Hydroxyl-terminated Polybutadiene
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Hydroxyl-terminated Polybutadiene
Hydroxyl-terminated polybutadiene (HTPB) is an oligomer of butadiene terminated at each end with a hydroxyl functional group. It reacts with isocyanates to form polyurethane polymers. HTPB is a translucent liquid with a color similar to wax paper and a viscosity similar to corn syrup. The properties vary because HTPB is a mixture rather than a pure compound, and it is manufactured to meet customers' specific requirements. A typical HTPB is R-45HTLO. This product consists of oligomeric units typically containing 40–50 butadiene molecules bonded together, with each end of the chain terminated with a hydroxyl Hgroup: R-45HTLO has a functionality of 2.4-2.6, which means that there is (approximately) one additional hydroxyl group located along the chain for every two oligomeric units. This provides side-to-side linkage for a stronger cured product. HTPB is usually cured by an addition reaction with di- or poly-isocyanate compounds. Uses Materials Production Polyurethanes prepare ...
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Oligomer
In chemistry and biochemistry, an oligomer () is a molecule that consists of a few repeating units which could be derived, actually or conceptually, from smaller molecules, monomers.Quote: ''Oligomer molecule: A molecule of intermediate relative molecular mass, the structure of which essentially comprises a small plurality of units derived, actually or conceptually, from molecules of lower relative molecular mass.'' The name is composed of Greek elements '' oligo-'', "a few" and '' -mer'', "parts". An adjective form is ''oligomeric''. The oligomer concept is contrasted to that of a polymer, which is usually understood to have a large number of units, possibly thousands or millions. However, there is no sharp distinction between these two concepts. One proposed criterion is whether the molecule's properties vary significantly with the removal of one or a few of the units. An oligomer with a specific number of units is referred to by the Greek prefix denoting that number, wi ...
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Synthetic Fibers
Synthetic fibers or synthetic fibres (in British English; see spelling differences) are fibers made by humans through chemical synthesis, as opposed to natural fibers that are directly derived from living organisms, such as plants (like cotton) or fur from animals. They are the result of extensive research by scientists to replicate naturally occurring animal and plant fibers. In general, synthetic fibers are created by extruding fiber-forming materials through spinnerets, forming a fiber. These are called synthetic or artificial fibers. The word polymer comes from a Greek prefix "poly" which means "many" and suffix "mer" which means "single units". (Note: each single unit of a polymer is called a monomer). Early experiments The first fully synthetic fiber was glass. Joseph Swan invented one of the first artificial fibers in the early 1880s; today it would be called semisynthetic in precise usage. His fiber was drawn from a cellulose liquid, formed by chemically modifying ...
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Black Powder
Gunpowder, also commonly known as black powder to distinguish it from modern smokeless powder, is the earliest known chemical explosive. It consists of a mixture of sulfur, carbon (in the form of charcoal) and potassium nitrate (saltpeter). The sulfur and carbon act as fuels while the saltpeter is an oxidizer. Gunpowder has been widely used as a propellant in firearms, artillery, rocketry, and pyrotechnics, including use as a blasting agent for explosives in quarrying, mining, building pipelines and road building. Gunpowder is classified as a low explosive because of its relatively slow decomposition rate and consequently low brisance. Low explosives deflagrate (i.e., burn at subsonic speeds), whereas high explosives detonate, producing a supersonic shockwave. Ignition of gunpowder packed behind a projectile generates enough pressure to force the shot from the muzzle at high speed, but usually not enough force to rupture the gun barrel. It thus makes a good propellant but is ...
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Specific Impulse
Specific impulse (usually abbreviated ) is a measure of how efficiently a reaction mass engine (a rocket using propellant or a jet engine using fuel) creates thrust. For engines whose reaction mass is only the fuel they carry, specific impulse is exactly proportional to the effective exhaust gas velocity. A propulsion system with a higher specific impulse uses the mass of the propellant more efficiently. In the case of a rocket, this means less propellant needed for a given delta-v, so that the vehicle attached to the engine can more efficiently gain altitude and velocity. In an atmospheric context, specific impulse can include the contribution to impulse provided by the mass of external air that is accelerated by the engine in some way, such as by an internal turbofan or heating by fuel combustion participation then thrust expansion or by external propeller. Jet engines breathe external air for both combustion and by-pass, and therefore have a much higher specific impulse than ...
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Ammonium Perchlorate Composite Propellant
Ammonium perchlorate composite propellant (APCP) is a solid-propellant rocket fuel. It differs from many traditional solid rocket propellants such as black powder or zinc-sulfur, not only in chemical composition and overall performance but also by the nature of how it is processed. APCP is cast into shape, as opposed to powder pressing as with black powder. This provides manufacturing regularity and repeatability, which are necessary requirements for use in the aerospace industry. Uses Ammonium perchlorate composite propellant is typically for aerospace rocket propulsion where simplicity and reliability are desired and specific impulses (depending on the composition and operating pressure) of are adequate. Because of these performance attributes, APCP has been used in the Space Shuttle Solid Rocket Boosters, aircraft ejection seats, and specialty space exploration applications such as NASA's Mars Exploration Rover descent stage retrorockets. In addition, the high-power rocket ...
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Aluminum
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It has a great affinity towards oxygen, and forms a protective layer of oxide on the surface when exposed to air. Aluminium visually resembles silver, both in its color and in its great ability to reflect light. It is soft, non-magnetic and ductile. It has one stable isotope, 27Al; this isotope is very common, making aluminium the twelfth most common element in the Universe. The radioactivity of 26Al is used in radiodating. Chemically, aluminium is a post-transition metal in the boron group; as is common for the group, aluminium forms compounds primarily in the +3 oxidation state. The aluminium cation Al3+ is small and highly charged; as such, it is polarizing, and bonds aluminium forms tend towards covalency. The strong affinity towards ox ...
