Hisingerite
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Hisingerite
Hisingerite is an iron(III) phyllosilicate mineral with formula . A black or dark brown, lustrous secondary mineral, it is formed by the weathering or hydrothermal alteration of other iron silicate and sulfide minerals. It was first described in 1751 by A.F. Cronstedt from Väster Silvberg, Dalarna, Sweden (under the name “kolspeglande järnmalm”), and in 1810 by W. Hisinger from the Gillinge iron mine, Södermanland, Sweden (“svart stenart”, later “gillingit”). In 1828 it was found at an occurrence in Riddarhyttan, Vastmanland, Sweden. It was named after Wilhelm Hisinger (1766–1852), a Swedish chemist. There are also ''aluminian hisingerite'' variety in which one of the iron atoms is replaced by aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ... and chr ...
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Wilhelm Hisinger
Wilhelm Hisinger (23 December 1766 – 28 June 1852) was a Swedish physicist and chemist who in 1807, working in coordination with Jöns Jakob Berzelius, noted that in electrolysis any given substance always went to the same pole, and that substances attracted to the same pole had other properties in common. This showed that there was at least a qualitative correlation between the chemical and electrical natures of bodies. Career In 1803, in separate laboratories, Martin Heinrich Klaproth in one, and Berzelius and Hisinger in another, the element Cerium was discovered, which was named after the newly discovered asteroid, Ceres. It was discovered nearly simultaneously by both laboratories, though it was later shown that Berzelius and Hisinger's cerium was actually a mixture of cerium, lanthanum and so-called didymium. The element was first isolated by Carl Gustaf Mosander in 1838. Hisinger was elected a member of the Royal Swedish Academy of Sciences in 1804. Death and legac ...
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Silicate Mineral
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually considered a silicate mineral. Silica is found in nature as the mineral quartz, and its polymorphs. On Earth, a wide variety of silicate minerals occur in an even wider range of combinations as a result of the processes that have been forming and re-working the crust for billions of years. These processes include partial melting, crystallization, fractionation, metamorphism, weathering, and diagenesis. Living organisms also contribute to this geologic cycle. For example, a type of plankton known as diatoms construct their exoskeletons ("frustules") from silica extracted from seawater. The frustules of dead diatoms are a major constituent of deep ocean sediment, and of diatomaceous earth. General structure A silicate mineral is generally a ...
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Hydroxyl
In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula and composed of one oxygen atom covalently bonded to one hydrogen atom. In organic chemistry, alcohols and carboxylic acids contain one or more hydroxy groups. Both the negatively charged anion , called hydroxide, and the neutral radical , known as the hydroxyl radical, consist of an unbonded hydroxy group. According to IUPAC definitions, the term ''hydroxyl'' refers to the hydroxyl radical () only, while the functional group is called a ''hydroxy group''. Properties Water, alcohols, carboxylic acids, and many other hydroxy-containing compounds can be readily deprotonated due to a large difference between the electronegativity of oxygen (3.5) and that of hydrogen (2.1). Hydroxy-containing compounds engage in intermolecular hydrogen bonding increasing the electrostatic attraction between molecules and thus to higher boiling and melting points than found for compounds that lack t ...
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Monoclinic
In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic system. They form a parallelogram prism. Hence two pairs of vectors are perpendicular (meet at right angles), while the third pair makes an angle other than 90°. Bravais lattices Two monoclinic Bravais lattices exist: the primitive monoclinic and the base-centered monoclinic. For the base-centered monoclinic lattice, the primitive cell has the shape of an oblique rhombic prism;See , row mC, column Primitive, where the cell parameters are given as a1 = a2, α = β it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. Note that the length a of the primitive cell below equals \frac \sqrt of the conventional cell above. Crystal classes The table below org ...
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Iron(III)
In chemistry, iron(III) refers to the element iron in its +3 oxidation state. In ionic compounds (salts), such an atom may occur as a separate cation (positive ion) denoted by Fe3+. The adjective ferric or the prefix ferri- is often used to specify such compounds — as in "ferric chloride" for iron(III) chloride, . The adjective "ferrous" is used instead for iron(II) salts, containing the cation Fe2+. The word ferric is derived from the Latin word ''ferrum'' for iron. Iron(III) metal centres also occur in coordination complexes, such as in the anion ferrioxalate, , where three bidentate oxalate ions surrounding the metal centre; or, in organometallic compounds, such as the ferrocenium cation , where two cyclopentadienyl anions are bound to the FeIII centre. Iron is almost always encountered in the oxidation states 0 (as in the metal), +2, or +3. Iron(III) is usually the most stable form in air, as illustrated by the pervasiveness of rust, an insoluble iron(III)-containing ...
