Metal Hydroxides
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Metal Hydroxides
Metal hydroxides are hydroxides of metals. They are often strong bases. They consist of hydroxide anions and metallic cations. Some metal hydroxides, such as alkali metal hydroxides, ionize completely when dissolved. Certain metal hydroxides are weak electrolytes and dissolve only partially in aqueous solution. Examples * Aluminium hydroxide * Beryllium hydroxide * Cobalt(II) hydroxide * Copper(II) hydroxide * Curium hydroxide * Gold(III) hydroxide * Iron(II) hydroxide * Mercury(II) hydroxide * Nickel(II) hydroxide * Tin(II) hydroxide * Uranyl hydroxide * Zinc hydroxide * Zirconium(IV) hydroxide * Lithium hydroxide * Rubidium hydroxide * Cesium hydroxide * Sodium hydroxide * Potassium hydroxide Alkali metal hydroxides Other metal hydroxides * Gallium(III) hydroxide * Lead(II) hydroxide * Thallium(I) hydroxide * Thallium(III) hydroxide Role in soils In soils, it is assumed that larger amounts of natural phenols are released from decomposing plant litter rather than f ...
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Hydroxide
Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical. The corresponding electrically neutral compound HO• is the hydroxyl radical. The corresponding covalently bound group –OH of atoms is the hydroxy group. Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry. Many inorganic substances which bear the word ''hydroxide'' in their names are not ionic compounds of the hydroxide ion, but covalent compounds which contain hydroxy groups. Hydroxide ion The hydroxide ion is a natural par ...
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Lithium Hydroxide
Lithium hydroxide is an inorganic compound with the formula LiOH. It can exist as anhydrous or hydrated, and both forms are white hygroscopic solids. They are soluble in water and slightly soluble in ethanol. Both are available commercially. While classified as a strong base, lithium hydroxide is the weakest known alkali metal hydroxide. Production The preferred feedstock is hard-rock spodumene, where the lithium content is expressed as % lithium oxide. Lithium carbonate route Lithium hydroxide is often produced industrially from lithium carbonate in a metathesis reaction with calcium hydroxide: : The initially produced hydrate is dehydrated by heating under vacuum up to 180 °C. Lithium sulfate route An alternative route involves the intermediacy of lithium sulfate: :α-spodumene → β-spodumene :β-spodumene + CaO → + ... : : The main by-products are gypsum and sodium sulphate, which have some market value. Commercial setting According to Bloomberg, Ganfeng Lithiu ...
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Humus
In classical soil science, humus is the dark organic matter in soil that is formed by the decomposition of plant and animal matter. It is a kind of soil organic matter. It is rich in nutrients and retains moisture in the soil. Humus is the Latin word for "earth" or "ground". In agriculture, "humus" sometimes also is used to describe mature or natural compost extracted from a woodland or other spontaneous source for use as a soil conditioner. It is also used to describe a topsoil horizon that contains organic matter (''humus type'', ''humus form'', or ''humus profile''). Humus has many nutrients that improve the health of soil, nitrogen being the most important. The ratio of carbon to nitrogen (C:N) of humus commonly ranges between eight and fifteen with the median being about twelve. It also significantly affects the bulk density of soil. Humus is amorphous and lacks the "cellular cake structure characteristic of plants, micro-organisms or animals". Description The primary ...
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Lignin
Lignin is a class of complex organic polymers that form key structural materials in the support tissues of most plants. Lignins are particularly important in the formation of cell walls, especially in wood and bark, because they lend rigidity and do not rot easily. Chemically, lignins are polymers made by cross-linking phenolic precursors. History Lignin was first mentioned in 1813 by the Swiss botanist A. P. de Candolle, who described it as a fibrous, tasteless material, insoluble in water and alcohol but soluble in weak alkaline solutions, and which can be precipitated from solution using acid. He named the substance “lignine”, which is derived from the Latin word '' lignum'', meaning wood. It is one of the most abundant organic polymers on Earth, exceeded only by cellulose. Lignin constitutes 30% of non-fossil organic carbon on Earth, and 20 to 35% of the dry mass of wood. Lignin is present in red algae, which suggest that the common ancestor of plants and red algae ...
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Plant Litter
Plant litter (also leaf litter, tree litter, soil litter, litterfall or duff) is dead plant material (such as leaves, bark, needles, twigs, and cladodes) that have fallen to the ground. This detritus or dead organic material and its constituent nutrients are added to the top layer of soil, commonly known as the litter layer or O horizon ("O" for "organic"). Litter is an important factor in ecosystem dynamics, as it is indicative of ecological productivity and may be useful in predicting regional nutrient cycling and soil fertility. Characteristics and variability Litterfall is characterized as fresh, undecomposed, and easily recognizable (by species and type) plant debris. This can be anything from leaves, cones, needles, twigs, bark, seeds/nuts, logs, or reproductive organs (e.g. the stamen of flowering plants). Items larger than 2 cm diameter are referred to as coarse litter, while anything smaller is referred to as fine litter or litter. The type of litterfall is ...
