Oil Dispersants
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Oil Dispersants
An oil dispersant is a mixture of emulsifiers and solvents that helps break oil into small droplets following an oil spill. Small droplets are easier to disperse throughout a water volume, and small droplets may be more readily biodegraded by microbes in the water. Dispersant use involves a trade-off between exposing coastal life to surface oil and exposing aquatic life to dispersed oil. While submerging the oil with dispersant may lessen exposure to marine life on the surface, it increases exposure for animals dwelling underwater, who may be harmed by toxicity of both dispersed oil and dispersant. Although dispersant reduces the amount of oil that lands ashore, it may allow faster, deeper penetration of oil into coastal terrain, where it is not easily biodegraded. History ''Torrey Canyon'' In 1967, the supertanker ''Torrey Canyon'' leaked oil onto the English coastline. Alkylphenol surfactants were primarily used to break up the oil, but proved very toxic in the marine ...
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Dispersant Mechanism
A dispersant or a dispersing agent is a substance, typically a surfactant, that is added to a suspension (chemistry), suspension of solid or liquid particles in a liquid (such as a colloid or emulsion) to improve the separation of the particles and to prevent their settling or clumping. Dispersants are widely used to stabilize various industrial and artisanal products, such as paints, ferrofluids, and salad dressings. The plasticizers or superplasticizers, used to improve the workability of pastes like concrete and clay, are typically dispersants. The concept also largely overlaps with that of detergent, used to bring oily contamination into water suspension, and of emulsifier, used to create homogeneous mixtures of immiscible liquids like water and oil. Natural suspensions like milk and latex contain substances that act as dispersants. Applications Automotive Automotive Motor oil, engine oils contain both detergents and dispersants. Metallic-based detergents prevent the accumula ...
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Corexit
Corexit (often styled COREXIT) is a product line of oil dispersants used during oil spill response operations. It is produced by Nalco Holding Company, an indirect subsidiary of Ecolab. Corexit was originally developed by the Standard Oil Company of New Jersey. Corexit is typically applied by aerial spraying or spraying from ships directly onto an oil slick. On contact with the dispersant, oil that would otherwise float on the surface of the water is emulsified into tiny droplets and sinks or (in the unusual case of sub-surface application) remains suspended in the water. In theory this allows the oil to be more rapidly degraded by bacteria (bioremediation) and prevents it from accumulating on beaches and in marshes. Corexit was used in unprecedented quantities during the 2010 Deepwater Horizon oil spill in the Gulf of Mexico and became the largest use of such chemicals in the United States. In addition to spraying the dispersant onto the surface slick, it was used in an unteste ...
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Poise (unit)
The poise (symbol P; ) is the unit of dynamic viscosity (absolute viscosity) in the centimetre–gram–second system of units (CGS). It is named after Jean Léonard Marie Poiseuille (see Hagen–Poiseuille equation). The centipoise (1 cP = 0.01 P) is more commonly used than the poise itself. Dynamic viscosity has dimension \mathrm. 1~\text = 0.1~\text^ \text \text^ = 1~\text^ \text \text^ = 1~\text \text \text^. The analogous unit in the International System of Units is the pascal-second (Pa⋅s): 1~\text \text = 1~\text \text \text^ = 1~\text^ \text \text^ = 10~\text. The poise is often used with the metric prefix ''centi-'' because the viscosity of water at 20 °C ( standard conditions for temperature and pressure) is almost exactly 1 centipoise. A centipoise is one hundredth of a poise, or one millipascal-second (mPa⋅s) in SI units (1 cP = 10−3 Pa⋅s = 1 mPa⋅s). The CGS symbol for the centipoise is cP. The abbreviations cps, ...
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Viscosity
The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the internal frictional force between adjacent layers of fluid that are in relative motion. For instance, when a viscous fluid is forced through a tube, it flows more quickly near the tube's axis than near its walls. Experiments show that some stress (such as a pressure difference between the two ends of the tube) is needed to sustain the flow. This is because a force is required to overcome the friction between the layers of the fluid which are in relative motion. For a tube with a constant rate of flow, the strength of the compensating force is proportional to the fluid's viscosity. In general, viscosity depends on a fluid's state, such as its temperature, pressure, and rate of deformation. However, the dependence on some of these properties is ...
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Electric-field Screening
In physics, screening is the damping of electric fields caused by the presence of mobile charge carriers. It is an important part of the behavior of charge-carrying fluids, such as ionized gases (classical plasmas), electrolytes, and charge carriers in electronic conductors (semiconductors, metals). In a fluid, with a given permittivity , composed of electrically charged constituent particles, each pair of particles (with charges and ) interact through the Coulomb force as \mathbf = \frac\hat, where the vector is the relative position between the charges. This interaction complicates the theoretical treatment of the fluid. For example, a naive quantum mechanical calculation of the ground-state energy density yields infinity, which is unreasonable. The difficulty lies in the fact that even though the Coulomb force diminishes with distance as , the average number of particles at each distance is proportional to , assuming the fluid is fairly isotropic. As a result, a charge fl ...
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Interfacial Tension
Surface tension is the tendency of liquid surfaces at rest to shrink into the minimum surface area possible. Surface tension is what allows objects with a higher density than water such as razor blades and insects (e.g. water striders) to float on a water surface without becoming even partly submerged. At liquid–air interfaces, surface tension results from the greater attraction of liquid molecules to each other (due to cohesion) than to the molecules in the air (due to adhesion). There are two primary mechanisms in play. One is an inward force on the surface molecules causing the liquid to contract. Second is a tangential force parallel to the surface of the liquid. This ''tangential'' force is generally referred to as the surface tension. The net effect is the liquid behaves as if its surface were covered with a stretched elastic membrane. But this analogy must not be taken too far as the tension in an elastic membrane is dependent on the amount of deformation of the ...
