Perfluoropolyether
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Perfluoropolyether
Perfluoropolyether (PFPE) is a type of liquid lubricant that has been used in the aerospace industry for over 30 years. The main properties of PFPE are being temperature resistant between and (depending on specific composites), having very low outgassing compared to other fluids (vapour pressure of ) and having a dielectric strength of around 15.7 MV/m. Perfluoropolyether consists of a polymer chain in which monomers consisting of perfluoro-alkyl groups are joined by ether linkages. The bonds between carbon and oxygen or fluorine are strong. The thermal and chemical stability of PFPE along with a vapor–liquid equilibrium of 230 °C when mixed with the right composites make it a suitable candidate for vapor phase soldering technologies. History It's been developed in early 1960s at request of USAF with a requirement to be non-reacting with liquid and gaseous oxygen (O2). Manufacture Perfluoropolyether can be synthesized from tetrafluoroethylene or hexafluoropro ...
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Krytox
Krytox is a registered trademark of The Chemours Company. It refers to a group of colourless synthetic lubricants (oils and greases) with a variety of applications. Invented by researchers at DuPont, Krytox oils are fluorocarbon ether polymers of poly hexafluoropropylene oxide, with a chemical formula: F−(CF(CF3)−CF2−O)''n''−CF2CF3, where the degree of polymerization, n, generally lies within the range of 10 to 60. DuPont Krytox Performance Lubricants Product Overview, available onlinhere These compounds are collectively known by many names including perfluoropolyether (PFPE), perfluoroalkylether (PFAE) and perfluoropolyalkylether (PFPAE). A unique identifier is their CAS registry number, 60164-51-4. In addition to PFPE, Krytox grease also contains telomers of PTFE and in fact was designed as a liquid or grease form of PTFE. It is thermally stable, nonflammable (even in liquid oxygen), and insoluble in water, acids, bases, and most organic solvents. It is nonvolat ...
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Hexafluoropropylene
Hexafluoropropylene is the fluoroalkene with the formula CF3CF=CF2. It is the perfluorocarbon counterpart to the hydrocarbon propylene. It is mainly used to produce copolymers with tetrafluoroethylene. Hexafluoropropylene is used as a chemical intermediate. Preparation Hexafluoropropylene can be produced by pyrolysis of tetrafluoroethylene Tetrafluoroethylene (TFE) is a fluorocarbon with the chemical formula C2 F4. It is the simplest perfluorinated alkene. This gaseous species is used primarily in the industrial preparation of fluoropolymers. Properties Tetrafluoroethylene is a ...: :3CF2=CF2 → 2CF3CF=CF2 It can also be prepared from chlorodifluoromethane, or produced from various chlorofluorocarbons. References Fluorocarbons Haloalkenes {{organohalide-stub ...
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Wafer (electronics)
In electronics, a wafer (also called a slice or substrate) is a thin slice of semiconductor, such as a crystalline silicon (c-Si), used for the fabrication of integrated circuits and, in photovoltaics, to manufacture solar cells. The wafer serves as the substrate for microelectronic devices built in and upon the wafer. It undergoes many microfabrication processes, such as doping, ion implantation, etching, thin-film deposition of various materials, and photolithographic patterning. Finally, the individual microcircuits are separated by wafer dicing and packaged as an integrated circuit. History In the semiconductor or silicon wafer industry, the term wafer appeared in the 1950s to describe a thin round slice of semiconductor material, typically germanium or silicon. Round shape comes from single-crystal ingots usually produced using the Czochralski method. Silicon wafers were first introduced in the 1940s. By 1960, silicon wafers were being manufactured in the U. ...
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Plasma Etching
Plasma etching is a form of plasma processing used to fabricate integrated circuits. It involves a high-speed stream of glow discharge ( plasma) of an appropriate gas mixture being shot (in pulses) at a sample. The plasma source, known as etch species, can be either charged ( ions) or neutral (atoms and radicals). During the process, the plasma generates volatile etch products at room temperature from the chemical reactions between the elements of the material etched and the reactive species generated by the plasma. Eventually the atoms of the shot element embed themselves at or just below the surface of the target, thus modifying the physical properties of the target. Mechanisms Plasma generation A plasma is a high energetic condition in which a lot of processes can occur. These processes happen because of electrons and atoms. To form the plasma electrons have to be accelerated to gain energy. Highly energetic electrons transfer the energy to atoms by collisions. Three different ...
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Vacuum Grease
Vacuum grease is a lubricant with low volatility and is used for applications in low pressure environments. Lubricants with higher volatility would evaporate, causing two problems: * They would not be present to provide lubrication. * They would make lowering the pressure below their vapor pressure difficult. As well as a lubricant, vacuum grease is also used as a sealant for joints in vacuum systems. This is usually limited to soft vacuums, as ultra high vacuum or high temperatures may give problems with the grease outgassing. Grease is most commonly used with glass vacuum systems. All metal systems usually use knife-edge seals in soft metals instead. Where O ring seals are used, these should ''not'' be greased (in static seals at least) as it can cause the O rings to become permanently distorted when compressed., p. 115 In electronics manufacturing processes, vacuum grease is often used to prevent corrosion. One of the early vacuum greases is the Ramsay grease. Examp ...
