Hydrolyzable Tannins
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Hydrolyzable Tannins
A hydrolyzable tannin or pyrogallol-type tannin is a type of tannin that, on heating with hydrochloric or sulfuric acids, yields gallic or ellagic acids. At the center of a hydrolyzable tannin molecule, there is a carbohydrate (usually D-glucose but also cyclitols like quinic or shikimic acids). The hydroxyl groups of the carbohydrate are partially or totally esterified with phenolic groups such as gallic acid in gallotannins or ellagic acid in ellagitannins. Hydrolysable tannins are mixtures of polygalloyl glucoses and/or poly-galloyl quinic acid derivatives containing in between 3 up to 12 gallic acid residues per molecule. Hydrolyzable tannins are hydrolyzed by weak acids or weak bases to produce carbohydrate and phenolic acids. Examples of gallotannins are the gallic acid esters of glucose in tannic acid (C76H52O46), found in the leaves and bark of many plant species. Hydrolysable tannins can be extracted from different vegetable plants, such as chestnut wood ('' Castanea ...
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Pyrogallol
Pyrogallol is an organic compound with the formula C6H3(OH)3. It is a water-soluble, white solid although samples are typically brownish because of its sensitivity toward oxygen. It is one of three isomers of benzenetriols. Production and reactions It is produced in the manner first reported by Scheele in 1786: heating gallic acid to induce decarboxylation. Gallic acid is also obtained from tannin. Many alternative routes have been devised. One preparation involves treating ''para''-chlorophenoldisulfonic acid with potassium hydroxide, a variant on the time-honored route to phenols from sulfonic acids. When in alkaline solution, pyrogallol undergoes deprotonation of one or more phenolic groups. Such solutions absorb oxygen from the air, turning brown. This conversion can be used to determine the amount of oxygen in a gas sample, notably by the use of the Orsat apparatus. Polyhydroxybenzenes are relatively electron-rich. One manifestation is the easy C-acetylation of pyrog ...
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Glucose
Glucose is a simple sugar with the molecular formula . Glucose is overall the most abundant monosaccharide, a subcategory of carbohydrates. Glucose is mainly made by plants and most algae during photosynthesis from water and carbon dioxide, using energy from sunlight, where it is used to make cellulose in cell walls, the most abundant carbohydrate in the world. In energy metabolism, glucose is the most important source of energy in all organisms. Glucose for metabolism is stored as a polymer, in plants mainly as starch and amylopectin, and in animals as glycogen. Glucose circulates in the blood of animals as blood sugar. The naturally occurring form of glucose is -glucose, while -glucose is produced synthetically in comparatively small amounts and is less biologically active. Glucose is a monosaccharide containing six carbon atoms and an aldehyde group, and is therefore an aldohexose. The glucose molecule can exist in an open-chain (acyclic) as well as ring (cyclic) form. Gluco ...
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Quercus Infectoria
''Quercus infectoria'' or the Aleppo oak is a species of oak well known for producing galls (called manjakani in Malaysia, majuphal in India) that have been traditionally used for centuries in Asia medicinally while also used in softening leather and in making black dye and ink. Description ''Quercus infectoria'' is a small tree, growing to in height. The stems are crooked, shrubby looking with smooth and bright-green leaves borne on short petioles of long. The leaves are bluntly mucronate, rounded, smooth, unequal at the base and shiny on the upper side. The galls arise on young branches of the tree when gall wasps sting the oak tree and deposit their larvae. The chemical reaction causes an abnormality in the tree, causing hard balls to be formed. They are corrugated in appearance. Gall chemistry The galls from ''Quercus infectoria'' contain the highest naturally occurring level of tannin, approximately 50–70%, as well as syringic acid, β-sitosterol, amentoflavone, hexam ...
