Knipholone
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Knipholone
Knipholone is a chemical compound found in the roots of ''Kniphofia foliosa'' of the family Asphodelaceae Asphodelaceae is a family of flowering plants in the order Asparagales. Such a family has been recognized by most taxonomists, but the circumscription has varied widely. In its current circumscription in the APG IV system, it includes about 40 .... References Dihydroxyanthraquinones Phenol ethers {{aromatic-stub ...
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Atropisomer
Atropisomers are stereoisomers arising because of hindered rotation about a single bond, where energy differences due to steric strain or other contributors create a barrier to rotation that is high enough to allow for isolation of individual conformers. They occur naturally and are important in pharmaceutical design. When the substituents are achiral, these conformers are enantiomers (''atropoenantiomers''), showing axial chirality; otherwise they are diastereomers (''atropodiastereomers''). Etymology and history The word ''atropisomer'' ( el, άτροπος, , meaning "without turn") was coined in application to a theoretical concept by German biochemist Richard Kuhn for Karl Freudenberg's seminal ''Stereochemie'' volume in 1933. Atropisomerism was first experimentally detected in a tetra substituted biphenyl, a diacid, by George Christie and James Kenner in 1922. Michinori Ōki further refined the definition of atropisomers taking into account the temperature-dependence asso ...
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Kniphofia Foliosa
''Kniphofia'' is a genus of perennial flowering plants in the family Asphodelaceae, first described as a genus in 1794. Species are native to Africa. Common names include tritoma, red hot poker, torch lily and poker plant. Description Herbaceous species and hybrids have narrow, grass-like leaves long, while evergreen species have broader, strap-shaped foliage up to long. All plants produce spikes of upright, brightly coloured flowers well above the foliage, in shades of red, orange and yellow, often bicoloured. The flowers produce copious nectar while blooming and are attractive to bees and sunbirds. In the New World, they may attract nectarivores such as hummingbirds and New World orioles. Etymology The genus ''Kniphofia'' is named after Johann Hieronymus Kniphof, an 18th-century German physician and botanist. Species There are about 73 described species, including two hybrids. # ''Kniphofia acraea'' Codd - Cape Provinces of South Africa # ''Kniphofia albescens'' Codd - Mp ...
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Family (biology)
Family ( la, familia, plural ') is one of the eight major hierarchical taxonomic ranks in Linnaean taxonomy. It is classified between order and genus. A family may be divided into subfamilies, which are intermediate ranks between the ranks of family and genus. The official family names are Latin in origin; however, popular names are often used: for example, walnut trees and hickory trees belong to the family Juglandaceae, but that family is commonly referred to as the "walnut family". What belongs to a family—or if a described family should be recognized at all—are proposed and determined by practicing taxonomists. There are no hard rules for describing or recognizing a family, but in plants, they can be characterized on the basis of both vegetative and reproductive features of plant species. Taxonomists often take different positions about descriptions, and there may be no broad consensus across the scientific community for some time. The publishing of new data and opini ...
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Asphodelaceae
Asphodelaceae is a family of flowering plants in the order Asparagales. Such a family has been recognized by most taxonomists, but the circumscription has varied widely. In its current circumscription in the APG IV system, it includes about 40 genera and 900 known species. The type genus is ''Asphodelus''. The family has a wide but scattered distribution throughout the tropics and temperate zones. Many of the species are cultivated as ornamentals. A few are grown commercially for cut flowers. Two species of '' Aloe'' are grown for their leaf sap, which has medicinal and cosmetic uses. ''Xanthorrhoea'' is endemic to Australia. Description Members of the Asphodelaceae are diverse, with few characters uniting the three subfamilies currently recognized. The presence of anthraquinones is one common character. The flowers (the inflorescence) are typically borne on a leafless stalk ( scape) which arises from a basal rosette of leaves. The individual flowers have jointed stalks ( ...
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Dihydroxyanthraquinones
A dihydroxyanthraquinone is any of several isomeric organic compounds with formula , formally derived from 9,10-anthraquinone by replacing two hydrogen atoms by hydroxyl groups. Dihyroxyantraquinones have been studied since the early 1900s, and include some compounds of historical and current importance. The isomers differ in the position of the hydroxyl groups, and of the carbonyl oxygens (=O) of the underlying anthraquinone. Isomers From 9,10-anthraquinone The unqualified term "dihydroxyanthraquinone" usually means a hydroxy derivative of 9,10-anthraquinone. The dihydroxy-9,10-anthraquinone functional group occurs widely in natural products, and is an important feature of the anthracycline antitumour antibiotics. In particular, 1,8-Dihydroxy-9,10-anthraquinone is the precursor for the important topical antipsoriatic drug anthralin, 1,8-dihydroxy-9-anthrone, There are 28 ways of choosing two of the 8 possible hydrogens, but because of the four-fold symmetry of the 9,10-anth ...
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