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Nylon-6,6
Nylon 66 (loosely written nylon 6-6, nylon 6/6, nylon 6,6, or nylon 6:6) is a type of polyamide or nylon. It, and nylon 6, are the two most common for textile and plastic industries. Nylon 66 is made of two monomers each containing 6 carbon atoms, hexamethylenediamine and adipic acid, which give nylon 66 its name. Aside from its superior physical characteristics, nylon 66 is attractive because its precursors are inexpensive. Synthesis and manufacturing Hexamethylenediamine (top) and adipic acid (bottom), monomers used for polycondensation of Nylon 66. Nylon 66 is synthesized by polycondensation of hexamethylenediamine and adipic acid. Equivalent amounts of hexamethylenediamine and adipic acid are combined in water. In the original implementation, the resulting ammonium/carboxylate salt was isolated and then heated either in batches or continuously to induce polycondensation.n(HOOC - (CH2)4 - COOH) + n(H2N - (CH2)6 - NH2) -> OC - (CH2)4 - CO - NH - (CH2)6 - NH - n + (2n - 1) ...
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Polyamide
A polyamide is a polymer with repeating units linked by amide bonds. Polyamides occur both naturally and artificially. Examples of naturally occurring polyamides are proteins, such as wool and silk. Artificially made polyamides can be made through step-growth polymerization or solid-phase synthesis yielding materials such as nylons, aramids, and sodium polyaspartate. Synthetic polyamides are commonly used in textiles, automotive industry, carpets, kitchen utensils and sportswear due to their high durability and strength. The transportation manufacturing industry is the major consumer, accounting for 35% of polyamide (PA) consumption. Classification Polymers of amino acids are known as polypeptides or proteins. According to the composition of their main chain, synthetic polyamides are classified as follows: All polyamides are made by the formation of an amide function to link two molecules of monomer together. The monomers can be amides themselves (usually in the form of a cycli ...
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Radiator
Radiators are heat exchangers used to transfer thermal energy from one medium to another for the purpose of cooling and heating. The majority of radiators are constructed to function in cars, buildings, and electronics. A radiator is always a source of heat to its environment, although this may be for either the purpose of heating this environment, or for cooling the fluid or coolant supplied to it, as for automotive engine cooling and HVAC dry cooling towers. Despite the name, most radiators transfer the bulk of their heat via convection instead of thermal radiation. History The Roman hypocaust is an early example of a type of radiator for building space heating. Franz San Galli, a Prussian-born Russian businessman living in St. Petersburg, is credited with inventing the heating radiator around 1855, having received a radiator patent in 1857, but American Joseph Nason developed a primitive radiator in 1841 and received a number of U.S. patents for hot water and steam heating. ...
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Synthetic Fibers
Synthetic fibers or synthetic fibres (in British English; see spelling differences) are fibers made by humans through chemical synthesis, as opposed to natural fibers that are directly derived from living organisms, such as plants (like cotton) or fur from animals. They are the result of extensive research by scientists to replicate naturally occurring animal and plant fibers. In general, synthetic fibers are created by extruding fiber-forming materials through spinnerets, forming a fiber. These are called synthetic or artificial fibers. The word polymer comes from a Greek prefix "poly" which means "many" and suffix "mer" which means "single units". (Note: each single unit of a polymer is called a monomer). Early experiments The first fully synthetic fiber was glass. Joseph Swan invented one of the first artificial fibers in the early 1880s; today it would be called semisynthetic in precise usage. His fiber was drawn from a cellulose liquid, formed by chemically modifying ...
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Plastics
Plastics are a wide range of synthetic polymers, synthetic or semi-synthetic materials that use polymers as a main ingredient. Their Plasticity (physics), plasticity makes it possible for plastics to be Injection moulding, moulded, Extrusion, extruded or Compression molding, pressed into solid objects of various shapes. This adaptability, plus a wide range of other properties, such as being lightweight, durable, flexible, and inexpensive to produce, has led to its widespread use. Plastics typically are made through human industrial systems. Most modern plastics are derived from petrochemical, fossil fuel-based chemicals like natural gas or petroleum; however, recent industrial methods use variants made from renewable materials, such as corn or cotton derivatives. 9.2 billion tonnes of plastic are estimated to have been made between 1950 and 2017. More than half this plastic has been produced since 2004. In 2020, 400 million tonnes of plastic were produced. If global trends on pl ...
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Polyamides
A polyamide is a polymer with repeating units linked by amide bonds. Polyamides occur both naturally and artificially. Examples of naturally occurring polyamides are proteins, such as wool and silk. Artificially made polyamides can be made through step-growth polymerization or solid-phase synthesis yielding materials such as nylons, aramids, and sodium polyaspartate. Synthetic polyamides are commonly used in textiles, automotive industry, carpets, kitchen utensils and sportswear due to their high durability and strength. The transportation manufacturing industry is the major consumer, accounting for 35% of polyamide (PA) consumption. Classification Polymers of Amino acid, amino acids are known as polypeptides or proteins. According to the composition of their main chain, synthetic polyamides are classified as follows: All polyamides are made by the formation of an amide function to link two molecules of monomer together. The monomers can be amides themselves (usually in the for ...
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Nylon Rope Trick
The nylon rope trick is a scientific demonstration that illustrates some of the fundamental chemical principles of step-growth polymerization and provides students and other observers with a hands-on demonstration of the preparation of a synthetic polymer. The nylon rope trick typically makes use of a water solution of an aliphatic diamine with a solution of an aliphatic diacid chloride in a solvent that does not dissolve in water, yielding a synthetic polyamide of the nylon-type. Nylon 610 is commonly used, in which hexamethylene diamine is dissolved in water to a concentration of about 0.40 moles / deciliter. A solution of sebacoyl chloride in cyclohexane (0.15 moles / deciliter concentration) is then layered on top of the water solution, the reaction typically being conducted in a beaker. The solution is not agitated; instead the nylon 610 polymer forms as a flexible film at the interface of the water and cyclohexane layers, in an example of an interfacial polymerizatio ...