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Gall
Galls (from the Latin , 'oak-apple') or ''cecidia'' (from the Greek , anything gushing out) are a kind of swelling growth on the external tissues of plants, fungi, or animals. Plant galls are abnormal outgrowths of plant tissues, similar to benign tumors or warts in animals. They can be caused by various parasites, from viruses, fungi and bacteria, to other plants, insects and mites. Plant galls are often highly organized structures so that the cause of the gall can often be determined without the actual agent being identified. This applies particularly to some insect and mite plant galls. The study of plant galls is known as cecidology. In human pathology, a gall is a raised sore on the skin, usually caused by chafing or rubbing. Causes of plant galls Insects and mites Insect galls are the highly distinctive plant structures formed by some herbivorous insects as their own microhabitats. They are plant tissue which is controlled by the insect. Galls act as both the habitat a ...
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Caesalpinia Spinosa
''Tara spinosa'', commonly known as ''tara'' (Quechua), also known as Peruvian carob or spiny holdback, is a small leguminous tree or thorny shrub native to Peru. ''T. spinosa'' is cultivated as a source of tannins based on a galloylated quinic acid structure. This chemical structure has been confirmed also by LC-MS.M. N. Clifford, S. Stoupi and N. Kuhnert''Profiling and Characterization by LC-MSn of the Galloylquinic Acids of Green Tea, Tara Tannin, and Tannic Acid'' J. Agric. Food Chem., 2007, 55 (8), pp. 2797-2807. DOI: 10.1021/jf063533l. Publication Date (Web): March 24, 2007. It is also grown as an ornamental plant because of its large colorful flowers and pods. Names and taxonomy Its common names include spiny holdback,'' tara, taya,'' and '' algarroba tanino'' (Peru). ''T. spinosa'' is placed in the family Fabaceae, subfamily Caesalpinioideae, and tribe Caesalpinieae. Description ''T. spinosa'' typically grows 2–5 m tall; its bark is dark gray with scattered prickles ...
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Quercus Alba
An oak is a tree or shrub in the genus ''Quercus'' (; Latin "oak tree") of the beech family, Fagaceae. There are approximately 500 extant species of oaks. The common name "oak" also appears in the names of species in related genera, notably '' Lithocarpus'' (stone oaks), as well as in those of unrelated species such as ''Grevillea robusta'' (silky oaks) and the Casuarinaceae (she-oaks). The genus ''Quercus'' is native to the Northern Hemisphere, and includes deciduous and evergreen species extending from cool temperate to tropical latitudes in the Americas, Asia, Europe, and North Africa. North America has the largest number of oak species, with approximately 160 species in Mexico of which 109 are endemic and about 90 in the United States. The second greatest area of oak diversity is China, with approximately 100 species. Description Oaks have spirally arranged leaves, with lobate margins in many species; some have serrated leaves or entire leaves with smooth margins. ...
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Quercus Petraea
''Quercus petraea'', commonly known as the sessile oak, Cornish oak, Irish Oak or durmast oak, is a species of oak tree native to most of Europe and into Anatolia and Iran. The sessile oak is the national tree of Ireland, and an unofficial emblem in Wales and Cornwall. Description The sessile oak is a large deciduous tree up to tall, in the white oak section of the genus (''Quercus'' sect. ''Quercus'') and similar to the pedunculate oak (''Q. robur''), with which it overlaps extensively in range. The leaves are long and broad, evenly lobed with five to six lobes on each side and a petiole. The male flowers are grouped into catkins, produced in the spring. The fruit is an acorn long and broad, which matures in about six months. Comparison with pedunculate oak Significant botanical differences from pedunculate oak (''Q. robur'') include the stalked leaves, and the stalkless (sessile) acorns from which one of its common names is derived. It occurs in upl ...
