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Multiferroic
Multiferroics are defined as materials that exhibit more than one of the primary ferroic properties in the same phase: * ferromagnetism – a magnetisation that is switchable by an applied magnetic field * ferroelectricity – an electric polarisation that is switchable by an applied electric field * ferroelasticity – a deformation that is switchable by an applied stress While ferroelectric ferroelastics and ferromagnetic ferroelastics are formally multiferroics, these days the term is usually used to describe the ''magnetoelectric multiferroics'' that are simultaneously ferromagnetic and ferroelectric. Sometimes the definition is expanded to include nonprimary order parameters, such as antiferromagnetism or ferrimagnetism. In addition, other types of primary order, such as ferroic arrangements of magnetoelectric multipoles of which ferrotoroidicity is an example, have also been recently proposed. Besides scientific interest in their physical properties, multiferroics have pote ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Multiferroics History Use Of Terms Magnetoelectric And Multiferroic
Multiferroics are defined as materials that exhibit more than one of the primary Ferroics, ferroic properties in the same phase: * ferromagnetism – a magnetisation that is switchable by an applied magnetic field * ferroelectricity – an electric polarisation that is switchable by an applied electric field * ferroelasticity – a deformation that is switchable by an applied stress While ferroelectric ferroelastics and ferromagnetic ferroelastics are formally multiferroics, these days the term is usually used to describe the ''Magnetoelectric effect#cite note-5, magnetoelectric multiferroics'' that are simultaneously ferromagnetic and ferroelectric. Sometimes the definition is expanded to include nonprimary order parameters, such as antiferromagnetism or ferrimagnetism. In addition, other types of primary order, such as ferroic arrangements of magnetoelectric multipoles of which Toroidal moment, ferrotoroidicity is an example, have also been recently proposed. Besides scientific in ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Magnetoelectric Effect
In its most general form, the magnetoelectric effect (ME) denotes any coupling between the magnetic and the electric properties of a material. The first example of such an effect was described by Wilhelm Röntgen in 1888, who found that a dielectric material moving through an electric field would become magnetized. A material where such a coupling is intrinsically present is called a magnetoelectric. Historically, the first and most studied example of this effect is the linear magnetoelectric effect. Mathematically, while the electric susceptibility \chi^e and magnetic susceptibility \chi^v describe the electric and magnetic polarization responses to an electric, resp. a magnetic field, there is also the possibility of a magnetoelectric susceptibility \alpha_ which describes a linear response of the electric polarization to a magnetic field, and vice versa: :P_i= \sum_j \epsilon_0\chi^e_ E_ + \sum_j \alpha_H_j :\mu_0 M_i= \sum_j \mu_0\chi^v_H_ + \sum_j \alpha_E_j, The tensor \alpha ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bismuth Ferrite
Bismuth ferrite (BiFeO3, also commonly referred to as BFO in materials science) is an inorganic chemical compound with perovskite structure and one of the most promising multiferroic materials. The room-temperature phase of BiFeO3 is classed as rhombohedral belonging to the space group R3c. It is synthesized in bulk and thin film form and both its antiferromagnetic (G type ordering) Néel temperature (approximately 653 K) and ferroelectric Curie temperature are well above room temperature (approximately 1100K). Ferroelectric polarization occurs along the pseudocubic direction (\langle 111\rangle_c) with a magnitude of 90–95 μC/cm2. Sample Preparation Bismuth ferrite is not a naturally occurring mineral and several synthesis routes to obtain the compound have been developed. Solid state synthesis In the solid state reaction method bismuth oxide (Bi2O3) and iron oxide (Fe2O3) in a 1:1 mole ratio are mixed with a mortar or by ball milling and then fired at elevated te ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bismuth Ferrite
Bismuth ferrite (BiFeO3, also commonly referred to as BFO in materials science) is an inorganic chemical compound with perovskite structure and one of the most promising multiferroic materials. The room-temperature phase of BiFeO3 is classed as rhombohedral belonging to the space group R3c. It is synthesized in bulk and thin film form and both its antiferromagnetic (G type ordering) Néel temperature (approximately 653 K) and ferroelectric Curie temperature are well above room temperature (approximately 1100K). Ferroelectric polarization occurs along the pseudocubic direction (\langle 111\rangle_c) with a magnitude of 90–95 μC/cm2. Sample Preparation Bismuth ferrite is not a naturally occurring mineral and several synthesis routes to obtain the compound have been developed. Solid state synthesis In the solid state reaction method bismuth oxide (Bi2O3) and iron oxide (Fe2O3) in a 1:1 mole ratio are mixed with a mortar or by ball milling and then fired at elevated te ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nicola Spaldin
Nicola Ann Spaldin (born 1969)Nicola Spaldin's FRS is Professor of Materials Theory at ETH Zurich, known for her pioneering research on multiferroics. Education and early life A native of Sunderland, Tyne and Wear, England, Spaldin earned a Bachelor of Arts degree in Natural Sciences from the University of Cambridge in 1991, and a PhD in chemistry from the University of California, Berkeley in 1996. retrieved 2015-06-16. Career and research Spaldin was inspired to search for multiferroics, magnetic ferroelectric materials, by a remark about potential collaboration made by a colleague studying ferroelectrics during her postdoctoral research studying magnetic phenomena at Yale University from 1996 to 1997. She continued to develop the theory of these materials as a new faculty member at the University of California, Santa Barbara (UCSB), and in 2000 published (under her previous name, Hill) "a seminal article" that for the first time explained why few such materials were know ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ferroelectrics (journal)
