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Proteracacinidin
Proteracacinidins are polymeric condensed tannins composed of mesquitol. This type of tannin can be found in ''Acacia caffra'' ('' Senegalia caffra'').A novel doubly-linked proteracacinidin analogue from Acacia caffra. E Malan, A Sireeparsad, JFW Burger and D Ferreira, Tetrahedron letters, 1994 The oxydative depolymerisation of proteracacinidins yields the anthocyanidin Anthocyanidins are common plant pigments, the sugar-free counterparts of anthocyanins. They are based on the flavylium cation, an oxonium ion, with various groups substituted for its hydrogen atoms. They generally change color from red through ... teracacinidin. References Condensed tannins Senegalia {{phenol-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Condensed Tannin
Condensed tannins (proanthocyanidins, polyflavonoid tannins, catechol-type tannins, pyrocatecollic type tannins, non-hydrolyzable tannins or flavolans) are polymers formed by the condensation of flavans. They do not contain sugar residues. They are called proanthocyanidins as they yield anthocyanidins when depolymerized under oxidative conditions. Different types of condensed tannins exist, such as the procyanidins, propelargonidins, prodelphinidins, profisetinidins, proteracacinidins, proguibourtinidins or prorobinetidins. All of the above are formed from flavan-3-ols, but flavan-3,4-diols, called (leucoanthocyanidin) also form condensed tannin oligomers, e.g. leuco-fisetinidin form profisetinidin, and flavan-4-ols form condensed tannins, e.g. 3',4',5,7-flavan-4-ol form proluteolinidin (luteoforolor). One particular type of condensed tannin, found in grape, are procyanidins, which are polymers of 2 to 50 (or more) catechin units joined by carbon-carbon bonds. These are not ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mesquitol
Mesquitol is a flavan-3-ol, a type of flavonoid. ''Prosopis juliflora'', an invasive New World mesquite now found in Kenya, has unusually high levels of (-)-mesquitol in its heartwood. Mesquitol, with its pyrogallol-type A-ring, is more susceptible to quinone formation at this ring, leading to aryl–aryl bond formation at carbon 5. The structural moieties constitute the proteracacinidin class of proanthocyanidins. Mesquitol-(5→8)-catechin atropisomers can be isolated from ''Prosopis glandulosa ''Prosopis glandulosa'', commonly known as honey mesquite, is a species of small to medium-sized, thorny shrub or tree in the legume family (Fabaceae). Distribution The plant is primarily native to the Southwestern United States and Northern M ...''.Synthesis of condensed tannins. Part 17. Oligomeric (2R,3S)-3,3′,4′,7,8-pentahydroxyflavans: atropisomerism and conformation of biphenyl and m-terphenyl analogues from Prosopis glandulosa(‘mesquite’). Esmé Young, Edward V. Br ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Senegalia Caffra
''Senegalia caffra'', also known as hook-thorn or ''Acacia caffra'', is a tree that occurs commonly in southern Africa. Though it is cultivated, it often occurs naturally in Gauteng suburban gardens, together with '' Acacia karroo'' and ''Acacia robusta''. It is up to tall and may be found in open woodland, grassland, rocky hillsides or watercourses. Description It has extremely hard, dense and attractive timber, and is only spared from intense exploitation because of its strongly twisted trunk which does not lend itself to long planks, and its tendency to develop heart rot. The bark is rough, dark grey and flaking, while the strong, paired hooked thorns are a formidable deterrent on young plants. Twigs which may vary in hairiness from densely puberulous to pubescent or tomentose. Due to its variability the species has been described under many names, some being listed below. ''Senegalia caffra'' is deciduous and older plants are resistant to frost, fire and drought. Its appe ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Promelacacinidin
Promelacacinidin is a polymeric condensed tannin composed of mesquitol. This type of tannin can be found in '' Senegalia caffra''. The oxidative depolymerization of proteracacinidins yields the anthocyanidin Anthocyanidins are common plant pigments, the sugar-free counterparts of anthocyanins. They are based on the flavylium cation, an oxonium ion, with various groups substituted for its hydrogen atoms. They generally change color from red through ... melacacinidin. References Condensed tannins Senegalia {{phenol-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Anthocyanidin
Anthocyanidins are common plant pigments, the sugar-free counterparts of anthocyanins. They are based on the flavylium cation, an oxonium ion, with various groups substituted for its hydrogen atoms. They generally change color from red through purple, blue, and bluish green as a function of pH. Anthocyanidins are an important subclass of the polymethine dyes and flavonoids. The flavylium cation is a chromenylium cation with a phenyl group substituted in position 2; and chromenylium (also called benzopyrylium) is a bicyclic version of pyrylium. The positive charge can move around the molecule. At least 31 monomeric anthocyanidins have been properly identified in living organisms, mostly as the core components of anthocyanins. The latter are responsible for the red, purple, blue, or black color of many fruits (like grapes and blueberries), flowers (like roses), leaves (like purple cabbage), and even tubers (like radishes and purple yams). They are also found in some animals ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Condensed Tannins
Condensed tannins (proanthocyanidins, polyflavonoid tannins, catechol-type tannins, pyrocatecollic type tannins, non-hydrolyzable tannins or flavolans) are polymers formed by the condensation of flavans. They do not contain sugar residues. They are called proanthocyanidins as they yield anthocyanidins when depolymerized under oxidative conditions. Different types of condensed tannins exist, such as the procyanidins, propelargonidins, prodelphinidins, profisetinidins, proteracacinidins, proguibourtinidins or prorobinetidins. All of the above are formed from flavan-3-ols, but flavan-3,4-diols, called (leucoanthocyanidin) also form condensed tannin oligomers, e.g. leuco-fisetinidin form profisetinidin, and flavan-4-ols form condensed tannins, e.g. 3',4',5,7-flavan-4-ol form proluteolinidin (luteoforolor). One particular type of condensed tannin, found in grape, are procyanidins, which are polymers of 2 to 50 (or more) catechin units joined by carbon-carbon bonds. These are n ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
