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Kevlar
Kevlar (para-aramid) is a strong, heat-resistant synthetic fiber, related to other aramids such as Nomex and Technora. Developed by Stephanie Kwolek at DuPont in 1965, the high-strength material was first used commercially in the early 1970s as a replacement for steel in racing tires. It is typically spun into ropes or fabric sheets that can be used as such, or as an ingredient in composite material components. Kevlar has many applications, ranging from bicycle tires and racing sails to bulletproof vests, all due to its high tensile strength-to-weight ratio; by this measure it is five times stronger than steel. It is also used to make modern marching drumheads that withstand high impact; and for mooring lines and other underwater applications. A similar fiber called Twaron with the same chemical structure was developed by Akzo in the 1970s; commercial production started in 1986, and Twaron is now manufactured by Teijin. History Poly-paraphenylene terephthalamide (K2 ...
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Stephanie Kwolek
Stephanie Louise Kwolek (; July 31, 1923 – June 18, 2014) was a Polish-American chemist who is known for inventing Kevlar. Her career at the DuPont company spanned more than 40 years. She discovered the first of a family of synthetic fibers of exceptional strength and stiffness: poly-paraphenylene terephthalamide. For her discovery, Kwolek was awarded the DuPont company's Lavoisier Medal for outstanding technical achievement. As of August 2019, she was the only female employee to have received that honor.Dan Samorodnitsky"Meet Stephanie Kwolek, the woman who gave us bulletproof vests and yoga pants"''Massive Science, July 31, 2019. In 1995 she became the fourth woman to be added to the National Inventors Hall of Fame. Kwolek won numerous awards for her work in polymer chemistry, including the National Medal of Technology, the IRI Achievement Award and the Perkin Medal. Early life and education Kwolek was one of two children born to Polish immigrant parents in the Pittsburgh ...
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Bulletproof Vest
A bulletproof vest, also known as a ballistic vest or a bullet-resistant vest, is an item of body armor that helps absorb the impact and reduce or stop penetration to the torso from firearm-fired projectiles and fragmentation from explosions. The vest may come in a soft form, as worn by many police officers, prison guards, security guards, and some private citizens, used to protect against stabbing attacks or light projectiles, using metallic or para-aramid components. Soldiers, police tactical units, marines, and special operations forces wear hard armors, either in conjunction with soft armor or alone, to protect against rifle ammunition or fragmentation. History Early modern era In 1538, Francesco Maria della Rovere commissioned Filippo Negroli to create a bulletproof vest. In 1561, Maximilian II, Holy Roman Emperor is recorded as testing his armor against gun-fire. Similarly, in 1590 Sir Henry Lee expected his Greenwich armor to be "pistol proof". Its actual effectiveness ...
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Drumhead
A drumhead or drum skin is a membrane stretched over one or both of the open ends of a drum. The drumhead is struck with sticks, mallets, or hands, so that it vibrates and the sound resonates through the drum. Additionally outside of percussion instruments, drumheads are also used on some string instruments, most notably the banjo. History Originally, drumheads were made from animal hide and were first used in early human history, long before records began. The term ''drumhead'' is first attested in English in 1580, in the writings of the soldier Thomas Churchyard, who mentioned how "Dice plaie began ... on the toppe of Drommes heddes". In 1957, Remo Belli and Sam Muchnick together developed a polymer head (also known as Mylar) leading to the development of the Remo drumhead company. Despite the benefits of plastic heads, drummers in historical reenactment groups such as fife and drum use animal skin heads for historical accuracy. Rawhide heads are also popular with music ...
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P-Phenylenediamine
''p''-Phenylenediamine (PPD) is an organic compound with the formula C6H4(NH2)2. This derivative of aniline is a white solid, but samples can darken due to air oxidation. It is mainly used as a component of engineering polymers and composites like kevlar. It is also an ingredient in hair dyes and is occasionally used as a substitute for henna. Production PPD is produced via three routes. Most commonly, 4-nitrochlorobenzene is treated with ammonia and the resulting 4-nitroaniline is then hydrogenated: :ClC6H4NO2 + 2 NH3 → H2NC6H4NO2 + NH4Cl :H2NC6H4NO2 + 3 H2 → H2NC6H4NH2 + 2 H2O In the DuPont route, aniline is converted to diphenyltriazine, which is then converted by acid-catalysis to 4-aminoazobenzene. Hydrogenation of the latter affords PPD.Robert A. Smiley "Phenylene- and Toluenediamines" in ''Ullmann's Encyclopedia of Industrial Chemistry'', 2002, Wiley-VCH, Weinheim. Uses Precursor to polymers PPD is a precursor to aramid plastics and fibers such as ...
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Nylon
Nylon is a generic designation for a family of synthetic polymers composed of polyamides ( repeating units linked by amide links).The polyamides may be aliphatic or semi-aromatic. Nylon is a silk-like thermoplastic, generally made from petroleum, that can be melt-processed into fibers, films, or shapes. Nylon polymers can be mixed with a wide variety of additives to achieve many property variations. Nylon polymers have found significant commercial applications in fabric and fibers (apparel, flooring and rubber reinforcement), in shapes (molded parts for cars, electrical equipment, etc.), and in films (mostly for food packaging). History DuPont and the invention of nylon Researchers at DuPont began developing cellulose based fibers, culminating in the synthetic fiber rayon. DuPont's experience with rayon was an important precursor to its development and marketing of nylon. DuPont's invention of nylon spanned an eleven-year period, ranging from the initial research pr ...
