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Organic Geochemistry
Organic geochemistry is the study of the impacts and processes that organisms have had on the Earth. It is mainly concerned with the composition and mode of origin of organic matter in rocks and in bodies of water. The study of organic geochemistry is traced to the work of Alfred E. Treibs, "the father of organic geochemistry." Treibs first isolated metalloporphyrins from petroleum. This discovery established the biological origin of petroleum, which was previously poorly understood. Metalloporphyrins in general are highly stable organic compounds, and the detailed structures of the extracted derivatives made clear that they originated from chlorophyll. Applications Energy Petroleum The relationship between the occurrence of organic compounds in sedimentary deposits and petroleum deposits has long been of interest. Studies of ancient sediments and rock provide insights into the origins and sources of oil and petroleum, as well as the biochemical antecedents of life. Oil spills in ...
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Carbon Cycle-cute Diagram
Carbon () is a chemical element with the chemical symbol, symbol C and atomic number 6. It is nonmetallic and tetravalence, tetravalent—its atom making four electrons available to form covalent bond, covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon makes up only about 0.025 percent of Earth's crust. Three Isotopes of carbon, isotopes occur naturally, Carbon-12, C and Carbon-13, C being stable, while Carbon-14, C is a radionuclide, decaying with a half-life of about 5,730 years. Carbon is one of the Timeline of chemical element discoveries#Ancient discoveries, few elements known since antiquity. Carbon is the 15th Abundance of elements in Earth's crust, most abundant element in the Earth's crust, and the Abundance of the chemical elements, fourth most abundant element in the universe by mass after hydrogen, helium, and oxygen. Carbon's abundance, its unique diversity of organic compounds, and its unusual ability to form polymers at the tempera ...
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Isochron
In the mathematical theory of dynamical systems, an isochron is a set of initial conditions for the system that all lead to the same long-term behaviour. Mathematical isochron An introductory example Consider the ordinary differential equation for a solution y(t) evolving in time: : \frac + \frac = 1 This ordinary differential equation (ODE) needs two initial conditions at, say, time t=0. Denote the initial conditions by y(0)=y_0 and dy/dt(0)=y'_0 where y_0 and y'_0 are some parameters. The following argument shows that the isochrons for this system are here the straight lines y_0+y'_0=\mbox. The general solution of the above ODE is :y=t+A+B\exp(-t) Now, as time increases, t\to\infty, the exponential terms decays very quickly to zero (exponential decay). Thus ''all'' solutions of the ODE quickly approach y\to t+A. That is, ''all'' solutions with the same A have the same long term evolution. The exponential decay of the B\exp(-t) term brings together a host of solution ...
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Climate Forcing
Earth's climate system is a complex system having five interacting components: the atmosphere (air), the hydrosphere (water), the cryosphere (ice and permafrost), the lithosphere (earth's upper rocky layer) and the biosphere (living things). ''Climate'' is the statistical characterization of the climate system, representing the average weather, typically over a period of 30 years, and is determined by a combination of processes in the climate system, such as ocean currents and wind patterns. Circulation in the atmosphere and oceans is primarily driven by solar radiation and transports heat from the tropical regions to regions that receive less energy from the Sun. The water cycle also moves energy throughout the climate system. In addition, different chemical elements, necessary for life, are constantly recycled between the different components. The climate system can change due to internal variability and external forcings. These external forcings can be natural, such as vari ...
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Aerosol Movement
An aerosol is a suspension of fine solid particles or liquid droplets in air or another gas. Aerosols can be natural or anthropogenic. Examples of natural aerosols are fog or mist, dust, forest exudates, and geyser steam. Examples of anthropogenic aerosols include particulate air pollutants, mist from the discharge at hydroelectric dams, irrigation mist, perfume from atomizers, smoke, steam from a kettle, sprayed pesticides, and medical treatments for respiratory illnesses. When a person inhales the contents of a vape pen or e-cigarette, they are inhaling an anthropogenic aerosol. The liquid or solid particles in an aerosol have diameters typically less than 1 μm (larger particles with a significant settling speed make the mixture a suspension, but the distinction is not clear-cut). In general conversation, ''aerosol'' often refers to a dispensing system that delivers a consumer product from a can. Diseases can spread by means of small droplets in the breath, so ...
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Hydrocarbons
In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or exemplified by the odors of gasoline and lighter fluid. They occur in a diverse range of molecular structures and phases: they can be gases (such as methane and propane), liquids (such as hexane and benzene), low melting solids (such as paraffin wax and naphthalene) or polymers (such as polyethylene and polystyrene). In the fossil fuel industries, ''hydrocarbon'' refers to the naturally occurring petroleum, natural gas and coal, and to their hydrocarbon derivatives and purified forms. Combustion of hydrocarbons is the main source of the world's energy. Petroleum is the dominant raw-material source for organic commodity chemicals such as solvents and polymers. Most anthropogenic (human-generated) emissions of greenhouse gases are carb ...
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Late Cretaceous Period
The Late Cretaceous (100.5–66 Ma) is the younger of two epochs into which the Cretaceous Period is divided in the geologic time scale. Rock strata from this epoch form the Upper Cretaceous Series. The Cretaceous is named after ''creta'', the Latin word for the white limestone known as chalk. The chalk of northern France and the white cliffs of south-eastern England date from the Cretaceous Period. Climate During the Late Cretaceous, the climate was warmer than present, although throughout the period a cooling trend is evident. The tropics became restricted to equatorial regions and northern latitudes experienced markedly more seasonal climatic conditions. Geography Due to plate tectonics, the Americas were gradually moving westward, causing the Atlantic Ocean to expand. The Western Interior Seaway divided North America into eastern and western halves; Appalachia and Laramidia. India maintained a northward course towards Asia. In the Southern Hemisphere, Australia and Antar ...
