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Kaolin
Kaolinite ( ; also called kaolin) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral sheet of alumina (). Kaolinite is a soft, earthy, usually white, mineral (dioctahedral phyllosilicate clay), produced by the chemical weathering of aluminium silicate minerals like feldspar. It has a low shrink–swell capacity and a low cation-exchange capacity (1–15 meq/100 g). Rocks that are rich in kaolinite, and halloysite, are known as kaolin () or china clay. In many parts of the world kaolin is colored pink-orange-red by iron oxide, giving it a distinct rust hue. Lower concentrations of iron oxide yield the white, yellow, or light orange colors of kaolin. Alternating lighter and darker layers are sometimes found, as at Providence Canyon State Park in Georgia, United States. Kaolin is an important raw material in many industries and appli ...
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Clay Mineral
Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay minerals form in the presence of water and have been important to life, and many theories of abiogenesis involve them. They are important constituents of soils, and have been useful to humans since ancient times in agriculture and manufacturing. Properties Clay is a very fine-grained geologic material that develops plasticity when wet, but becomes hard, brittle and non–plastic upon drying or firing. It is a very common material, and is the oldest known ceramic. Prehistoric humans discovered the useful properties of clay and used it for making pottery. The chemistry of clay, including its capacity to retain nutrient cations such as potassium and ammonium, is important to soil fertility. Because the individual particles in clay are less ...
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Clay
Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, ). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impurities, such as a reddish or brownish colour from small amounts of iron oxide. Clays develop plasticity (physics), plasticity when wet but can be hardened through Pottery#Firing, firing. Clay is the longest-known ceramic material. Prehistoric humans discovered the useful properties of clay and used it for making pottery. Some of the earliest pottery shards have been radiocarbon dating, dated to around 14,000 BCE, and Clay tablet, clay tablets were the first known writing medium. Clay is used in many modern industrial processes, such as paper making, cement production, and chemical filtration, filtering. Between one-half and two-thirds of the world's population live or work in buildings made with clay, often baked into brick, as an essenti ...
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Aluminium Silicate
Aluminum silicate (or aluminium silicate) is a name commonly applied to chemical compounds which are derived from aluminium oxide, Al2O3 and silicon dioxide, SiO2 which may be anhydrous or hydrated, naturally occurring as minerals or synthetic. Their chemical formulae are often expressed as xAl2O3·ySiO2·zH2O. It is known as E number E559. Main representatives Andalusite, kyanite, and sillimanite are the principal aluminium silicate minerals. The triple point of the three polymorphs is located at a temperature of and a pressure of . These three minerals are commonly used as index minerals in metamorphic rocks. * Al2SiO5, (Al2O3·SiO2), which occurs naturally as the minerals andalusite, kyanite and sillimanite which have distinct crystal structures. * Al2Si2O7, (Al2O3·2SiO2), called metakaolinite, formed from kaolin by heating at . * Al6Si2O13, (3Al2O3·2SiO2), the mineral mullite, the only thermodynamically stable intermediate phase in the Al2O3-SiO2 system at at ...
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Halloysite
Halloysite is an aluminosilicate clay mineral with the empirical formula Al2Si2O5(OH)4. Its main constituents are oxygen (55.78%), silicon (21.76%), aluminium (20.90%), and hydrogen (1.56%). It is a member of the kaolinite group. Halloysite typically forms by hydrothermal alteration of alumino-silicate minerals. It can occur intermixed with dickite, kaolinite, montmorillonite and other clay minerals. X-ray diffraction studies are required for positive identification. It was first described in 1826, and subsequently named after, the Belgian people, Belgian geologist Jean Baptiste Julien d'Omalius d'Halloy, Omalius d'Halloy. Structure Halloysite naturally occurs as small cylinders (nanotubes) that have a wall thickness of 10–15 atomic aluminosilicate sheets, an outer diameter of 50–60 nm, an inner diameter of 12–15 nm, and a length of 0.5–10 μm. Their outer surface is mostly composed of SiO2 and the inner surface of Al2O3, and hence those surfaces are opposit ...
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Industrial Mineral
Industrial resources (minerals) are geological materials that are mined for their commercial value, which are not fuel ( fuel minerals or mineral fuels) and are not sources of metals (metallic minerals) but are used in the industries based on their physical and/or chemical properties. They are used in their natural state or after beneficiation either as raw materials or as additives in a wide range of applications. Examples and applications Typical examples of industrial rocks and minerals are limestone, clays, sand, gravel, diatomite, kaolin, bentonite, silica, barite, gypsum, and talc. Some examples of applications for industrial minerals are construction, ceramics, paints, electronics, filtration, plastics, glass, detergents and paper. In some cases, even organic materials (peat) and industrial products or by-products (cement, slag, silica fume) are categorized under industrial minerals, as well as metallic compounds mainly utilized in non-metallic form (as an example ...
