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Molecule-based Magnets
Molecule-based magnets (MBMs) or molecular magnets are a class of materials capable of displaying ferromagnetism and other more complex magnetic phenomena. This class expands the materials properties typically associated with magnets to include low density, transparency, electrical insulation, and low-temperature fabrication, as well as combine magnetic ordering with other properties such as photoresponsiveness. Essentially all of the common magnetic phenomena associated with conventional transition-metal magnets and rare-earth magnets can be found in molecule-based magnets. Molecule-Based MagnetMaterials Research SocietyRetrieved on 20 December 2007 Prior to 2011, MBMs were seen to exhibit "magnetic ordering with Curie temperature (Tc) exceeding room temperature". History The first synthesis and characterization of MBMs was accomplished by Wickman and co-workers in 1967. This was a diethyldithiocarbamate-Fe(III) chloride compound. In February 1992, Gatteschi and Sessoli publi ...
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Ferromagnetism
Ferromagnetism is a property of certain materials (such as iron) which results in a large observed magnetic permeability, and in many cases a large magnetic coercivity allowing the material to form a permanent magnet. Ferromagnetic materials are the familiar metals noticeably attracted to a magnet, a consequence of their large magnetic permeability. Magnetic permeability describes the induced magnetization of a material due to the presence of an ''external'' magnetic field, and it is this temporarily induced magnetization inside a steel plate, for instance, which accounts for its attraction to the permanent magnet. Whether or not that steel plate acquires a permanent magnetization itself, depends not only on the strength of the applied field, but on the so-called coercivity of that material, which varies greatly among ferromagnetic materials. In physics, several different types of material magnetism are distinguished. Ferromagnetism (along with the similar effect ferrimagnetis ...
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Metallic Bonding
Metallic bonding is a type of chemical bonding that arises from the electrostatic attractive force between conduction electrons (in the form of an electron cloud of delocalized electrons) and positively charged metal ions. It may be described as the sharing of ''free'' electrons among a structure of positively charged ions ( cations). Metallic bonding accounts for many physical properties of metals, such as strength, ductility, thermal and electrical resistivity and conductivity, opacity, and luster. Metallic bonding is not the only type of chemical bonding a metal can exhibit, even as a pure substance. For example, elemental gallium consists of covalently-bound pairs of atoms in both liquid and solid-state—these pairs form a crystal structure with metallic bonding between them. Another example of a metal–metal covalent bond is the mercurous ion (). History As chemistry developed into a science, it became clear that metals formed the majority of the periodic ...
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Chemical Physics Letters
''Chemical Physics Letters'' is a biweekly peer-reviewed scientific journal covering research in chemical physics and physical chemistry. It was established in 1967 and is published by Elsevier. The editors-in-chief are David C. Clary David (; , "beloved one") (traditional spelling), , ''Dāwūd''; grc-koi, Δαυΐδ, Dauíd; la, Davidus, David; gez , ዳዊት, ''Dawit''; xcl, Դաւիթ, ''Dawitʿ''; cu, Давíдъ, ''Davidŭ''; possibly meaning "beloved one". w ..., B. Dietzek, K-L. Han, anA. Karton External links * Chemical physics journals Publications established in 1967 Elsevier academic journals English-language journals {{chem-journal-stub ...
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Magnetic Thin Film
Thin-film memory is a high-speed alternative to core memory developed by Sperry Rand in a government-funded research project. Instead of threading individual ferrite cores on wires, thin-film memory consisted of 4-micrometre thick dots of permalloy, an iron–nickel alloy, deposited on small glass plates by vacuum evaporation techniques and a mask. The drive and sense lines were then added using printed circuit wiring over the alloy dots. This provided very fast access times in the range of 670 nanoseconds, but was very expensive to produce. In 1962, the UNIVAC 1107, intended for the civilian marketplace, used thin-film memory only for its 128-word general register stack. Military computers, where cost was less of a concern, used larger amounts of thin-film memory. Thin film was also used in a number of high-speed computer projects, including the high-end of the IBM System/360 The IBM System/360 (S/360) is a family of mainframe computer systems that was announced by ...
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Coercive Field
Coercivity, also called the magnetic coercivity, coercive field or coercive force, is a measure of the ability of a ferromagnetic material to withstand an external magnetic field without becoming demagnetized. Coercivity is usually measured in oersted or ampere/meter units and is denoted . An analogous property in electrical engineering and materials science, electric coercivity, is the ability of a ferroelectric material to withstand an external electric field without becoming depolarized. Ferromagnetic materials with high coercivity are called magnetically ''hard'', and are used to make permanent magnets. Materials with low coercivity are said to be magnetically ''soft''. The latter are used in transformer and inductor cores, recording heads, microwave devices, and magnetic shielding. Definitions Coercivity in a ferromagnetic material is the intensity of the applied magnetic field (''H'' field) required to demagnetize that material, after the magnetization of the sa ...
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Coordination Compound
A coordination complex consists of a central atom or ion, which is usually metallic and is called the ''coordination centre'', and a surrounding array of bound molecules or ions, that are in turn known as ''ligands'' or complexing agents. Many metal-containing compounds, especially those that include transition metals (elements like titanium that belong to the Periodic Table's d-block), are coordination complexes. Nomenclature and terminology Coordination complexes are so pervasive that their structures and reactions are described in many ways, sometimes confusingly. The atom within a ligand that is bonded to the central metal atom or ion is called the donor atom. In a typical complex, a metal ion is bonded to several donor atoms, which can be the same or different. A polydentate (multiple bonded) ligand is a molecule or ion that bonds to the central atom through several of the ligand's atoms; ligands with 2, 3, 4 or even 6 bonds to the central atom are common. These compl ...