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Comparative Tracking Index
The Comparative Tracking Index (CTI) is used to measure the electrical breakdown (tracking) properties of an insulating material. Tracking is an electrical breakdown on the ''surface'' of an insulating material wherein an initial exposure to electrical arcing heat carbonizes the material. The carbonized areas are more conductive than the pristine insulator, increasing current flow, resulting in increased heat generation, and eventually the insulation becomes completely conductive. Details A large voltage difference gradually creates a conductive leakage path across the surface of the material by forming a carbonized track. Testing method is specified in IEC standard 60112 and ASTM D3638. To measure the tracking, 50 drops of 0.1% ammonium chloride solution are dropped on the material, and the voltage measured for a 3 mm thickness is considered representative of the material performance. Also term PTI (Proof Tracking Index) is used: it means voltage at which during testing on ...
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UL 94
UL 94, the Standard for Safety of Flammability of Plastic Materials for Parts in Devices and Appliances testing, is a plastics flammability standard released by Underwriters Laboratories of the United States. The standard determines the material’s tendency to either extinguish or spread the flame once the specimen has been ignitedUL-94is now harmonized with IECbr>60695-11-10an60695-11-20and ISObr>9772an The VW-1 (vertical wire burn) rating is sometimes erroneously associated with UL 94, but it (and some other flammability tests) is described by UL 1581 (Reference Standard for Electrical Wires, Cables, and Flexible Cords). Classifications From lowest (Least flame-retardant) to highest (Most flame-retardant): *HB: slow burning on a horizontal specimen; burning rate < 76 mm/min for thickness < 3 mm or burning stops before 100 mm *V-2: burning stops within 30 seconds on a vertical specimen; drips of flaming particles are allowed. *V-1: burning stops within 30 seconds ...
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Aluminium Diethyl Phosphinate
Aluminium diethyl phosphinate is a chemical compound with formula Al()3. It decomposes above 300 °C. Applications In the family of dialkyl phosphinic acid salts, aluminium diethyl phosphinate has been found to be an excellent flame retardant for use in engineering plastics such as polyamides, polyesters, thermosets and elastomers. It was developed by Hoechst, later by Clariant chemicals and Ticona. In 2004 and 2012, Clariant chemicals opened its first and second commercial production lines respectively in Huerth-Knapsack near Cologne. Aluminium diethyl phosphinate acts as a flame retardant in the condensed phase in contributing to charring of the polymer matrix and thus protecting the substrate against heat and oxygen attack. In parallel it acts in the gas phase by radical reactions removing from the combustion zone the high energy radicals H. and OH., which determine flame propagation and heat release. The phosphinate partly vaporises and partly decomposes to volatile d ...
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Fire-safe Polymers
Fire-safe polymers are polymers that are resistant to degradation at high temperatures. There is need for fire-resistant polymers in the construction of small, enclosed spaces such as skyscrapers, boats, and airplane cabins.Zhang, H. ''Fire-Safe Polymers and Polymer Composites,'' Federal Aviation Administration technical report; U.S. Department of Transportation: Washington, D.C., 2004. In these tight spaces, ability to escape in the event of a fire is compromised, increasing fire risk. In fact, some studies report that about 20% of victims of airplane crashes are killed not by the crash itself but by ensuing fires.Sarkos, C. P. The Effect of Cabin Materials on Aircraft Postcrash Fire Survivability. ''Technical Papers of the Annual Technical Conference'' 1996, ''54'' (3), 3068-3071. Fire-safe polymers also find application as adhesives in aerospace materials,Kumar, D.; Gupta, A. D.; Khullar, M. Heat-resistant thermosetting polymers based on a novel tetrakisaminophenoxycyclotriphospha ...
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Fiberglass
Fiberglass (American English) or fibreglass (Commonwealth English) is a common type of fiber-reinforced plastic using glass fiber. The fibers may be randomly arranged, flattened into a sheet called a chopped strand mat, or woven into glass cloth. The plastic matrix may be a thermoset polymer matrix—most often based on thermosetting polymers such as epoxy, polyester resin, or vinyl ester resin—or a thermoplastic. Cheaper and more flexible than carbon fiber, it is stronger than many metals by weight, non- magnetic, non-conductive, transparent to electromagnetic radiation, can be molded into complex shapes, and is chemically inert under many circumstances. Applications include aircraft, boats, automobiles, bath tubs and enclosures, swimming pools, hot tubs, septic tanks, water tanks, roofing, pipes, cladding, orthopedic casts, surfboards, and external door skins. Other common names for fiberglass are glass-reinforced plastic (GRP), glass-fiber reinforced plastic (GFRP) or GF ...
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Guitar
The guitar is a fretted musical instrument that typically has six strings. It is usually held flat against the player's body and played by strumming or plucking the strings with the dominant hand, while simultaneously pressing selected strings against frets with the fingers of the opposite hand. A plectrum or individual finger picks may also be used to strike the strings. The sound of the guitar is projected either acoustically, by means of a resonant chamber on the instrument, or amplified by an electronic pickup and an amplifier. The guitar is classified as a chordophone – meaning the sound is produced by a vibrating string stretched between two fixed points. Historically, a guitar was constructed from wood with its strings made of catgut. Steel guitar strings were introduced near the end of the nineteenth century in the United States; nylon strings came in the 1940s. The guitar's ancestors include the gittern, the vihuela, the four- course Renaissance guitar, and the ...
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