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Herapathite
Herapathite, or iodoquinine sulfate, is a chemical compound whose crystals are dichroic and thus can be used for polarizing light. It was discovered in 1852 by William Bird Herapath, a Bristol surgeon and chemist. One of his pupils found that adding iodine to the urine of a dog that had been fed quinine produced unusual green crystals. Herapath noticed while studying the crystals under a microscope that they appeared to polarize light. In the 1930s, invented a process to grow single herapathite crystals large enough to be sandwiched between two sheets of glass to create a polarizing filter; these were sold under the Bernotar name by Carl Zeiss. Herapathite can be formed by precipitation by dissolving quinine sulfate in acetic acid and adding iodine tincture. Herapathite's dichroic properties came to the attention of Sir David Brewster, and were later used by Edwin H. Land in 1929 to construct the first type of Polaroid sheet polarizer. He did this by embedding herapathite crysta ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
William Bird Herapath
Dr William Bird Herapath FRS FRSE FRCS (28 February 1820 – 12 October 1868) was an English surgeon and chemist known for his discovery of Herapathite. Life He was born in Bristol, the eldest son of William Herapath, Professor of Chemistry at Bristol Medical School and educated at London University, where he was awarded M.B. in 1844. He worked as a surgeon at Queen Elizabeth Hospital, Bristol and St Peter's Hospital, Bristol and was awarded M.D. in 1851. He published many articles in medical, chemical, and other scientific journals and was vice-president of the Bristol Microscopical Society. In 1852 one of his pupils found that adding iodine to the urine of a dog that had been fed quinine produced unusual green crystals. Herapath noticed while studying the crystals under a microscope that they appeared to polarize light and patented the discovery for optical use as Herapathite. He described it as artificial tourmaline, a semi-precious gem. He went on to develop new analytica ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quinine
Quinine is a medication used to treat malaria and babesiosis. This includes the treatment of malaria due to ''Plasmodium falciparum'' that is resistant to chloroquine when artesunate is not available. While sometimes used for nocturnal leg cramps, quinine is not recommended for this purpose due to the risk of serious side effects. It can be taken by mouth or intravenously. Malaria resistance to quinine occurs in certain areas of the world. Quinine is also used as an ingredient in tonic water to impart a bitter taste. Common side effects include headache, ringing in the ears, vision issues, and sweating. More severe side effects include deafness, low blood platelets, and an irregular heartbeat. Use can make one more prone to sunburn. While it is unclear if use during pregnancy causes harm to the baby, treating malaria during pregnancy with quinine when appropriate is still recommended. Quinine is an alkaloid, a naturally occurring chemical compound. How it works as a medicin ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Acetic Acid
Acetic acid , systematically named ethanoic acid , is an acidic, colourless liquid and organic compound with the chemical formula (also written as , , or ). Vinegar is at least 4% acetic acid by volume, making acetic acid the main component of vinegar apart from water and other trace elements. Acetic acid is the second simplest carboxylic acid (after formic acid). It is an important Reagent, chemical reagent and industrial chemical, used primarily in the production of cellulose acetate for photographic film, polyvinyl acetate for wood Adhesive, glue, and synthetic fibres and fabrics. In households, diluted acetic acid is often used in descaling agents. In the food industry, acetic acid is controlled by the E number, food additive code E260 as an acidity regulator and as a condiment. In biochemistry, the acetyl group, derived from acetic acid, is fundamental to all forms of life. When bound to coenzyme A, it is central to the metabolism of carbohydrates and fats. The global ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitrogen Heterocycles
Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at seventh in total abundance in the Milky Way and the Solar System. At standard temperature and pressure, two atoms of the element bond to form N2, a colorless and odorless diatomic gas. N2 forms about 78% of Earth's atmosphere, making it the most abundant uncombined element. Nitrogen occurs in all organisms, primarily in amino acids (and thus proteins), in the nucleic acids ( DNA and RNA) and in the energy transfer molecule adenosine triphosphate. The human body contains about 3% nitrogen by mass, the fourth most abundant element in the body after oxygen, carbon, and hydrogen. The nitrogen cycle describes the movement of the element from the air, into the biosphere and organic compounds, then back into the atmosphere. Many industrially importa ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polyiodide
The polyiodides are a class of polyhalogen anions composed entirely of iodine atoms. The most common and simplest member is the triiodide ion, . Other known larger polyiodides include 4sup>2−, 5sup>−, 6sup>2−, 7sup>−, 8sup>2−, 9sup>−, 10sup>2−, 10sup>4−, 11sup>3−, 12sup>2−, 13sup>3−, 14sup>4-, 16sup>2−, 22sup>4−, 26sup>3−, 26sup>4−, 28sup>4− and 29sup>3−. All these can be considered as formed from the interaction of the I–, I2, and building blocks. Preparation The polyiodides can be made by addition of stoichiometric amounts of I2 to solutions containing I− and , with the presence of large countercations to stabilize them. For example, KI3·H2O can be crystallized from a saturated solution of KI when a stoichiometric amount of I2 is added and cooled. Structure ] ] Polyiodides are characterized by their highly complex and variable structures, and can be considered as associations of I2, I−, and units. Discrete polyiodid ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrate
In chemistry, a hydrate is a substance that contains water or its constituent elements. The chemical state of the water varies widely between different classes of hydrates, some of which were so labeled before their chemical structure was understood. Chemical nature Inorganic chemistry Hydrates are inorganic salts "containing water molecules combined in a definite ratio as an integral part of the crystal" that are either bound to a metal center or that have crystallized with the metal complex. Such hydrates are also said to contain ''water of crystallization'' or ''water of hydration''. If the water is heavy water in which the constituent hydrogen is the isotope deuterium, then the term ''deuterate'' may be used in place of ''hydrate''. A colorful example is cobalt(II) chloride, which turns from blue to red upon hydration, and can therefore be used as a water indicator. The notation "''hydrated compound''⋅''n''", where ''n'' is the number of water molecules per formula un ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Triiodide
In chemistry, triiodide usually refers to the triiodide ion, . This anion, one of the polyhalogen ions, is composed of three iodine atoms. It is formed by combining aqueous solutions of iodide salts and iodine. Some salts of the anion have been isolated, including thallium(I) triiodide (Tl+ 3sup>−) and ammonium triiodide ( H4sup>+ 3sup>−). Triiodide is observed to be a red colour in solution. Nomenclature Other chemical compounds with "triiodide" in their name may contain three iodide centers that are not bonded to each other as the triiodide ion, but exist instead as separate iodine atoms or iodide ions. Examples include nitrogen triiodide (NI3) and phosphorus triiodide (PI3), where individual iodine atoms are covalently bonded to a central atom. As some cations have the theoretical possibility to form compounds with both triiodide and iodide ions, such as ammonium, compounds containing iodide anions in a 3:1 stoichiometric ratio should only be referred to as triiodides ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Protonated
In chemistry, protonation (or hydronation) is the adding of a proton (or hydron, or hydrogen cation), (H+) to an atom, molecule, or ion, forming a conjugate acid. (The complementary process, when a proton is removed from a Brønsted–Lowry acid, is deprotonation.) Some examples include *The protonation of water by sulfuric acid: *:H2SO4 + H2O H3O+ + *The protonation of isobutene in the formation of a carbocation: *:(CH3)2C=CH2 + HBF4 (CH3)3C+ + *The protonation of ammonia in the formation of ammonium chloride from ammonia and hydrogen chloride: *:NH3( g) + HCl( g) → NH4Cl( s) Protonation is a fundamental chemical reaction and is a step in many stoichiometric and catalytic processes. Some ions and molecules can undergo more than one protonation and are labeled polybasic, which is true of many biological macromolecules. Protonation and deprotonation (removal of a proton) occur in most acid–base reactions; they are the core of most acid–base reaction theories. A Brønsted ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polaroid (polarizer)