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Natural Phenol
In biochemistry, naturally occurring phenols are natural products containing at least one phenol functional group. Phenolic compounds are produced by plants and microorganisms. Organisms sometimes synthesize phenolic compounds in response to ecological pressures such as pathogen and insect attack, UV radiation and wounding. As they are present in food consumed in human diets and in plants used in traditional medicine of several cultures, their role in human health and disease is a subject of research. Some phenols are germicidal and are used in formulating disinfectants. Classification Various classification schemes can be applied. A commonly used scheme is based on the number of carbons and was devised by Jeffrey Harborne and Simmonds in 1964 and published in 1980: C6-C7-C6 Diarylheptanoids are not included in this Harborne classification. They can also be classified on the basis of their number of phenol groups. They can therefore be called ''simple phenols'' or ...
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Soil
Soil, also commonly referred to as earth or dirt, is a mixture of organic matter, minerals, gases, liquids, and organisms that together support life. Some scientific definitions distinguish ''dirt'' from ''soil'' by restricting the former term specifically to displaced soil. Soil consists of a solid phase of minerals and organic matter (the soil matrix), as well as a porous phase that holds gases (the soil atmosphere) and water (the soil solution). Accordingly, soil is a three-state system of solids, liquids, and gases. Soil is a product of several factors: the influence of climate, relief (elevation, orientation, and slope of terrain), organisms, and the soil's parent materials (original minerals) interacting over time. It continually undergoes development by way of numerous physical, chemical and biological processes, which include weathering with associated erosion. Given its complexity and strong internal connectedness, soil ecologists regard soil as an ecosystem. Most ...
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Thallium(III) Hydroxide
Thallium(III) hydroxide, , also known as thallic hydroxide, is a hydroxide of thallium. It is a white solid. Thallium(III) hydroxide is a very weak base; it dissociates to give the thallium(III) ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ..., , only in strongly acidic conditions. Preparation Thallium(III) hydroxide can be produced by the reaction of thallium(III) chloride with sodium hydroxide or the electrochemical oxidation of in alkaline conditions. References Hydroxides Thallium(III) compounds {{Inorganic-compound-stub ...
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Thallium(I) Hydroxide
Thallium(I) hydroxide, also called thallous hydroxide, TlOH, is a hydroxide of thallium, with thallium in oxidation state +1. Synthesis Thallium(I) hydroxide is obtained from the decomposition of thallium(I) ethoxide in water. :C2H5OTl + H2O → TlOH + C2H5OH This can also be done by direct reaction of thallium with ethanol and oxygen gas. :4 Tl + 2 C2H5OH + O2 → 2 C2H5OTl + 2 TlOH Another method is the reaction between thallium(I) sulfate and barium hydroxide. :Tl2SO4 + Ba(OH)2 → 2 TlOH + BaSO4 Properties Thallous hydroxide is a strong base; it dissociates to the thallous ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ..., Tl+, except in strongly basic conditions. Tl+ resembles an alkali metal ion, A+, such as Li+ or K+. References Hydroxides Thallium(I) ...
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Lead(II) Hydroxide
Lead(II) hydroxide, Pb(OH)2, is a hydroxide of lead, with lead in oxidation state +2. In 1964 it was believed that such a simple compound did not exist, as lead basic carbonate (2PbCO3·Pb(OH)2) or lead(II) oxide (PbO) was encountered where lead hydroxide was expected. This has been a subject of considerable confusion in the past. However, subsequent research has demonstrated that lead(II) hydroxide does indeed exist as one of a series of lead hydroxides. Preparation When a hydroxide is added to a solution of a lead(II) salt, a hydrated lead oxide PbO·xH2O (with x < 1) is obtained. Careful of solution yields a crystalline product with a formula 6PbO·2H2O = Pb6O4(OH)4
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Gallium(III) Hydroxide
Gallium hydroxide, Ga(OH)3 is formed as a gel following the addition of ammonia to Ga3+ salts.Anthony John Downs, (1993), ''Chemistry of Aluminium, Gallium, Indium, and Thallium'', Springer, It is also found in nature as the rare mineral söhngeite which is reported to contain octahedrally coordinated gallium atoms Crystal Structure of a new mineral söhngeite, J.D. Scott, The American Mineralogist, (1971), 56, 355 Gallium hydroxide is amphoteric. In strongly acidic conditions, the gallium ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven ..., Ga3+ is formed. In strongly basic conditions, Ga(OH)4− is formed. Salts of Ga(OH)4− are sometimes called gallates. References Hydroxides Gallium compounds {{inorganic-compound-stub ...
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Potassium Hydroxide
Potassium hydroxide is an inorganic compound with the formula K OH, and is commonly called caustic potash. Along with sodium hydroxide (NaOH), KOH is a prototypical strong base. It has many industrial and niche applications, most of which exploit its caustic nature and its reactivity toward acids. An estimated 700,000 to 800,000 tonnes were produced in 2005. KOH is noteworthy as the precursor to most soft and liquid soaps, as well as numerous potassium-containing chemicals. It is a white solid that is dangerously corrosive. Properties and structure KOH exhibits high thermal stability. Because of this high stability and relatively low melting point, it is often melt-cast as pellets or rods, forms that have low surface area and convenient handling properties. These pellets become tacky in air because KOH is hygroscopic. Most commercial samples are ca. 90% pure, the remainder being water and carbonates. Its dissolution in water is strongly exothermic. Concentrated aqueous solut ...
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