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Composite Material
A composite material (also called a composition material or shortened to composite, which is the common name) is a material which is produced from two or more constituent materials. These constituent materials have notably dissimilar chemical or physical properties and are merged to create a material with properties unlike the individual elements. Within the finished structure, the individual elements remain separate and distinct, distinguishing composites from mixtures and solid solutions. Typical engineered composite materials include: *Reinforced concrete and masonry *Composite wood such as plywood *Reinforced plastics, such as fibre-reinforced polymer or fiberglass *Ceramic matrix composites ( composite ceramic and metal matrices) *Metal matrix composites *and other advanced composite materials There are various reasons where new material can be favoured. Typical examples include materials which are less expensive, lighter, stronger or more durable when compared with commo ...
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Tire
A tire (American English) or tyre (British English) is a ring-shaped component that surrounds a Rim (wheel), wheel's rim to transfer a vehicle's load from the axle through the wheel to the ground and to provide Traction (engineering), traction on the surface over which the wheel travels. Most tires, such as those for automobiles and bicycles, are pneumatically inflated structures, which also provide a flexible cushion that absorbs shock as the tire rolls over rough features on the surface. Tires provide a footprint, called a contact patch, that is designed to match the weight of the vehicle with the bearing strength of the surface that it rolls over by providing a bearing pressure that will not deform the surface excessively. The materials of modern pneumatic tires are synthetic rubber, natural rubber, fabric, and wire, along with carbon black and other chemical compounds. They consist of a tire tread, tread and a body. The tread provides Traction (engineering), traction ...
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Synthetic Fiber
Synthetic fibers or synthetic fibres (in British English; see spelling differences) are fibers made by humans through chemical synthesis, as opposed to natural fibers that are directly derived from living organisms, such as plants (like cotton) or fur from animals. They are the result of extensive research by scientists to replicate naturally occurring animal and plant fibers. In general, synthetic fibers are created by extruding fiber-forming materials through spinnerets, forming a fiber. These are called synthetic or artificial fibers. The word polymer comes from a Greek prefix "poly" which means "many" and suffix "mer" which means "single units". (Note: each single unit of a polymer is called a monomer). Early experiments The first fully synthetic fiber was glass. Joseph Swan invented one of the first artificial fibers in the early 1880s; today it would be called semisynthetic in precise usage. His fiber was drawn from a cellulose liquid, formed by chemically modifying th ...
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Viscosity
The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the internal frictional force between adjacent layers of fluid that are in relative motion. For instance, when a viscous fluid is forced through a tube, it flows more quickly near the tube's axis than near its walls. Experiments show that some stress (such as a pressure difference between the two ends of the tube) is needed to sustain the flow. This is because a force is required to overcome the friction between the layers of the fluid which are in relative motion. For a tube with a constant rate of flow, the strength of the compensating force is proportional to the fluid's viscosity. In general, viscosity depends on a fluid's state, such as its temperature, pressure, and rate of deformation. However, the dependence on some of these properties is ...
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Spinneret (polymers)
A spinneret is a device used to extrude a polymer solution or polymer melt to form fibers. Streams of viscous polymer exit via the spinneret into air or liquid leading to a phase inversion which allows the polymer to solidify. The individual polymer chains tend to align in the fiber because of viscous flow. This airstream liquid-to-fiber formation process is similar to the production process for cotton candy. The fiber production process is generally referred to as "spinning". Depending on the type of spinneret used, either solid or hollow fibers can be formed. Spinnerets are also used for electrospinning and electrospraying applications. They are sometimes called ''coaxial needles,'' or ''coaxial emitters.'' Spinnerets are usually made of metals with melting points too low to withstand the heating processes employed in industrial metallurgy, and thus are generally not used to form metallic fibers. See also * Electrospinning * Hollow fiber membrane * Spinning (polymers) * Tex ...
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Polymer Chemistry
Polymer chemistry is a sub-discipline of chemistry that focuses on the structures of chemicals, chemical synthesis, and chemical and physical properties of polymers and macromolecules. The principles and methods used within polymer chemistry are also applicable through a wide range of other chemistry sub-disciplines like organic chemistry, analytical chemistry, and physical chemistry. Many materials have polymeric structures, from fully inorganic metals and ceramics to DNA and other biological molecules. However, polymer chemistry is typically related to synthetic and organic compositions. Synthetic polymers are ubiquitous in commercial materials and products in everyday use, such as plastics, and rubbers, and are major components of composite materials. Polymer chemistry can also be included in the broader fields of polymer science or even nanotechnology, both of which can be described as encompassing polymer physics and polymer engineering.Hans-Heinrich Moretto, Manfred Sch ...
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Poly(p-phenylenterephthalamid)-Synthese
Poly, from the Greek πολύς meaning "many" or "much", may refer to: Businesses * China Poly Group Corporation, a Chinese business group, and its subsidiaries: ** Poly Property, a Hong Kong incorporated Chinese property developer ** Poly Real Estate, a Chinese real estate developer ** Poly Technologies, a defense manufacturing company * Poly (company), formerly Polycom, an American communications technology company People * Poly (footballer) (1906-1986), full name Policarpo Ribeiro de Oliveira, Brazilian footballer * Natasha Poly (born 1985), stage name of Russian supermodel Natalya Sergeyevna Polevshchikova * Poly Styrene (1957–2011), stage name of British musician Marianne Joan Elliott-Said Other uses * Hong Kong Polytechnic University, locally known as Poly * Poly (website), a website by Google * Polynesian, often shortened to poly, as in ‘Poly people are also called “Pasifika” or “Tangata Moana” (people of the ocean)’ * Polyamory, often shortened to poly, a ...
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