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Metaldehyde
Metaldehyde is an organic compound with the chemical formula, formula (C8H16O4). It is used as a pesticide against slugs, snails, and other gastropods. It is the cyclic tetramer of acetaldehyde. Production and properties Metaldehyde is flammable, toxic if ingested in large quantities, and irritating to the skin and eyes.  It has a white crystalline appearance with a menthol odor. Metaldehyde is obtained in moderate yields by treatment of acetaldehyde with various Acid catalysis, acid catalysts, such as hydrogen bromide, and cooling. The liquid trimer, paraldehyde is also obtained. The reaction is reversible; upon heating to about 80 °C, metaldehyde and paraldehyde revert to acetaldehyde. Metaldehyde exists as a mixture of four stereoisomers, molecules that differ with respect to the relative orientation of the methyl groups on the 8-membered ring. The stereoisomers have respectively the molecular symmetries C (with symmetry of order 2), C (order 4), D (order 8), and C ( ...
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Molluscicides
Molluscicides () – also known as snail baits, snail pellets, or slug pellets – are pesticides against molluscs, which are usually used in agriculture or gardening, in order to control Pest (organism)#Gastropods, gastropod pests specifically slugs and snails which damage crops or other valued plants by feeding on them. A number of chemicals can be employed as a molluscicide: * Metal salt (chemistry), salts such as iron(III) phosphate, aluminium sulfate, and ferric sodium EDTA, relatively non-toxic, also used in organic gardening * Metaldehyde * Niclosamide * Acetylcholinesterase inhibitors (e.g. methiocarb), highly toxic to other animals and humans, acts also as a contact poison Accidental poisonings Metal salt-based molluscicides are not toxic to higher animals. However, metaldehyde-based and especially acetylcholinesterase inhibitor-based products are highly toxic, and have resulted in many deaths of pets and humans. Some products contain a bitter (taste), bittering agen ...
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Paraldehyde
Paraldehyde is the cyclic trimer of acetaldehyde molecules. Formally, it is a derivative of 1,3,5-trioxane, with a methyl group substituted for a hydrogen atom at each carbon. The corresponding tetramer is metaldehyde. A colourless liquid, it is sparingly soluble in water and highly soluble in ethanol. Paraldehyde slowly oxidizes in air, turning brown and producing an odour of acetic acid. It quickly reacts with most plastics and rubber. Paraldehyde was first observed in 1835 by the German chemist Justus Liebig; its empirical formula was determined in 1838 by Liebig's student Hermann Fehling. The German chemist Valentin Hermann Weidenbusch (1821–1893), another of Liebig's students, synthesized paraldehyde in 1848 by treating acetaldehyde with acid (either sulfuric or nitric acid) and cooling to 0°C. He found it quite remarkable that when paraldehyde was ''heated'' with a trace of the same acid, the reaction went the other way, recreating acetaldehyde. Paraldehyde has uses i ...
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Acetaldehyde
Acetaldehyde (IUPAC systematic name ethanal) is an organic chemical compound with the formula CH3 CHO, sometimes abbreviated by chemists as MeCHO (Me = methyl). It is a colorless liquid or gas, boiling near room temperature. It is one of the most important aldehydes, occurring widely in nature and being produced on a large scale in industry. Acetaldehyde occurs naturally in coffee, bread, and ripe fruit, and is produced by plants. It is also produced by the partial oxidation of ethanol by the liver enzyme alcohol dehydrogenase and is a contributing cause of hangover after alcohol consumption. Pathways of exposure include air, water, land, or groundwater, as well as drink and smoke. Consumption of disulfiram inhibits acetaldehyde dehydrogenase, the enzyme responsible for the metabolism of acetaldehyde, thereby causing it to build up in the body. The International Agency for Research on Cancer (IARC) has listed acetaldehyde as a Group 1 carcinogen. Acetaldehyde is "one of the mos ...
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Molluscicide
Molluscicides () – also known as snail baits, snail pellets, or slug pellets – are pesticides against molluscs, which are usually used in agriculture or gardening, in order to control gastropod pests specifically slugs and snails which damage crops or other valued plants by feeding on them. A number of chemicals can be employed as a molluscicide: * Metal salts such as iron(III) phosphate, aluminium sulfate, and ferric sodium EDTA, relatively non-toxic, also used in organic gardening * Metaldehyde * Niclosamide * Acetylcholinesterase inhibitors (e.g. methiocarb), highly toxic to other animals and humans, acts also as a contact poison Accidental poisonings Metal salt-based molluscicides are not toxic to higher animals. However, metaldehyde-based and especially acetylcholinesterase inhibitor-based products are highly toxic, and have resulted in many deaths of pets and humans. Some products contain a bittering agent that reduces but does not eliminate the risk of accidental ...
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Paraldehyde
Paraldehyde is the cyclic trimer of acetaldehyde molecules. Formally, it is a derivative of 1,3,5-trioxane, with a methyl group substituted for a hydrogen atom at each carbon. The corresponding tetramer is metaldehyde. A colourless liquid, it is sparingly soluble in water and highly soluble in ethanol. Paraldehyde slowly oxidizes in air, turning brown and producing an odour of acetic acid. It quickly reacts with most plastics and rubber. Paraldehyde was first observed in 1835 by the German chemist Justus Liebig; its empirical formula was determined in 1838 by Liebig's student Hermann Fehling. The German chemist Valentin Hermann Weidenbusch (1821–1893), another of Liebig's students, synthesized paraldehyde in 1848 by treating acetaldehyde with acid (either sulfuric or nitric acid) and cooling to 0°C. He found it quite remarkable that when paraldehyde was ''heated'' with a trace of the same acid, the reaction went the other way, recreating acetaldehyde. Paraldehyde has uses i ...