Ferroelectricity is a characteristic of certain materials that have a spontaneous electric polarization that can be reversed by the application of an external electric field. All ferroelectrics are also piezoelectric and pyroelectric, with the additional property that their natural electrical polarization is reversible. The term is used in analogy to ferromagnetism, in which a material exhibits a permanent magnetic moment. Ferromagnetism was already known when ferroelectricity was discovered in 1920 in Rochelle salt by Joseph Valasek.See and Thus, the prefix ''ferro'', meaning iron, was used to describe the property despite the fact that most ferroelectric materials do not contain iron. Materials that are both ferroelectric ''and'' ferromagnetic are known as multiferroics. Polarization When most materials are electrically polarized, the polarization induced, ''P'', is almost exactly proportional to the applied external electric field ''E''; so the polarization is a linear fun ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ferroelectricity
Ferroelectricity is a characteristic of certain materials that have a spontaneous electric polarization that can be reversed by the application of an external electric field. All ferroelectrics are also piezoelectric and pyroelectric, with the additional property that their natural electrical polarization is reversible. The term is used in analogy to ferromagnetism, in which a material exhibits a permanent magnetic moment. Ferromagnetism was already known when ferroelectricity was discovered in 1920 in Rochelle salt by Joseph Valasek.See and Thus, the prefix ''ferro'', meaning iron, was used to describe the property despite the fact that most ferroelectric materials do not contain iron. Materials that are both ferroelectric ''and'' ferromagnetic are known as multiferroics. Polarization When most materials are electrically polarized, the polarization induced, ''P'', is almost exactly proportional to the applied external electric field ''E''; so the polarization is a linear fun ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
T-symmetry
T-symmetry or time reversal symmetry is the theoretical symmetry of physical laws under the transformation of time reversal, : T: t \mapsto -t. Since the second law of thermodynamics states that entropy increases as time flows toward the future, in general, the macroscopic universe does not show symmetry under time reversal. In other words, time is said to be non-symmetric, or asymmetric, except for special equilibrium states when the second law of thermodynamics predicts the time symmetry to hold. However, quantum noninvasive measurements are predicted to violate time symmetry even in equilibrium, contrary to their classical counterparts, although this has not yet been experimentally confirmed. Time ''asymmetries'' generally are caused by one of three categories: # intrinsic to the dynamic physical law (e.g., for the weak force) # due to the initial conditions of the universe (e.g., for the second law of thermodynamics) # due to measurements (e.g., for the noninvasive measur ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spintronic
Spintronics (a portmanteau meaning spin transport electronics), also known as spin electronics, is the study of the intrinsic spin of the electron and its associated magnetic moment, in addition to its fundamental electronic charge, in solid-state devices. The field of spintronics concerns spin-charge coupling in metallic systems; the analogous effects in insulators fall into the field of multiferroics. Spintronics fundamentally differs from traditional electronics in that, in addition to charge state, electron spins are exploited as a further degree of freedom, with implications in the efficiency of data storage and transfer. Spintronic systems are most often realised in dilute magnetic semiconductors (DMS) and Heusler alloys and are of particular interest in the field of quantum computing and neuromorphic computing. History Spintronics emerged from discoveries in the 1980s concerning spin-dependent electron transport phenomena in solid-state devices. This includes the observ ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Piezoresponse Force Microscopy
Piezoresponse force microscopy (PFM) is a variant of atomic force microscopy (AFM) that allows imaging and manipulation of piezoelectric/ferroelectric materials domains. This is achieved by bringing a sharp conductive probe into contact with a ferroelectric surface (or piezoelectric material) and applying an alternating current (AC) bias to the probe tip in order to excite deformation of the sample through the converse piezoelectric effect (CPE). The resulting deflection of the probe cantilever is detected through standard split photodiode detector methods and then demodulated by use of a lock-in amplifier (LiA). In this way topography and ferroelectric domains can be imaged simultaneously with high resolution. Basic principles General overview Piezoresponse force microscopy is a technique which since its inception and first implementation by Güthner and Dransfeld has steadily attracted more and more interest. This is due in large part to the many benefits and few drawbacks that ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Perovskite (structure)
A perovskite is any material with a crystal structure following the formula ABX3, which was first discovered as the mineral called perovskite, which consists of calcium titanium oxide (CaTiO3). The mineral was first discovered in the Ural mountains of Russia by Gustav Rose in 1839 and named after Russian mineralogist L. A. Perovski (1792–1856). 'A' and 'B' are two positively charged ions (i.e. cations), often of very different sizes, and X is a negatively charged ion (an anion, frequently oxide) that bonds to both cations. The 'A' atoms are generally larger than the 'B' atoms. The ideal cubic structure has the B cation in 6-fold coordination, surrounded by an octahedron of anions, and the A cation in 12-fold cuboctahedral coordination. Additional perovskite forms may exist where either/both the A and B sites have a configuration of A1x-1A2x and/or B1y-1B2y and the X may deviate from the ideal coordination configuration as ions within the A and B sites undergo changes in thei ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Barium Titanate
Barium titanate (BTO) is an inorganic compound with chemical formula BaTiO3. Barium titanate appears white as a powder and is transparent when prepared as large crystals. It is a Ferroelectricity, ferroelectric, Pyroelectricity, pyroelectric, and Piezoelectricity, piezoelectric ceramic material that exhibits the photorefractive effect. It is used in capacitors, electromechanical transducers and nonlinear optics. Structure The solid exists in one of four polymorphs depending on temperature. From high to low temperature, these crystal symmetries of the four polymorphs are Cubic crystal system, cubic, Tetragonal crystal system, tetragonal, Orthorhombic crystal system, orthorhombic and Trigonal crystal system, rhombohedral crystal structure. All of these phases exhibit the ferroelectric effect apart from the cubic phase. The high temperature cubic phase is easiest to describe, as it consists of regular corner-sharing octahedral TiO6 units that define a cube with O vertices and Ti- ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
