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Napalm
Napalm is an incendiary mixture of a gelling agent and a volatile petrochemical (usually gasoline (petrol) or diesel fuel). The name is a portmanteau of two of the constituents of the original thickening and gelling agents: coprecipitated aluminium salts of naphthenic acid and palmitic acid. Napalm B is the more modern version of napalm (utilizing polystyrene derivatives) and, although distinctly different in its chemical composition, is often referred to simply as "napalm". A team led by chemist Louis Fieser originally developed napalm for the US Chemical Warfare Service in 1942 in a secret laboratory at Harvard University. Of immediate first interest was its viability as an incendiary device to be used in fire bombing campaigns during World War II; its potential to be coherently projected into a solid stream that would carry for distance (instead of the bloomy fireball of pure gasoline) resulted in widespread adoption in infantry flamethrowers as well. Napalm burns at temp ...
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Incendiary Device
Incendiary weapons, incendiary devices, incendiary munitions, or incendiary bombs are weapons designed to start fires or destroy sensitive equipment using fire (and sometimes used as anti-personnel weaponry), that use materials such as napalm, thermite, magnesium powder, chlorine trifluoride, or white phosphorus. Though colloquially often known as bombs, they are not explosives but in fact are designed to slow the process of chemical reactions and use ignition rather than detonation to start or maintain the reaction. Napalm for example, is petroleum especially thickened with certain chemicals into a 'gel' to slow, but not stop, combustion, releasing energy over a longer time than an explosive device. In the case of napalm, the gel adheres to surfaces and resists suppression. Pre-modern history A range of early thermal weapons were utilized by ancient, medieval/post-classical and early modern armies, including hot pitch, oil, resin, animal fat and other similar compounds. Subs ...
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Incendiary Device
Incendiary weapons, incendiary devices, incendiary munitions, or incendiary bombs are weapons designed to start fires or destroy sensitive equipment using fire (and sometimes used as anti-personnel weaponry), that use materials such as napalm, thermite, magnesium powder, chlorine trifluoride, or white phosphorus. Though colloquially often known as bombs, they are not explosives but in fact are designed to slow the process of chemical reactions and use ignition rather than detonation to start or maintain the reaction. Napalm for example, is petroleum especially thickened with certain chemicals into a 'gel' to slow, but not stop, combustion, releasing energy over a longer time than an explosive device. In the case of napalm, the gel adheres to surfaces and resists suppression. Pre-modern history A range of early thermal weapons were utilized by ancient, medieval/post-classical and early modern armies, including hot pitch, oil, resin, animal fat and other similar compounds. Subs ...
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Louis Fieser
Louis Frederick Fieser (April 7, 1899 – July 25, 1977) was an American organic chemist, professor, and in 1968, professor emeritus at Harvard University. He is known for inventing military effective napalm whilst he worked at Harvard in 1942. His award-winning research included work on blood-clotting agents including the first synthesis of vitamin K, synthesis and screening of quinones as antimalarial drugs, work with steroids leading to the synthesis of cortisone, and study of the nature of polycyclic aromatic hydrocarbons. Overview Fieser was born in Columbus, Ohio, obtained his BA in chemistry in 1920 from Williams College, and his PhD under James Bryant Conant at Harvard in 1924. His graduate research concerned the measurement of oxidation potentials in quinone oxidation. Note: nice anecdote in supplementary info in 1924-1925 Fieser worked at the University of Oxford with W.H. Perkin Jr. and with Julius von Braun at the Frankfurt University as a postdoc. Between 192 ...
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Flamethrower
A flamethrower is a ranged incendiary device designed to project a controllable jet of fire. First deployed by the Byzantine Empire in the 7th century AD, flamethrowers saw use in modern times during World War I, and more widely in World War II as a tactical siege weapon against fortifications. Most military flamethrowers use liquid fuel, typically either gasoline or diesel, but commercial flamethrowers are generally blowtorches using gaseous fuels such as propane; gases are safer in peacetime applications, because their flames have less mass flow rate and dissipate faster, and often are easier to extinguish when necessary. The military use of flamethrowers is restricted through the Protocol on Incendiary Weapons. Apart from the military applications, flamethrowers have peacetime applications where there is a need for controlled burning, such as in sugarcane harvesting and other land-management tasks. Various forms are designed for an operator to carry, while others a ...
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US Chemical Warfare Service
The Chemical Corps is the branch of the United States Army tasked with defending against chemical, biological, radiological, and nuclear (CBRN) weapons. The Chemical Warfare Service was established on 28 June 1918, combining activities that until then had been dispersed among five separate agencies of the United States federal government. It was made a permanent branch of the Regular Army by the National Defense Act of 1920. In 1945, it was redesignated the Chemical Corps. History Origins Discussion of the topic dates back to the American Civil War. A letter to the War Department dated 5 April 1862 from New York City resident John Doughty proposed the use of chlorine shells to drive the Confederate Army from its positions. Doughty included a detailed drawing of the shell with his letter. It is unknown how the military reacted to Doughty's proposal but the letter was unnoticed in a pile of old official documents until modern times. Another American, Forrest Shepherd, also propose ...
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Flamethrowers
A flamethrower is a ranged incendiary device designed to project a controllable jet of fire. First deployed by the Byzantine Empire in the 7th century AD, flamethrowers saw use in modern times during World War I, and more widely in World War II as a tactical siege weapon against fortifications. Most military flamethrowers use liquid fuel, typically either gasoline or diesel, but commercial flamethrowers are generally blowtorches using gaseous fuels such as propane; gases are safer in peacetime applications, because their flames have less mass flow rate and dissipate faster, and often are easier to extinguish when necessary. The military use of flamethrowers is restricted through the Protocol on Incendiary Weapons. Apart from the military applications, flamethrowers have peacetime applications where there is a need for controlled burning, such as in sugarcane harvesting and other land-management tasks. Various forms are designed for an operator to carry, while others are ...