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Lonza Group
Lonza Group is a Swiss multinational manufacturing company for the pharmaceutical, biotechnology and nutrition sectors, headquartered in Basel, with major facilities in Europe, North America and South Asia. Lonza was established under that name in the late 19th-century in Switzerland. The company provides product development services to the pharmaceutical and biologic industries, including custom manufacturing of biopharmaceuticals and detection systems and services for the bioscience sector. History Lonza was founded in 1897 in the small Swiss town of Gampel, situated in the canton of Valais, taking its name from the nearby river. In the course of the 20th century Lonza evolved from hydroelectricity and C2 chemistry, through nitrogen chemistry to petrochemistry before moving into fine chemistry and biochemistry. Initially the company produced electricity. The following year, calcium carbide manufacture began using the electricity to heat a furnace to the 2000 °C required f ...
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Iron(III) Phosphate
Iron(III) phosphate, also ferric phosphate, is the inorganic compound with the formula Fe PO4. Several related materials are known, including four polymorphs of FePO4 and two polymorphs of the dihydrate FePO4·(H2O)2. These materials find few technical applications as well as occurring in the mineral kingdom. Structure The most common form of FePO4 adopts the structure of α-quartz. As such the material consists of tetrahedral Fe(III) and phosphate sites. As such the P and Fe have tetrahedral molecular geometry. At high pressures, a phase change occurs to a more dense structure with octahedral Fe centres. Two orthorhombic structures and a monoclinic phase are also known. In the two polymorphs of the dihydrate, the Fe centre is octahedral with two mutually cis water ligands. Uses Iron(III) phosphate can be used in steel and metal manufacturing processes. When bonded to a metal surface, iron phosphate prevents further oxidation of the metal. Its presence is partially r ...
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Slug
Slug, or land slug, is a common name for any apparently shell-less terrestrial gastropod mollusc. The word ''slug'' is also often used as part of the common name of any gastropod mollusc that has no shell, a very reduced shell, or only a small internal shell, particularly sea slugs and semislugs (this is in contrast to the common name ''snail'', which applies to gastropods that have a coiled shell large enough that they can fully retract their soft parts into it). Various taxonomic families of land slugs form part of several quite different evolutionary lineages, which also include snails. Thus, the various families of slugs are not closely related, despite a superficial similarity in the overall body form. The shell-less condition has arisen many times independently as an example of convergent evolution, and thus the category "slug" is polyphyletic. Taxonomy Of the six orders of Pulmonata, two – the Onchidiacea and Soleolifera – solely comprise slugs. A third family, ...
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Field Ration
A field ration (combat ration, ration pack, or food packet) is a type of prepackaged or canned military ration. Field rations are distinguished from garrison rations by virtue of being designed for minimal preparation in the field, as well as for long shelf life. They contain canned, vacuum-sealed, pre-cooked or freeze-dried foods, powdered beverage mixes or concentrated food bars. Many field rations contain meat as one of their main courses, but countries such as the United States offer vegetarian options as well. A WWI term, the "iron ration" is a soldier's dry emergency rations. The term ''MRE'' is sometimes used synonymously with ''field ration'' but it more accurately describes a specific type from the United States. Most armed forces in the world today now field some form of pre-packaged combat ration, often suitably tailored to meet national or regional cuisines. Such meals used for field rations also prove invaluable for disaster or wartime relief, where large sto ...
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University Of California, Davis
The University of California, Davis (UC Davis, UCD, or Davis) is a public land-grant research university near Davis, California. Named a Public Ivy, it is the northernmost of the ten campuses of the University of California system. The institution was first founded as an agricultural branch of the system in 1905 and became the seventh campus of the University of California in 1959. The university is classified among "R1: Doctoral Universities – Very high research activity". The UC Davis faculty includes 23 members of the National Academy of Sciences, 30 members of the American Academy of Arts and Sciences, 17 members of the American Law Institute, 14 members of the Institute of Medicine, and 14 members of the National Academy of Engineering. Among other honors that university faculty, alumni, and researchers have won are two Nobel Prizes, one Fields Medal, a Presidential Medal of Freedom, three Pulitzer Prizes, three MacArthur Fellowships, and a National Medal of Scien ...
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Ferric Sodium EDTA
Ferric sodium EDTA, also known as sodium ferric ethylenediaminetetraacetate, is a broad spectrum molluscicide used to kill snails and slugs and protect agricultural crops and garden plants, and in particular to eliminate infestations of ''Cornu aspersum'', the common garden snail. Chemically, it is a salt of ethylenediaminetetraacetic acid. Mechanism of action and environmental impacts Ferric sodium EDTA works by interacting with and destroying hemocyanin, a copper based compound found in the blood of molluscs and arthropods which is used to carry oxygen, similar to hemoglobin found in vertebrates, and typically kills snails and slugs in a matter of days following exposure. The compound is much safer than Metaldehyde Metaldehyde is an organic compound with the chemical formula, formula (C8H16O4). It is used as a pesticide against slugs, snails, and other gastropods. It is the cyclic tetramer of acetaldehyde. Production and properties Metaldehyde is flammable, ... and does n ...
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Organic Compound
In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The study of the properties, reactions, and syntheses of organic compounds comprise the discipline known as organic chemistry. For historical reasons, a few classes of carbon-containing compounds (e.g., carbonate salts and cyanide salts), along with a few other exceptions (e.g., carbon dioxide, hydrogen cyanide), are not classified as organic compounds and are considered inorganic. Other than those just named, little consensus exists among chemists on precisely which carbon-containing compounds are excluded, making any rigorous definition of an organic compound elusive. Although organic compounds make up only a small percentage of Earth's crust, they are of central importance because all known life is based on organic compounds. Living t ...
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