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Uranium Isotopes
Uranium (92U) is a naturally occurring radioactive element that has no stable isotope. It has two primordial isotopes, uranium-238 and uranium-235, that have long half-lives and are found in appreciable quantity in the Earth's crust. The decay product uranium-234 is also found. Other isotopes such as uranium-233 have been produced in breeder reactors. In addition to isotopes found in nature or nuclear reactors, many isotopes with far shorter half-lives have been produced, ranging from 214U to 242U (with the exceptions of 220U and 241U). The standard atomic weight of natural uranium is . Naturally occurring uranium is composed of three major isotopes, uranium-238 (99.2739–99.2752% natural abundance), uranium-235 (0.7198–0.7202%), and uranium-234 (0.0050–0.0059%). All three isotopes are radioactive (i.e., they are radioisotopes), and the most abundant and stable is uranium-238, with a half-life of (close to the age of the Earth). Uranium-238 is an alpha emitter, deca ...
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Isochron Dating
Isochron dating is a common technique of radiometric dating and is applied to date certain events, such as crystallization, metamorphism, shock events, and differentiation of precursor melts, in the history of rocks. Isochron dating can be further separated into ''mineral isochron dating'' and ''whole rock isochron dating''; both techniques are applied frequently to date terrestrial and also extraterrestrial rocks (meteorites). The advantage of isochron dating as compared to simple radiometric dating techniques is that no assumptions are needed about the initial amount of the daughter nuclide in the radioactive decay sequence. Indeed, the initial amount of the daughter product can be determined using isochron dating. This technique can be applied if the daughter element has at least one stable isotope other than the daughter isotope into which the parent nuclide decays. Basis for method All forms of isochron dating assume that the source of the rock or rocks contained unknown amo ...
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Pyrolysis
The pyrolysis (or devolatilization) process is the thermal decomposition of materials at elevated temperatures, often in an inert atmosphere. It involves a change of chemical composition. The word is coined from the Greek-derived elements ''pyro'' "fire", "heat", "fever" and '' lysis'' "separating". Pyrolysis is most commonly used in the treatment of organic materials. It is one of the processes involved in charring wood.''Burning of wood''
, InnoFireWood's website. Accessed on 2010-02-06.
In general, pyrolysis of organic substances produces volatile products and leaves , a carbon-rich solid residue. Extreme pyrolysis, which leaves mostly

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Exxon Valdez Oil Spill
The ''Exxon Valdez'' oil spill occurred in Prince William Sound, Alaska, on March 24, 1989. ''Exxon Valdez'', an oil supertanker owned by Exxon Shipping Company bound for Long Beach, California struck Prince William Sound's Bligh Reef, west of Tatitlek, Alaska at 12:04 a.m. and spilled (or 37,000 tonnes) of crude oil over the next few days. The ''Exxon Valdez'' spill is the second largest in U.S. waters, after the 2010 ''Deepwater Horizon'' oil spill, in terms of volume of oil released. Prince William Sound's remote location, accessible only by helicopter, plane, or boat, made government and industry response efforts difficult and made existing response plans especially hard to implement. The region is a habitat for salmon, sea otters, seals, and seabirds. The oil, extracted from the Prudhoe Bay Oil Field, eventually affected of coastline, of which were heavily or moderately oiled. Spill ''Exxon Valdez'' was carrying of oil, of which approximately were spilled int ...
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Gas Chromatography-mass Spectrometry
Gas is one of the four fundamental states of matter (the others being solid, liquid, and plasma). A pure gas may be made up of individual atoms (e.g. a noble gas like neon), elemental molecules made from one type of atom (e.g. oxygen), or compound molecules made from a variety of atoms (e.g. carbon dioxide). A gas mixture, such as air, contains a variety of pure gases. What distinguishes a gas from liquids and solids is the vast separation of the individual gas particles. This separation usually makes a colourless gas invisible to the human observer. The gaseous state of matter occurs between the liquid and plasma states, the latter of which provides the upper temperature boundary for gases. Bounding the lower end of the temperature scale lie degenerative quantum gases which are gaining increasing attention. High-density atomic gases super-cooled to very low temperatures are classified by their statistical behavior as either Bose gases or Fermi gases. For a comprehensive listi ...
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Carbon NMR
Carbon-13 (C13) nuclear magnetic resonance (most commonly known as carbon-13 NMR spectroscopy or 13C NMR spectroscopy or sometimes simply referred to as carbon NMR) is the application of nuclear magnetic resonance (NMR) spectroscopy to carbon. It is analogous to proton NMR ( NMR) and allows the identification of carbon atoms in an organic molecule just as proton NMR identifies hydrogen atoms. 13C NMR detects only the isotope. The main carbon isotope, is not detected. Although much less sensitive than 1H NMR spectroscopy, 13C NMR spectroscopy is widely used for characterizing organic and organometallic compounds. Chemical shifts 13C NMR chemical shifts follow the same principles as those of 1H, although the typical range of chemical shifts is much larger than for 1H (by a factor of about 20). The chemical shift reference standard for 13C is the carbons in tetramethylsilane (TMS), whose chemical shift is considered to be 0.0 ppm. ImageSize = width:540 height:440 AlignBar ...
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