis by measuring the ejected electrons. Types X-ray photoelectron spectroscopy (XPS) was developed by Kai Siegbahn starting in 1957 and is used to study the energy levels of atomic core electrons, primarily in solids. Siegbahn referred to the technique as "electron spectroscopy for chemical analysis" (ESCA), since the core levels have small chemical shifts depending on the chemical environment of the atom that is ionized, allowing chemical structure to be determined. Siegbahn ...
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Kinetic Energy
In physics, the kinetic energy of an object is the energy that it possesses due to its motion. It is defined as the work needed to accelerate a body of a given mass from rest to its stated velocity. Having gained this energy during its acceleration, the body maintains this kinetic energy unless its speed changes. The same amount of work is done by the body when decelerating from its current speed to a state of rest. Formally, a kinetic energy is any term in a system's Lagrangian which includes a derivative with respect to time. In classical mechanics, the kinetic energy of a non-rotating object of mass ''m'' traveling at a speed ''v'' is \fracmv^2. In relativistic mechanics, this is a good approximation only when ''v'' is much less than the speed of light. The standard unit of kinetic energy is the joule, while the English unit of kinetic energy is the foot-pound. History and etymology The adjective ''kinetic'' has its roots in the Greek word κίνησις ''kinesis'', m ...
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