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Maritime New Zealand
Maritime New Zealand (New Zealand Maritime Safety Authority) is a Crown entity and also a state maritime safety authority responsible for protecting the maritime transport sequence and marine environment within New Zealand and maintaining safety and security. They define their vision as: "a maritime environment with minimum deaths, accidents, incidents and pollution as part of an integrated and sustainable transport system”. Maritime New Zealand supports people by providing guidance and advice about Seafarer Certifications as well. History A maritime authority called the Marine Board was originally established in 1862 and controlled by the Customs Department until near the end of the nineteenth century, when it was renamed the Marine Department. In 1907 the Marine Department acquired the 805 ton Royal Navy gun boat HMS ''Sparrow''. This was converted into a training ship and renamed NZS ''Amokura''. Over the next 14 years 527 boys trained in ''Amokura'', 25 of them going o ...
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Ecotoxicity
Ecotoxicity, the subject of study in the field of ecotoxicology (a portmanteau of ecology and toxicology), refers to the biological, chemical or physical stressors that affect ecosystems. Such stressors could occur in the natural environment at densities, concentrations, or levels high enough to disrupt natural biochemical and physiological behavior and interactions. This ultimately affects all living organisms that comprise an ecosystem. Ecotoxicology has been defined as a branch of toxicology that focuses on the study of toxic effects, caused by natural or synthetic pollutants. These pollutants affect animals (including humans), vegetation, and microbes, in an intrinsic way. Acute vs. chronic ecotoxicity According to Barrie Peake in their paper “Impact of Pharmaceuticals on the Environment.”, The ecotoxicity of chemicals can be described based on the amount of exposure to any hazardous materials. There are two categories of ecotoxicity founded off of this description: ...
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Georgia Institute Of Technology
The Georgia Institute of Technology, commonly referred to as Georgia Tech or, in the state of Georgia, as Tech or The Institute, is a public research university and institute of technology in Atlanta, Georgia. Established in 1885, it is part of the University System of Georgia and has satellite campuses in Savannah, Georgia; Metz, France; Shenzhen, China; and Singapore. The school was founded as the Georgia School of Technology as part of Reconstruction plans to build an industrial economy in the post-Civil War Southern United States. Initially, it offered only a degree in mechanical engineering. By 1901, its curriculum had expanded to include electrical, civil, and chemical engineering. In 1948, the school changed its name to reflect its evolution from a trade school to a larger and more capable technical institute and research university. Today, Georgia Tech is organized into six colleges and contains about 31 departments/units, with emphasis on science and technology. I ...
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Plankton
Plankton are the diverse collection of organisms found in Hydrosphere, water (or atmosphere, air) that are unable to propel themselves against a Ocean current, current (or wind). The individual organisms constituting plankton are called plankters. In the ocean, they provide a crucial source of food to many small and large aquatic organisms, such as bivalves, fish and whales. Marine plankton include bacteria, archaea, algae, protozoa and drifting or floating animals that inhabit the saltwater of oceans and the brackish waters of estuaries. Freshwater plankton are similar to marine plankton, but are found in the freshwaters of lakes and rivers. Plankton are usually thought of as inhabiting water, but there are also airborne versions, the aeroplankton, that live part of their lives drifting in the atmosphere. These include plant spores, pollen and wind-scattered seeds, as well as microorganisms swept into the air from terrestrial dust storms and oceanic plankton swept into the air ...
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Exxon Valdez Oil Spill
The ''Exxon Valdez'' oil spill occurred in Prince William Sound, Alaska, on March 24, 1989. ''Exxon Valdez'', an oil supertanker owned by Exxon Shipping Company bound for Long Beach, California struck Prince William Sound's Bligh Reef, west of Tatitlek, Alaska at 12:04 a.m. and spilled (or 37,000 tonnes) of crude oil over the next few days. The ''Exxon Valdez'' spill is the second largest in U.S. waters, after the 2010 ''Deepwater Horizon'' oil spill, in terms of volume of oil released. Prince William Sound's remote location, accessible only by helicopter, plane, or boat, made government and industry response efforts difficult and made existing response plans especially hard to implement. The region is a habitat for salmon, sea otters, seals, and seabirds. The oil, extracted from the Prudhoe Bay Oil Field, eventually affected of coastline, of which were heavily or moderately oiled. Spill ''Exxon Valdez'' was carrying of oil, of which approximately were spilled int ...
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Ixtoc I Oil Spill
Ixtoc 1 was an exploratory oil well being drilled by the semi-submersible drilling rig ''Sedco 135'' in the Bay of Campeche of the Gulf of Mexico, about northwest of Ciudad del Carmen, Campeche in waters deep. On 3 June 1979, the well suffered a blowout resulting in one of the largest oil spills in history. Accident Mexico's state-owned oil company Pemex (Petróleos Mexicanos) was drilling a deep oil well when the drilling rig ''Sedco 135'' lost drilling mud circulation. In modern rotary drilling, mud is circulated down the drillpipe and back up the wellbore to the surface. The goal is to equalize the pressure through the shaft and to monitor the returning mud for gas. Without the counter-pressure provided by the circulating mud, the pressure in the formation allowed oil to fill the well column, blowing out the well. The oil caught fire, and ''Sedco 135'' was extensively burned then scuttled. At the time of the accident ''Sedco 135'' was drilling at a depth of about bel ...
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