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Ammonium Perchlorate
Ammonium perchlorate ("AP") is an inorganic compound with the formula NH4 ClO4. It is a colorless or white solid that is soluble in water. It is a powerful oxidizer. Combined with a fuel, it can be used as a rocket propellant called ammonium perchlorate composite propellant. Its instability has involved it in a number of accidents, such as the PEPCON disaster. Production Ammonium perchlorate (AP) is produced by reaction between ammonia and perchloric acid. This process is the main outlet for the industrial production of perchloric acid. The salt also can be produced by salt metathesis reaction of ammonium salts with sodium perchlorate. This process exploits the relatively low solubility of NH4ClO4, which is about 10% of that for sodium perchlorate.Helmut Vogt, Jan Balej, John E. Bennett, Peter Wintzer, Saeed Akbar Sheikh, Patrizio Gallone "Chlorine Oxides and Chlorine Oxygen Acids" in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH. AP crystallises as colorle ...
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JAXA
The is the Japanese national air and space agency. Through the merger of three previously independent organizations, JAXA was formed on 1 October 2003. JAXA is responsible for research, technology development and launch of satellites into orbit, and is involved in many more advanced missions such as asteroid exploration and possible human exploration of the Moon. Its motto is ''One JAXA'' and its corporate slogan is ''Explore to Realize'' (formerly ''Reaching for the skies, exploring space''). History On 1 October 2003, three organizations were merged to form the new JAXA: Japan's Institute of Space and Astronautical Science (ISAS), the National Aerospace Laboratory of Japan (NAL), and National Space Development Agency of Japan (NASDA). JAXA was formed as an Independent Administrative Institution administered by the Ministry of Education, Culture, Sports, Science and Technology (MEXT) and the Ministry of Internal Affairs and Communications (MIC). Before the merger, ISA ...
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ISRO
The Indian Space Research Organisation (ISRO; ) is the national space agency of India, headquartered in Bengaluru. It operates under the Department of Space (DOS) which is directly overseen by the Prime Minister of India, while the Chairman of ISRO acts as the executive of DOS as well. ISRO is India's primary agency for performing tasks related to space-based applications, space exploration and the development of related technologies. It is one of six government space agencies in the world which possess full launch capabilities, deploy cryogenic engines, launch extraterrestrial missions and operate large fleets of artificial satellites. The Indian National Committee for Space Research (INCOSPAR) was established by Jawaharlal Nehru under the Department of Atomic Energy (DAE) in 1962, on the urging of scientist Vikram Sarabhai, recognising the need in space research. INCOSPAR grew and became ISRO in 1969, within DAE. In 1972, the government of India set up a Space Commissio ...
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PSLV
The Polar Satellite Launch Vehicle (PSLV) is an expendable medium-lift launch vehicle designed and operated by the Indian Space Research Organisation (ISRO). It was developed to allow India to launch its Indian Remote Sensing (IRS) satellites into sun-synchronous orbits, a service that was, until the advent of the PSLV in 1993, only commercially available from Russia. PSLV can also launch small size satellites into Geostationary Transfer Orbit (GTO). Some notable payloads launched by PSLV include India's first lunar probe Chandrayaan-1, India's first interplanetary mission, Mars Orbiter Mission (Mangalyaan) and India's first space observatory, Astrosat. PSLV has gained credibility as a leading provider of rideshare services for small satellites, owing to its numerous multi-satellite deployment campaigns with auxiliary payloads, usually ride-sharing along with an Indian primary payload. As of June 2022, PSLV has launched 345 foreign satellites from 36 countries. Most notab ...
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M-5 Rocket
The M-V rocket, also called M-5 or Mu-5, was a Japanese solid-fuel rocket designed to launch scientific satellites. It was a member of the Mu family of rockets. The Institute of Space and Astronautical Science (ISAS) began developing the M-V in 1990 at a cost of 15 billion yen. It has three stages and is high, in diameter, and weighs about . It was capable of launching a satellite weighing into an orbit as high as . The first M-V rocket launched the HALCA radio astronomy satellite in 1997, and the second the Nozomi Mars explorer in July 1998. The third rocket attempted to launch the Astro-E X-ray satellite on 10 February 2000 but failed. ISAS recovered from this setback and launched Hayabusa to 25143 Itokawa in 2003. The following M-V launch was the scientific Astro-E2 satellite, a replacement for Astro-E, which took place on 10 July 2005. The final launch was that of the Hinode (SOLAR-B) spacecraft, along with the SSSat microsat and a nanosatellite, HIT-SAT, on 22 Septe ...
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Oxidizing Agent
An oxidizing agent (also known as an oxidant, oxidizer, electron recipient, or electron acceptor) is a substance in a redox chemical reaction that gains or "Electron acceptor, accepts"/"receives" an electron from a (called the , , or ). In other words, an oxidizer is any substance that oxidizes another substance. The oxidation state, which describes the degree of loss of electrons, of the oxidizer decreases while that of the reductant increases; this is expressed by saying that oxidizers "undergo reduction" and "are reduced" while reducers "undergo oxidation" and "are oxidized". Common oxidizing agents are oxygen, hydrogen peroxide and the halogens. In one sense, an oxidizing agent is a chemical species that undergoes a chemical reaction in which it gains one or more electrons. In that sense, it is one component in an Redox, oxidation–reduction (redox) reaction. In the second sense, an oxidizing agent is a chemical species that transfers electronegative atoms, usually oxygen ...
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