Mercury Iodide
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Mercury Iodide
Mercury iodide may refer to: *Mercury(I) iodide, Hg2I2 *Mercury(II) iodide Mercury(II) iodide is a chemical compound with the molecular formula Hg I2. It is typically produced synthetically but can also be found in nature as the extremely rare mineral coccinite. Unlike the related mercury(II) chloride it is hardly solu ..., HgI2 Mercury (element) {{Short pages monitor ...
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Mercury(I) Iodide
Mercury(I) iodide is a chemical compound of mercury (element), mercury and iodine. The chemical formula is Hg2I2. It is photosensitive and decomposes easily to mercury and Mercury(II)_iodide, HgI2. Synthesis Mercury(I) iodide can be prepared by directly reacting mercury (element), mercury and iodine. Structure In common with other Hg(I) (mercurous) compounds which contain linear X-Hg-Hg-X units, Hg2I2 contains linear IHg2I units with an Hg-Hg bond length of 272 pm (Hg-Hg in the metal is 300 pm) and an Hg-I bond length of 268 pm. Wells A.F. (1984) ''Structural Inorganic Chemistry'' 5th edition Oxford Science Publications The overall coordination of each Hg atom is octahedral as it has in addition to the two nearest neighbours there are four other I atoms at 351 pm. The compound is often formulated as Hg22+ 2I−. Historical Uses Mercury(I) iodide was a commonly used as a drug in the 19th century, sometimes under the contemporary name of protiodide of mercury. It was used to trea ...
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Mercury(II) Iodide
Mercury(II) iodide is a chemical compound with the molecular formula Hg I2. It is typically produced synthetically but can also be found in nature as the extremely rare mineral coccinite. Unlike the related mercury(II) chloride it is hardly soluble in water (<100 ppm).


Production

Mercury(II) iodide is produced by adding an aqueous solution of to an aqueous solution of with stirring; the precipitate is filtered off, washed and dried at 70 °C. : HgCl2 + 2 KI → HgI2 + 2 KCl


Properties

Mercury(II) iodide displays