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Quercus Robur
''Quercus robur'', commonly known as common oak, pedunculate oak, European oak or English oak, is a species of flowering plant in the beech and oak family, Fagaceae. It is a large tree, native plant, native to most of Europe west of the Caucasus. It is widely cultivated in temperate regions elsewhere and has escaped into the wild in scattered parts of China and North America. Description ''Quercus robur'' is a large deciduous tree, with circumference of grand oaks from to an exceptional . The Majesty Oak with a circumference of is the thickest tree in Great Britain. The Brureika (Bridal Oak) in Norway with a circumference of (2018) and the Kaive Oak in Latvia with a circumference of are among the thickest trees in Northern Europe. The largest historical oak was known as the Imperial Oak from Bosnia and Herzegovina. This specimen was recorded at 17.5 m in circumference at breast height and estimated at over 150 m³ in total volume. It collapsed in 1998. The species has l ...
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Castanea Sativa
''Castanea sativa'', the sweet chestnut, Spanish chestnut or just chestnut, is a species of tree in the family Fagaceae, native to Southern Europe and Asia Minor, and widely cultivated throughout the temperate world. A substantial, long-lived deciduous tree, it produces an edible seed, the chestnut, which has been used in cooking since ancient times. Description ''C. sativa'' attains a height of with a trunk often in diameter. Around 20 trees are recorded with diameters over including one in diameter at breast height. A famous ancient tree known as the Hundred Horse Chestnut in Sicily was historically recorded at in diameter (although it has split into multiple trunks above ground). The bark often has a net-shaped (retiform) pattern with deep furrows or fissures running spirally in both directions up the trunk. The trunk is mostly straight with branching starting at low heights. The oblong-lanceolate, boldly toothed leaves are long and broad. The flowers of both sexe ...
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Chestnut
The chestnuts are the deciduous trees and shrubs in the genus ''Castanea'', in the beech family Fagaceae. They are native to temperate regions of the Northern Hemisphere. The name also refers to the edible nuts they produce. The unrelated horse chestnuts (genus ''Aesculus'') are not true chestnuts, but are named for producing nuts of similar appearance that are mildly poisonous to humans. True chestnuts should also not be confused with water chestnuts, which are tubers of an aquatic herbaceous plant in the sedge family Cyperaceae. Other species commonly mistaken for chestnut trees are the chestnut oak ('' Quercus prinus'') and the American beech (''Fagus grandifolia''),Chestnut Tree
in chestnuttree.net.
both of which are also in the Fagaceae family.

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Plants
Plants are predominantly Photosynthesis, photosynthetic eukaryotes of the Kingdom (biology), kingdom Plantae. Historically, the plant kingdom encompassed all living things that were not animals, and included algae and fungi; however, all current definitions of Plantae exclude the fungi and some algae, as well as the prokaryotes (the archaea and bacteria). By one definition, plants form the clade Viridiplantae (Latin name for "green plants") which is sister of the Glaucophyte, Glaucophyta, and consists of the green algae and Embryophyte, Embryophyta (land plants). The latter includes the flowering plants, conifers and other gymnosperms, ferns and Fern ally, their allies, hornworts, liverworts, and mosses. Most plants are multicellular organisms. Green plants obtain most of their energy from sunlight via photosynthesis by primary chloroplasts that are derived from endosymbiosis with cyanobacteria. Their chloroplasts contain chlorophylls a and b, which gives them their green colo ...
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Plant
Plants are predominantly photosynthetic eukaryotes of the kingdom Plantae. Historically, the plant kingdom encompassed all living things that were not animals, and included algae and fungi; however, all current definitions of Plantae exclude the fungi and some algae, as well as the prokaryotes (the archaea and bacteria). By one definition, plants form the clade Viridiplantae (Latin name for "green plants") which is sister of the Glaucophyta, and consists of the green algae and Embryophyta (land plants). The latter includes the flowering plants, conifers and other gymnosperms, ferns and their allies, hornworts, liverworts, and mosses. Most plants are multicellular organisms. Green plants obtain most of their energy from sunlight via photosynthesis by primary chloroplasts that are derived from endosymbiosis with cyanobacteria. Their chloroplasts contain chlorophylls a and b, which gives them their green color. Some plants are parasitic or mycotrophic and have lost the ...
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