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Phyllosilicate
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually considered a silicate mineral. Silica is found in nature as the mineral quartz, and its polymorphs. On Earth, a wide variety of silicate minerals occur in an even wider range of combinations as a result of the processes that have been forming and re-working the crust for billions of years. These processes include partial melting, crystallization, fractionation, metamorphism, weathering, and diagenesis. Living organisms also contribute to this geologic cycle. For example, a type of plankton known as diatoms construct their exoskeletons ("frustules") from silica extracted from seawater. The frustules of dead diatoms are a major constituent of deep ocean sediment, and of diatomaceous earth. General structure A silicate mineral is generally a ...
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Weathering
Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs ''in situ'' (on site, with little or no movement), and so is distinct from erosion, which involves the transport of rocks and minerals by agents such as water, ice, snow, wind, waves and gravity. Weathering processes are divided into ''physical'' and ''chemical weathering''. Physical weathering involves the breakdown of rocks and soils through the mechanical effects of heat, water, ice, or other agents. Chemical weathering involves the chemical reaction of water, atmospheric gases, and biologically produced chemicals with rocks and soils. Water is the principal agent behind both physical and chemical weathering, though atmospheric oxygen and carbon dioxide and the activities of biological organisms are also important. Chemical weathering by biological action is also known as biologic ...
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Hydrothermal Alteration
Metasomatism (from the Greek μετά ''metá'' "change" and σῶμα ''sôma'' "body") is the chemical alteration of a rock by hydrothermal and other fluids. It is the replacement of one rock by another of different mineralogical and chemical composition. The minerals which compose the rocks are dissolved and new mineral formations are deposited in their place. Dissolution and deposition occur simultaneously and the rock remains solid. Synonyms to the word metasomatism are metasomatose and metasomatic process. The word metasomatose can also be used as a name for specific varieties of metasomatism (for example '' Mg-metasomatose'' and '' Na-metasomatose''). Metasomatism can occur via the action of hydrothermal fluids from an igneous or metamorphic source. In the igneous environment, metasomatism creates skarns, greisen, and may affect hornfels in the contact metamorphic aureole adjacent to an intrusive rock mass. In the metamorphic environment, metasomatism is created by m ...
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Sulfide Mineral
The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the arsenides, the antimonides, the bismuthinides, the sulfarsenides and the sulfosalts.http://www.minerals.net/mineral/sort-met.hod/group/sulfgrp.htm Minerals.net Dana Classification, SulfidesKlein, Cornelis and Cornelius S. Hurlbut, Jr., 1986, ''Manual of Mineralogy'', Wiley, 20th ed., pp 269-293 Sulfide minerals are inorganic compounds. Minerals Common or important examples include: * Acanthite *Chalcocite *Bornite *Galena *Sphalerite * Chalcopyrite * Pyrrhotite * Millerite * Pentlandite * Covellite * Cinnabar * Realgar *Orpiment * Stibnite *Pyrite * Marcasite *Molybdenite Sulfarsenides: *Cobaltite *Arsenopyrite * Gersdorffite Sulfosalts: * Pyrargyrite * Proustite *Tetrahedrite * Tennantite * Enargite * B ...
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Axel Fredrik Cronstedt
Baron Axel Fredrik Cronstedt (''/kroonstet/'' 23 December 1722 – 19 August 1765) was a Swedish mineralogist and chemist who discovered the element nickel in 1751 as a mining expert with the Bureau of Mines. Cronstedt is considered a founder of modern mineralogy, for introducing the blowpipe as a tool for mineralogists, and for proposing that the mineral kingdom be organized on the basis of chemical analysis in his book ''Försök til mineralogie, eller mineral-rikets upställning'' (“An attempt at mineralogy or arrangement of the Mineral Kingdom”, 1758). Life Axel Fredrik Cronstedt was born on 23 December 1722 on the estate of Ströpsta, in Sudermania. His father, Gabriel Olderman Cronstedt (1670–1757), was a military engineer. His mother, Maria Elizabeth Adlersberg, was Gabriel Cronstedt's second wife. Beginning in 1738, Axel Cronstedt was an unregistered student at the University of Uppsala, hearing lectures with Johan Gottschalk Wallerius (1709–1785), ...
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Sweden
Sweden, formally the Kingdom of Sweden,The United Nations Group of Experts on Geographical Names states that the country's formal name is the Kingdom of SwedenUNGEGN World Geographical Names, Sweden./ref> is a Nordic countries, Nordic country located on the Scandinavian Peninsula in Northern Europe. It borders Norway to the west and north, Finland to the east, and is connected to Denmark in the southwest by Øresund Bridge, a bridgetunnel across the Öresund. At , Sweden is the largest Nordic country, the third-largest country in the European Union, and the List of European countries by area, fifth-largest country in Europe. The Capital city, capital and largest city is Stockholm. Sweden has a total population of 10.5 million, and a low population density of , with around 87% of Swedes residing in urban areas in the central and southern half of the country. Sweden has a nature dominated by forests and a large amount of lakes, including List of largest lakes of Europ ...
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