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Ferrofluidic Seal
Ferrofluidic is the brand name of a staged magnetic liquid rotary sealing mechanism made by the Ferrotec Corporation and was first patented by the predecessor company's co-founder R.E.Rosensweig (USP 3,620,584). The seals are used in rotating equipment to enable rotary motion while maintaining a hermetic seal by means of a physical barrier in the form of a ferrofluid. The ferrofluid is suspended in place by use of a permanent magnet. Benefits and limitations Magnetic liquid rotary seals operate with no maintenance and extremely low leakage in a very wide range of applications. Ferrofluid-based seals used in industrial and scientific applications are most often packaged in mechanical seal assemblies called rotary feedthroughs, which also contain a central shaft, ball bearings and an outer housing. The ball bearings provide two important functions: maintaining the shaft's centering within the seal gap, and supporting external loads. The bearings are the only mechanical wear-items, ...
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Galling
Galling is a form of wear caused by adhesion between sliding surfaces. When a material galls, some of it is pulled with the contacting surface, especially if there is a large amount of force compressing the surfaces together. Galling is caused by a combination of friction and adhesion between the surfaces, followed by slipping and tearing of crystal structure beneath the surface. This will generally leave some material stuck or even friction welded to the adjacent surface, whereas the galled material may appear gouged with balled-up or torn lumps of material stuck to its surface. Galling is most commonly found in metal surfaces that are in sliding contact with each other. It is especially common where there is inadequate lubrication between the surfaces. However, certain metals will generally be more prone to galling, due to the atomic structure of their crystals. For example, aluminium is a metal that will gall very easily, whereas annealed (softened) steel is slightly mo ...
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Plastic Injection Molding
Plastics are a wide range of synthetic or semi-synthetic materials that use polymers as a main ingredient. Their plasticity makes it possible for plastics to be moulded, extruded or pressed into solid objects of various shapes. This adaptability, plus a wide range of other properties, such as being lightweight, durable, flexible, and inexpensive to produce, has led to its widespread use. Plastics typically are made through human industrial systems. Most modern plastics are derived from fossil fuel-based chemicals like natural gas or petroleum; however, recent industrial methods use variants made from renewable materials, such as corn or cotton derivatives. 9.2 billion tonnes of plastic are estimated to have been made between 1950 and 2017. More than half this plastic has been produced since 2004. In 2020, 400 million tonnes of plastic were produced. If global trends on plastic demand continue, it is estimated that by 2050 annual global plastic production will reach over 1,10 ...
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Airspace
Airspace is the portion of the atmosphere controlled by a country above its territory, including its territorial waters or, more generally, any specific three-dimensional portion of the atmosphere. It is not the same as aerospace, which is the general term for Earth's atmosphere and the outer space in its vicinity. Within the United States: * Controlled airspace exists where it is deemed necessary that air traffic control has some form of positive executive control over aircraft flying in that airspace (however, air traffic control does not necessarily control traffic operating under visual flight rules (VFR) within this airspace). Airspace may be further subdivided into a variety of areas and zones, including those where there are either restrictions on flying activities or complete prohibition of flying activities. Horizontal boundary By international law, a state "has complete and exclusive sovereignty over the airspace above its territory", which corresponds with ...
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Plug Valve
Plug valves are valves with cylindrical or conically tapered "plugs" which can be rotated inside the valve body to control flow through the valve. The plugs in plug valves have one or more hollow passageways going sideways through the plug, so that fluid can flow through the plug when the valve is open. Plug valves are simple and often economical. When the plug is conically tapered, the stem/handle is typically attached to the larger diameter end of the plug. Plug valves usually do not have bonnets but often have the end of the plug with the handle exposed or mostly exposed to the outside. In such cases, there is usually not much of a stem. The stem and handle often come in one piece, often a simple, approximately L-shaped handle attached to the end of the plug. The other end of the plug is often exposed to the outside of the valve too, but with a mechanism that retains the plug in the body. The simplest and most common general type of plug valve is a 2-port valve with two positi ...
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Chlorine Gas
Chlorine is a chemical element with the Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine is a yellow-green gas at room temperature. It is an extremely reactive element and a strong oxidising agent: among the elements, it has the highest electron affinity and the third-highest electronegativity on the revised Electronegativity#Pauling electronegativity, Pauling scale, behind only oxygen and fluorine. Chlorine played an important role in the experiments conducted by medieval Alchemy, alchemists, which commonly involved the heating of chloride Salt (chemistry), salts like ammonium chloride (sal ammoniac) and sodium chloride (common salt), producing various chemical substances containing chlorine such as hydrogen chloride, mercury(II) chloride (corrosive sublimate), and hydrochloric acid (in the form of ). However ...
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Sulfur Trioxide
Sulfur trioxide (alternative spelling sulphur trioxide, also known as ''nisso sulfan'') is the chemical compound with the formula SO3. It has been described as "unquestionably the most important economically" sulfur oxide. It is prepared on an industrial scale as a precursor to sulfuric acid. Sulfur trioxide exists in several forms - gaseous monomer, crystalline trimer, and solid polymer. Sulfur trioxide is a solid at just below room temperature with a relatively narrow liquid range. Gaseous SO3 is the primary precursor to acid rain. Molecular structure and bonding Monomer The molecule SO3 is trigonal planar. As predicted by VSEPR theory, its structure belongs to the D3h point group. The sulfur atom has an oxidation state of +6 and may be assigned a formal charge value as low as 0 (if all three sulfur-oxygen bonds are assumed to be double bonds) or as high as +2 (if the Octet Rule is assumed). When the formal charge is non-zero, the S-O bonding is assumed to be delocalized. ...
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