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Palmitic Acid
Palmitic acid (hexadecanoic acid in IUPAC nomenclature) is a fatty acid with a 16-carbon chain. It is the most common saturated fatty acid found in animals, plants and microorganisms.Gunstone, F. D., John L. Harwood, and Albert J. Dijkstra. The Lipid Handbook, 3rd ed. Boca Raton: CRC Press, 2007. , Its chemical formula is CH3(CH2)14COOH, and its C:D (the total number of carbon atoms to the number of carbon-carbon double-bonds) is 16:0. It is a major component of the oil from the fruit of oil palms ( palm oil), making up to 44% of total fats. Meats, cheeses, butter, and other dairy products also contain palmitic acid, amounting to 50–60% of total fats. Palmitates are the salts and esters of palmitic acid. The palmitate anion is the observed form of palmitic acid at physiologic pH (7.4). Occurrence and production Palmitic acid was discovered by Edmond Frémy in 1840, in saponified palm oil. This remains the primary industrial route for its production, with the triglycerides (fa ...
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Korean War
, date = {{Ubl, 25 June 1950 – 27 July 1953 (''de facto'')({{Age in years, months, weeks and days, month1=6, day1=25, year1=1950, month2=7, day2=27, year2=1953), 25 June 1950 – present (''de jure'')({{Age in years, months, weeks and days, month1=6, day1=25, year1=1950) , place = Korean Peninsula, Yellow Sea, Sea of Japan, Korea Strait, China–North Korea border , territory = Korean Demilitarized Zone established * North Korea gains the city of Kaesong, but loses a net total of {{Convert, 1506, sqmi, km2, abbr=on, order=flip, including the city of Sokcho, to South Korea. , result = Inconclusive , combatant1 = {{Flag, First Republic of Korea, name=South Korea, 1949, size=23px , combatant1a = {{Plainlist , * {{Flagicon, United Nations, size=23px United Nations Command, United Nations{{Refn , name = nbUNforces , group = lower-alpha , On 9 July 1951 troop constituents were: US: 70.4%, ROK: 23.3% other UNC: 6.3%{{Cite ...
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Vietnam War
The Vietnam War (also known by #Names, other names) was a conflict in Vietnam, Laos, and Cambodia from 1 November 1955 to the fall of Saigon on 30 April 1975. It was the second of the Indochina Wars and was officially fought between North Vietnam and South Vietnam. The north was supported by the Soviet Union, China, and other communist states, while the south was United States in the Vietnam War, supported by the United States and other anti-communism, anti-communist Free World Military Forces, allies. The war is widely considered to be a Cold War-era proxy war. It lasted almost 20 years, with direct U.S. involvement ending in 1973. The conflict also spilled over into neighboring states, exacerbating the Laotian Civil War and the Cambodian Civil War, which ended with all three countries becoming communist states by 1975. After the French 1954 Geneva Conference, military withdrawal from Indochina in 1954 – following their defeat in the First Indochina War – the Viet Minh to ...
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Fire Bombing
Firebombing is a bombing technique designed to damage a target, generally an urban area, through the use of fire, caused by incendiary devices, rather than from the blast effect of large bombs. In popular usage, any act in which an incendiary device is used to initiate a fire is often described as a "firebombing". This article is concerned with aerial incendiary bombing as a military tactic; for non-military (almost always criminal) acts, see ''arson''. Although simple incendiary bombs have been used to destroy buildings since the start of gunpowder warfare, World War I saw the first use of strategic bombing from the air to damage the morale and economy of the enemy, such as the German Zeppelin air raids conducted on London during the Great War. The Chinese wartime capital of Chongqing was firebombed by the Imperial Japanese starting in early 1939. London, Coventry, and many other British cities were firebombed during the Blitz by Germany. Most large German cities were extensiv ...
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Naphthenic Acid
Naphthenic acids (NAs) are a mixture of several cyclopentyl and cyclohexyl carboxylic acids with molecular weight of 120 to well over 700 atomic mass units. The main fraction are carboxylic acids with a carbon backbone of 9 to 20 carbons. McKee et al. claim that "naphthenic acids (NAs) are primarily cycloaliphatic carboxylic acids with 10 to 16 carbons" .html" ;"title="/sup>">/sup>, although acids containing up to 50 carbons have been identified in heavy petroleum.Qian, K. and W.K. Robbins (2001). Resolution and identification of elemental compositions for more than 3000 crude acids in heavy petroleum by negative-ion microelectrospray high-field Fourier Transform ion cyclotron resonance mass spectrometry. ''Energy & Fuels.'' 15:1505-1511. The term naphthenic acid has roots in the somewhat archaic term "naphthene" (cycloaliphatic but non-aromatic) used to classify hydrocarbons. It was originally used to describe the complex mixture of petroleum-based acids when the analytical method ...
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Air Raids On Japan
Air raids conducted by Allied forces on Japan during World War II caused extensive destruction to the country's cities and killed between 241,000 and 900,000 people. During the first years of the Pacific War these attacks were limited to the Doolittle Raid in April 1942 and small-scale raids on military positions in the Kuril Islands from mid-1943. Strategic bombing raids began in June 1944 and continued until the end of the war in August 1945. Allied naval and land-based tactical air units also attacked Japan during 1945. The United States military air campaign waged against Japan began in earnest in mid-1944 and intensified during the war's last months. While plans for attacks on Japan had been prepared prior to the Pacific War, these could not begin until the long-range B-29 Superfortress bomber was ready for combat. From June 1944 until January 1945, B-29s stationed in India staged through bases in China to make a series of nine raids on targets in western Japan, but this ...
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