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Organic Molecule
In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The study of the properties, reactions, and syntheses of organic compounds comprise the discipline known as organic chemistry. For historical reasons, a few classes of carbon-containing compounds (e.g., carbonate salts and cyanide salts), along with a few other exceptions (e.g., carbon dioxide, hydrogen cyanide), are not classified as organic compounds and are considered inorganic. Other than those just named, little consensus exists among chemists on precisely which carbon-containing compounds are excluded, making any rigorous definition of an organic compound elusive. Although organic compounds make up only a small percentage of Earth's crust, they are of central importance because all known life is based on organic compounds. Living thin ...
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Magnetic Moment
In electromagnetism, the magnetic moment is the magnetic strength and orientation of a magnet or other object that produces a magnetic field. Examples of objects that have magnetic moments include loops of electric current (such as electromagnets), permanent magnets, elementary particles (such as electrons), various molecules, and many astronomical objects (such as many planets, some moons, stars, etc). More precisely, the term ''magnetic moment'' normally refers to a system's magnetic dipole moment, the component of the magnetic moment that can be represented by an equivalent magnetic dipole: a magnetic north and south pole separated by a very small distance. The magnetic dipole component is sufficient for small enough magnets or for large enough distances. Higher-order terms (such as the magnetic quadrupole moment) may be needed in addition to the dipole moment for extended objects. The magnetic dipole moment of an object is readily defined in terms of the torque that the objec ...
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Hyperthermia Therapy
Hyperthermia therapy ''(or hyperthermia, or thermotherapy)'' is a type of medical treatment in which body tissue is exposed to temperatures above body temperature, in the region of 40–45 °C (104–113 °F). Hyperthermia is usually applied as an adjuvant to radiotherapy or chemotherapy, to which it works as a sensitizer, in an effort to treat cancer. Hyperthermia uses higher temperatures than diathermy and lower temperatures than ablation. When combined with radiation therapy, it can be called thermoradiotherapy. Definition Hyperthermia is defined as supra-normal body temperatures. There is no consensus as to what is the safest or most effective target temperature for the whole body. During treatment the body temperature reaches a level between . However, other researchers define hyperthermia between (Europe, USA) to near (Japan, Russia). Types * ''Local hyperthermia'' heats a very small area and is typically used for cancers near or on the skin or near natu ...
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Magnetic Resonance Imaging
Magnetic resonance imaging (MRI) is a medical imaging technique used in radiology to form pictures of the anatomy and the physiological processes of the body. MRI scanners use strong magnetic fields, magnetic field gradients, and radio waves to generate images of the organs in the body. MRI does not involve X-rays or the use of ionizing radiation, which distinguishes it from CT and PET scans. MRI is a medical application of nuclear magnetic resonance (NMR) which can also be used for imaging in other NMR applications, such as NMR spectroscopy. MRI is widely used in hospitals and clinics for medical diagnosis, staging and follow-up of disease. Compared to CT, MRI provides better contrast in images of soft-tissues, e.g. in the brain or abdomen. However, it may be perceived as less comfortable by patients, due to the usually longer and louder measurements with the subject in a long, confining tube, though "Open" MRI designs mostly relieve this. Additionally, implants and oth ...
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Magnetic Drug Delivery
Magnetic nanoparticle-based drug delivery is a means in which magnetic particles such as iron oxide nanoparticles are a component of a delivery vehicle for magnetic drug delivery, due to the simplicity with which the particles can be drawn to (external) magnetopuissant targets. Magnetic nanoparticles can impart imaging and controlled release capabilities to drug delivery materials such as micelles, liposomes, and polymers. Synopsis Molecular magnets (single-molecule magnets) are a platform that incorporates insoluble (toxic) drugs into biocompatible carrier materials, without adding magnetic iron oxide nanoparticles which might adversely affect patients susceptible to iron overdose. The drawbacks in conventional magnetic drug delivery methods can be overcome by switching from typical iron oxide nanoparticles to ones based on molecular magnets, such as Fe(salen)-based "anticancer nanomagnet" with proven cancer-fighting ability. However, insoluble drugs including Fe(salen) als ...
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Chemotherapy
Chemotherapy (often abbreviated to chemo and sometimes CTX or CTx) is a type of cancer treatment that uses one or more anti-cancer drugs (chemotherapeutic agents or alkylating agents) as part of a standardized chemotherapy regimen. Chemotherapy may be given with a curative intent (which almost always involves combinations of drugs) or it may aim to prolong life or to reduce symptoms ( palliative chemotherapy). Chemotherapy is one of the major categories of the medical discipline specifically devoted to pharmacotherapy for cancer, which is called ''medical oncology''. The term ''chemotherapy'' has come to connote non-specific usage of intracellular poisons to inhibit mitosis (cell division) or induce DNA damage, which is why inhibition of DNA repair can augment chemotherapy. The connotation of the word chemotherapy excludes more selective agents that block extracellular signals (signal transduction). The development of therapies with specific molecular or genetic targets, wh ...
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