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Mixing Ratio
In chemistry and physics, the dimensionless mixing ratio is the abundance of one component of a mixture relative to that of all other components. The term can refer either to mole ratio (see concentration) or mass ratio (see stoichiometry). In atmospheric chemistry and meteorology Mole ratio In atmospheric chemistry, mixing ratio usually refers to the mole ratio ''ri'', which is defined as the amount of a constituent ''ni'' divided by the total amount of all ''other'' constituents in a mixture: :r_i = \frac The mole ratio is also called amount ratio. If ''ni'' is much smaller than ''n''tot (which is the case for atmospheric trace constituents), the mole ratio is almost identical to the mole fraction. Mass ratio In meteorology, mixing ratio usually refers to the mass ratio of water \zeta, which is defined as the mass of water m_\mathrm divided by the mass of dry air (m_\mathrm-m_\mathrm) in a given air parcel: :\zeta = \frac The unit is typically given in \mathrm\,\mathrm^. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemistry
Chemistry is the scientific study of the properties and behavior of matter. It is a physical science within the natural sciences that studies the chemical elements that make up matter and chemical compound, compounds made of atoms, molecules and ions: their composition, structure, properties, behavior and the changes they undergo during chemical reaction, reactions with other chemical substance, substances. Chemistry also addresses the nature of chemical bonds in chemical compounds. In the scope of its subject, chemistry occupies an intermediate position between physics and biology. It is sometimes called the central science because it provides a foundation for understanding both Basic research, basic and Applied science, applied scientific disciplines at a fundamental level. For example, chemistry explains aspects of plant growth (botany), the formation of igneous rocks (geology), how atmospheric ozone is formed and how environmental pollutants are degraded (ecology), the prop ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ideal Solution
An ideal solution or ideal mixture is a solution that exhibits thermodynamic properties analogous to those of a mixture of ideal gases. The enthalpy of mixing is zero as is the volume change on mixing. The vapor pressures of all components obey Raoult's law across the entire range of concentrations, and the activity coefficient (which measures deviation from ideality) is equal to one for each component. The concept of an ideal solution is fundamental to both thermodynamics and chemical thermodynamics and their applications, such as the explanation of colligative properties. Physical origin Ideality of solutions is analogous to ideality for gases, with the important difference that intermolecular interactions in liquids are strong and cannot simply be neglected as they can for ideal gases. Instead we assume that the mean strength of the interactions are the same between all the molecules of the solution. More formally, for a mix of molecules of A and B, then the interacti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Amide
In organic chemistry, an amide, also known as an organic amide or a carboxamide, is a chemical compound, compound with the general formula , where R, R', and R″ represent any group, typically organyl functional group, groups or hydrogen atoms. The amide group is called a peptide bond when it is part of the Polymer backbone, main chain of a protein, and an isopeptide bond when it occurs in a side chain, as in asparagine and glutamine. It can be viewed as a Derivative (chemistry), derivative of a carboxylic acid () with the hydroxyl group () replaced by an amino group (); or, equivalently, an acyl group, acyl (alkanoyl) group () joined to an amino group. Common amides are formamide (), acetamide (), benzamide (), and dimethylformamide (). Some uncommon examples of amides are ''N''-chloroacetamide () and chloroformamide (). Amides are qualified as primary (chemistry), primary, secondary (chemistry), secondary, and tertiary (chemistry), tertiary according to the number of acyl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ammonium
Ammonium is a modified form of ammonia that has an extra hydrogen atom. It is a positively charged (cationic) polyatomic ion, molecular ion with the chemical formula or . It is formed by the protonation, addition of a proton (a hydrogen nucleus) to ammonia (). Ammonium is also a general name for positively charged (protonated) substituted amines and quaternary ammonium cations (), where one or more hydrogen atoms are replaced by Organic compound, organic or other groups (indicated by R). Not only is ammonium a source of nitrogen and a key metabolite for many living organisms, but it is an integral part of the global nitrogen cycle. As such, human impact in recent years could have an effect on the biological communities that depend on it. Acid–base properties The ammonium ion is generated when ammonia, a weak base, reacts with Brønsted–Lowry acid–base theory, Brønsted acids (proton donors): : The ammonium ion is mildly acidic, reacting with Brønsted bases to return ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alkoxide
In chemistry, an alkoxide is the conjugate base of an alcohol and therefore consists of an organic group bonded to a negatively charged oxygen atom. They are written as , where R is the organyl substituent. Alkoxides are strong bases and, when R is not bulky, good nucleophiles and good ligands. Alkoxides, although generally not stable in protic solvents such as water, occur widely as intermediates in various reactions, including the Williamson ether synthesis.excerpt Transition metal alkoxides are widely used for coatings and as catalysts. Enolates are unsaturated alkoxides derived by deprotonation of a bond adjacent to a ketone or aldehyde. The nucleophilic center for simple alkoxides is located on the oxygen, whereas the nucleophilic site on enolates is delocalized onto both carbon and oxygen sites. Ynolates are also unsaturated alkoxides derived from acetylenic alcohols. Phenoxides are close relatives of the alkoxides, in which the alkyl group is replaced by a phe ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydroxide
Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical. The corresponding electrically neutral compound HO• is the hydroxyl radical. The corresponding covalently bound group of atoms is the hydroxy group. Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry. Many inorganic substances which bear the word ''hydroxide'' in their names are not ionic compounds of the hydroxide ion, but covalent compounds which contain hydroxy groups. Hydroxide ion The hydroxide ion is naturally produced ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydronium
In chemistry, hydronium (hydroxonium in traditional British English) is the cation , also written as , the type of oxonium ion produced by protonation of water. It is often viewed as the positive ion present when an Arrhenius acid is dissolved in water, as Arrhenius acid molecules in solution give up a proton (a positive hydrogen ion, ) to the surrounding water molecules (). In fact, acids must be surrounded by more than a single water molecule in order to ionize, yielding aqueous and conjugate base. Three main structures for the aqueous proton have garnered experimental support: * the Eigen cation, which is a tetrahydrate, H3O+(H2O)3 * the Zundel cation, which is a symmetric dihydrate, H+(H2O)2 * and the Stoyanov cation, an expanded Zundel cation, which is a hexahydrate: H+(H2O)2(H2O)4 Spectroscopic evidence from well-defined IR spectra overwhelmingly supports the Stoyanov cation as the predominant form. For this reason, it has been suggested that wherever possible, the sy ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Grotthuss Mechanism
The Grotthuss mechanism (also known as proton jumping) is a model for the process by which an 'excess' proton diffuses through the hydrogen bond network of water molecules or other hydrogen-bonded liquids through the formation and concomitant cleavage of covalent bonds involving neighboring molecules. In his 1806 publication “Theory of decomposition of liquids by electrical currents”, Theodor Grotthuss proposed a theory of water conductivity. Grotthuss envisioned the electrolytic reaction as a sort of ‘bucket line’ where each oxygen atom simultaneously passes and receives a single hydrogen ion. It was an astonishing theory to propose at the time, since the water molecule was thought to be OH, not H2O, and the existence of ions was not fully understood. On its 200th anniversary, his article was reviewed by Cukierman. Although Grotthuss was using an incorrect empirical formula of water, his description of the passing of protons through the cooperation of neighboring water m ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molecular Autoionization
In chemistry, molecular autoionization (or self-ionization) is a chemical reaction between molecules of the same substance to produce ions. If a pure liquid partially dissociates into ions, it is said to be self-ionizing. In most cases the oxidation number on all atoms in such a reaction remains unchanged. Such autoionization can be '' protic'' ( transfer), or ''non-protic''. Examples Protic solvents Protic solvents often undergo some autoionization (in this case autoprotolysis): *2 H2O H3O+ + OH- **The self-ionization of water is particularly well studied, due to its implications for acid-base chemistry of aqueous solutions. *2 NH3 NH4+ + NH2- *2 H2SO4 H3SO4+ + HSO4- *3 HF H2F+ + HF2- **Here proton transfer between two HF combines with homoassociation of and a third HF to form Non-protic solvents *2 PF5 PF6- + PF4+ *N2O4 NO+ + NO3- ** Here the nitrogen oxidation numbers change from (+4 and +4) to (+3 and +5). *2 BrF3 BrF2+ + BrF4- These solvents al ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lyate Ion
In chemistry, a lyate ion is the anion derived by the deprotonation of a solvent molecule. For example, a hydroxide ion is formed by the deprotonation of water, and methoxide () is the anion formed by the deprotonation of methanol. Its counterpart is a lyonium ion, the cation formed by the protonation of a solvent molecule. Lyonium and lyate ions, resulting from molecular autoionization, contribute to the molar conductivity of protolytic solvents. Examples See also * Lyonium ion, a protonated solvent molecule *Ate complex *Ion transport number In chemistry, ion transport number, also called the transference number, is the fraction of the total electric current carried in an electrolyte by a given ionic species : :t_i = \frac Differences in transport number arise from differences in el ... * Ionic atmosphere References Anions Bases (chemistry) {{Base-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lyonium Ion
In chemistry, a lyonium ion is the cation derived by the protonation of a solvent molecule. For example, a hydronium ion is formed by the protonation of water, and is the cation formed by the protonation of methanol. Its counterpart is a lyate ion, the anion formed by the deprotonation of a solvent molecule. Lyonium and lyate ions, resulting from molecular autoionization In chemistry, molecular autoionization (or self-ionization) is a chemical reaction between molecules of the same substance to produce ions. If a pure liquid partially dissociates into ions, it is said to be self-ionizing. In most cases the ox ..., contribute to the molar conductivity of protolytic solvents. Examples See also * Lyate ion, a deprotonated solvent molecule * Onium ion, a protonated molecule more generally * Ion transport number * Ionic atmosphere References Acids Cations {{Acid-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Conductivity (electrolytic)
Conductivity or specific conductance of an electrolyte solution is a measure of its ability to conduct electricity. The SI unit of conductivity is siemens per meter (S/m). Conductivity measurements are used routinely in many industrial and environmental applications as a fast, inexpensive and reliable way of measuring the ionic content in a solution. For example, the measurement of product conductivity is a typical way to monitor and continuously trend the performance of water purification systems. In many cases, conductivity is linked directly to the total dissolved solids (TDS). High-quality deionized water has a conductivity of : \kappa = 0.05501 \pm 0.0001 μS/cm at 25 °C. This corresponds to a specific resistivity of : \rho = 18.18 \pm 0.03 MΩ⋅cm. The preparation of salt solutions often takes place in unsealed beakers. In this case the conductivity of purified water often is 10 to 20 times higher. A discussion can be found below. Typical drinking water is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
