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Myricanone
Myricanone is a cyclic diarylheptanoid isolated from the bark of ''Myrica rubra ''Myrica rubra'', also called yangmei (; Cantonese: yeung4 mui4; Shanghainese: ), , Chinese bayberry, red bayberry, yumberry, waxberry, or Chinese strawberry (and often mistranslated from Chinese as arbutus) is a subtropical tree grown for its f ...'' (Myricaceae). References Diarylheptanoids Macrocycles O-methylated natural phenols Cyclophanes Ketones Biphenyls {{aromatic-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Diarylheptanoid
The diarylheptanoids (also known as diphenylheptanoids) are a relatively small class of plant secondary metabolites. Diarylheptanoids consist of two aromatic rings (aryl groups) joined by a seven carbons chain (heptane) and having various substituents. They can be classified into linear ( curcuminoids) and cyclic diarylheptanoids. The best known member is curcumin, which is isolated from turmeric (''Curcuma longa'') and is known as food coloring E100. Some other ''Curcuma'' species, such as ''Curcuma comosa'' also produce diarylheptanoids. They have been reported from plants in 10 different families, e.g. ''Betulaceae'' and ''Zingiberaceae''. A diarylheptanoid is an intermediate in the biosynthesis of phenylphenalenones in '' Anigozanthos preissii'' or ''Wachendorfia thyrsiflora'' (Haemodoraceae). Cyclic diarylheptanoids Cyclic diarylheptanoids formed from myricanone can be isolated from the bark of ''Myrica rubra'' (Myricaceae). Two cyclic diarylheptanoids, named ostryopsitr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Diarylheptanoids
The diarylheptanoids (also known as diphenylheptanoids) are a relatively small class of plant secondary metabolites. Diarylheptanoids consist of two aromatic rings (aryl groups) joined by a seven carbons chain (heptane) and having various substituents. They can be classified into linear (curcuminoids) and cyclic diarylheptanoids. The best known member is curcumin, which is isolated from turmeric (''Curcuma longa'') and is known as food coloring E100. Some other ''Curcuma'' species, such as ''Curcuma comosa'' also produce diarylheptanoids. They have been reported from plants in 10 different families, e.g. ''Betulaceae'' and ''Zingiberaceae''. A diarylheptanoid is an intermediate in the biosynthesis of phenylphenalenones in '' Anigozanthos preissii'' or '' Wachendorfia thyrsiflora'' (Haemodoraceae). Cyclic diarylheptanoids Cyclic diarylheptanoids formed from myricanone can be isolated from the bark of ''Myrica rubra'' (Myricaceae). Two cyclic diarylheptanoids, named ostryopsitr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Myrica Rubra
''Myrica rubra'', also called yangmei (; Cantonese: yeung4 mui4; Shanghainese: ), , Chinese bayberry, red bayberry, yumberry, waxberry, or Chinese strawberry (and often mistranslated from Chinese as arbutus) is a subtropical tree grown for its fruit. Description ''Myrica rubra'' is an evergreen tree that grows to a height of up to high, with smooth gray bark and a uniform spherical to hemispherical crown. Leaves are leathery, bare, elliptic-obovate to oval lanceolate in shape, wedge-shaped at the base and rounded to pointed or tapered at the apex, margin is serrated or serrated in the upper half, with a length of and a width of . Leaves are alternately arranged on the branches are divided into petiole and leaf blade. The petiole is long. The leaf underside is pale green and sparsely to moderately golden glandular, the top surface is dark green. The species is dioecious. Male flowers with simple or unobtrusively branched bracts, are held in inflorescences individually or occa ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Macrocycles
Macrocycles are often described as molecules and ions containing a ring of twelve or more atoms. Classical examples include the crown ethers, calixarenes, porphyrins, and cyclodextrins. Macrocycles describe a large, mature area of chemistry. Synthesis The formation of macrocycles by ring-closure is called macrocylization. Pioneering work was reported for studies on terpenoid macrocycles. The central challenge to macrocyclization is that ring-closing reactions do not favor the formation of large rings. Instead, small rings or polymers tend to form. This kinetic problem can be addressed by using high-dilution reactions, whereby intramolecular processes are favored relative to polymerizations. Some macrocyclizations are favored using template reactions. Templates are ions, molecules, surfaces etc. that bind and pre-organize compounds, guiding them toward formation of a particular ring size. The crown ethers are often generated in the presence of an alkali metal cation ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ketones
In organic chemistry, a ketone is a functional group with the structure R–C(=O)–R', where R and R' can be a variety of carbon-containing substituents. Ketones contain a carbonyl group –C(=O)– (which contains a carbon-oxygen double bond C=O). The simplest ketone is acetone (where R and R' is methyl), with the formula . Many ketones are of great importance in biology and in industry. Examples include many sugars ( ketoses), many steroids (e.g., testosterone), and the solvent acetone. Nomenclature and etymology The word ''ketone'' is derived from ''Aketon'', an old German word for ''acetone''. According to the rules of IUPAC nomenclature, ketone names are derived by changing the suffix ''-ane'' of the parent alkane to ''-anone''. Typically, the position of the carbonyl group is denoted by a number, but traditional nonsystematic names are still generally used for the most important ketones, for example acetone and benzophenone. These nonsystematic names are considered ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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