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Serpentine Group
Serpentine subgroup (part of the kaolinite-serpentine group in the category of phyllosilicates) are greenish, brownish, or spotted minerals commonly found in serpentinite. They are used as a source of magnesium and asbestos, and as decorative stone. The name comes from the greenish color and smooth or scaly appearance from the Latin , meaning "snake-like". Serpentine subgroup is a set of common rock-forming hydrous magnesium iron phyllosilicate () minerals, resulting from the metamorphism of the minerals that are contained in mafic to ultramafic rocks. They may contain minor amounts of other elements including chromium, manganese, cobalt or nickel. In mineralogy and gemology, serpentine may refer to any of the 20 varieties belonging to the serpentine subgroup. Owing to admixture, these varieties are not always easy to individualize, and distinctions are not usually made. There are three important mineral polymorphs of serpentine: antigorite, lizardite and chrysotile. ...
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Feldspar
Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) feldspars and the ''alkali'' (potassium-sodium) feldspars. Feldspars make up about 60% of the Earth's crust and 41% of the Earth's continental crust by weight. Feldspars crystallize from magma as both intrusive and extrusive igneous rocks and are also present in many types of metamorphic rock. Rock formed almost entirely of calcic plagioclase feldspar is known as anorthosite. Feldspars are also found in many types of sedimentary rocks. Etymology The name ''feldspar'' derives from the German , a compound of the words ' ("field") and ("flake"). had long been used as the word for "a rock easily cleaved into flakes"; was introduced in the 18th century as a more specific term, referring perhaps to its comm ...
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Cation-exchange Capacity
Cation-exchange capacity (CEC) is a measure of how many cations can be retained on soil particle surfaces. Negative charges on the surfaces of soil particles bind positively-charged atoms or molecules (cations), but allow these to exchange with other positively charged particles in the surrounding soil water. This is one of the ways that solid materials in soil alter the chemistry of the soil. CEC affects many aspects of soil chemistry, and is used as a measure of soil fertility, as it indicates the capacity of the soil to retain several nutrients (e.g. K+, NH4+, Ca2+) in plant-available form. It also indicates the capacity to retain pollutant cations (e.g. Pb2+). Definition and principles Cation-exchange capacity is defined as the amount of positive charge that can be exchanged per mass of soil, usually measured in cmolc/kg. Some texts use the older, equivalent units me/100g or meq/100g. CEC is measured in moles of electric charge, so a cation-exchange capacity of 10 cmolc/kg co ...
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Silicon
Silicon is a chemical element; it has symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic lustre, and is a tetravalent metalloid (sometimes considered a non-metal) and semiconductor. It is a member of group 14 in the periodic table: carbon is above it; and germanium, tin, lead, and flerovium are below it. It is relatively unreactive. Silicon is a significant element that is essential for several physiological and metabolic processes in plants. Silicon is widely regarded as the predominant semiconductor material due to its versatile applications in various electrical devices such as transistors, solar cells, integrated circuits, and others. These may be due to its significant band gap, expansive optical transmission range, extensive absorption spectrum, surface roughening, and effective anti-reflection coating. Because of its high chemical affinity for oxygen, it was not until 1823 that Jöns Jakob Berzelius was first able to p ...
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Shrink–swell Capacity
The shrink–swell capacity of soils refers to the extent certain clay minerals will expand when wet and retract when dry. Soil with a high shrink–swell capacity is problematic and is known as shrink–swell soil, or expansive soil. The amount of certain clay minerals that are present, such as montmorillonite and smectite, directly affects the shrink-swell capacity of soil. This ability to drastically change volume can cause damage to existing structures, such as cracks in foundations or the walls of swimming pools. Description Due to the physical and chemical properties of some claysNagel, David. "Soil Science for Vegetable Producers." MSU: Coordinated Access to the Research and Extension System. 2001. Mississippi State U. 6 July 2008 http://msucares.com/pubs/publications/p1977.htm. (such as the Lias Group) large swelling occurs when water is absorbed. Conversely when the water dries up these clays contract (shrink). The presence of these clay minerals is what allows soils to ...
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Phyllosilicates
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, the crystalline forms of silica (silicon dioxide, ) are usually considered to be Silicate mineral#Tectosilicates, tectosilicates, and they are classified as such in the Dana system (75.1). However, the Nickel-Strunz system classifies them as oxide minerals (4.DA). Silica is found in nature as the mineral quartz, and its polymorphism (materials science), polymorphs. On Earth, a wide variety of silicate minerals occur in an even wider range of combinations as a result of the processes that have been forming and re-working the crust for billions of years. These processes include partial melting, crystallization, fractionation, metamorphism, weathering, and diagenesis. Living organisms also contribute to this carbonate–silicate cycle, geologic cycle. For example, a type of plankton ...
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Iron Oxide
An iron oxide is a chemical compound composed of iron and oxygen. Several iron oxides are recognized. Often they are non-stoichiometric. Ferric oxyhydroxides are a related class of compounds, perhaps the best known of which is rust. Iron oxides and oxyhydroxides are widespread in nature and play an important role in many geological and biological processes. They are used as iron ores, pigments, catalysts, and in thermite, and occur in hemoglobin. Iron oxides are inexpensive and durable pigments in paints, coatings and colored concretes. Colors commonly available are in the " earthy" end of the yellow/orange/red/brown/black range. When used as a food coloring, it has E number E172. Stoichiometries Iron oxides feature as ferrous ( Fe(II)) or ferric ( Fe(III)) or both. They adopt octahedral or tetrahedral coordination geometry. Only a few oxides are significant at the earth's surface, particularly wüstite, magnetite, and hematite. * Oxides of FeII ** FeO: ir ...
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