A Polaroid synthetic plastic sheet is a brand name product trademarked and produced by the Polaroid Corporation used as a polarizer or polarizing filter. The term “Polaroid” entered the common vocabulary with the early 1960s introduction of patented film and cameras manufactured by the corporation that produced “instant photos”. Patent The original material, patented in 1929 and further developed in 1932 by Edwin H. Land, consists of many microscopic crystals of iodoquinine sulphate (herapathite) embedded in a transparent nitrocellulose polymer film. The needle-like crystals are aligned during the manufacture of the film by stretching or by applying electric or magnetic fields. With the crystals aligned, the sheet is dichroic: it tends to absorb light which is polarized parallel to the direction of crystal alignment but to transmit light which is polarized perpendicular to it. The resultant electric field of an electromagnetic wave (such as light) determines its polarizat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Edwin H
The name Edwin means "rich friend". It comes from the Old English elements "ead" (rich, blessed) and "ƿine" (friend). The original Anglo-Saxon form is Eadƿine, which is also found for Anglo-Saxon figures. People * Edwin of Northumbria (died 632 or 633), King of Northumbria and Christian saint * Edwin (son of Edward the Elder) (died 933) * Eadwine of Sussex (died 982), King of Sussex * Eadwine of Abingdon (died 990), Abbot of Abingdon * Edwin, Earl of Mercia (died 1071), brother-in-law of Harold Godwinson (Harold II) *Edwin (director) (born 1978), Indonesian filmmaker * Edwin (musician) (born 1968), Canadian musician * Edwin Abeygunasekera, Sri Lankan Sinhala politician, member of the 1st and 2nd State Council of Ceylon * Edwin Ariyadasa (1922-2021), Sri Lankan Sinhala journalist * Edwin Austin Abbey (1852–1911) British artist * Edwin Eugene Aldrin (born 1930), although he changed it to Buzz Aldrin, American astronaut * Edwin Howard Armstrong (1890–1954), American ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
David Brewster
Sir David Brewster KH PRSE FRS FSA Scot FSSA MICE (11 December 178110 February 1868) was a British scientist, inventor, author, and academic administrator. In science he is principally remembered for his experimental work in physical optics, mostly concerned with the study of the polarization of light and including the discovery of Brewster's angle. He studied the birefringence of crystals under compression and discovered photoelasticity, thereby creating the field of optical mineralogy.A. D. Morrison-Low (2004) "Brewster, Sir David (1781–1868)" in ''Oxford Dictionary of National Biography'' For this work, William Whewell dubbed him the "father of modern experimental optics" and "the Johannes Kepler of optics." A pioneer in photography, Brewster invented an improved stereoscope, which he called "lenticular stereoscope" and which became the first portable 3D-viewing device. He also invented the stereoscopic camera, two types of polarimeters, the polyzonal lens, the li ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iodine Tincture
Tincture of iodine, iodine tincture, or weak iodine solution is an antiseptic. It is usually 2 to 7% elemental iodine, along with potassium iodide or sodium iodide, dissolved in a mixture of ethanol and water. Tincture solutions are characterized by the presence of alcohol. It was used from 1908 in pre-operative skin preparation by Italian surgeon Antonio Grossich. In the United Kingdom, the development of an iodine solution for skin sterilisation was pioneered by Lionel Stretton. The ''British Medical Journal'' published the detail of his work at Kidderminster Infirmary in 1909. Stretton used a much weaker solution than that used by Grossich. He claimed in 1915 that Grossich had been using a liquid akin to Liquor Iodi Fortis, and that it was he, Stretton, who had introduced the method using Tincture of Iodine BP which came to be used across the world. USP formulas USP Tincture of Iodine is defined in the U.S. National Formulary (NF) as containing in each 100 mL, 1.8 to 2.2& ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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