Green Coke
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Green Coke
Green coke (raw coke) is the primary solid carbonization product from high boiling hydrocarbon fractions obtained at temperatures below 900 K. It contains a fraction of matter that can be released as volatiles during subsequent heat treatment at temperatures up to approximately 1600 K. This mass fraction, called volatile matter, is in the case of green coke between 4 and 15 wt.%, but it depends also on the heating rate. Raw coke is an equivalent term to green coke although it is now less frequently used. The proportion of volatile matter of green coke depends on temperature and time of cooking, but also on the method for its determination. See also *Coker unit *Delayed coker *Petroleum coke *Coke (fuel) References

* IUPAC Compendium of Chemical Terminology 2nd Edition (1997) Coal {{energy-stub ...
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Coker Unit
A coker or coker unit is an oil refinery processing unit that converts the residual oil from the vacuum distillation column into low molecular weight hydrocarbon gases, naphtha, light and heavy gas oils, and petroleum coke. The process thermally cracks the long chain hydrocarbon molecules in the residual oil feed into shorter chain molecules leaving behind the excess carbon in the form of petroleum coke. This petroleum coke can either be fuel grade (high in sulphur and metals) or anode grade (low in sulphur and metals). The raw coke from the coker is often referred to as green coke. In this context, "green" means unprocessed. The further processing of green coke by calcining in a rotary kiln removes residual volatile hydrocarbons from the coke. The calcined petroleum coke can be further processed in an anode baking oven in order to produce anode coke of the desired shape and physical properties. The anodes are mainly used in the aluminium and steel industry. Types of coker u ...
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Delayed Coker
A delayed coker is a type of coker whose process consists of heating a residual oil feed to its thermal cracking temperature in a furnace with multiple parallel passes. This cracks the heavy, long chain hydrocarbon molecules of the residual oil into coker gas oil and petroleum coke. Delayed coking is one of the unit processes used in many oil refineries. The adjacent photograph depicts a delayed coking unit with 4 drums. However, larger units have tandem pairs of drums, some with as many as 8 drums, each of which may have diameters of up to 10 meters and overall heights of up to 43 meters. The yield of coke from the delayed coking process ranges from about 18 to 30 percent by weight of the feedstock residual oil, depending on the composition of the feedstock and the operating variables. Many refineries worldwide produce as much as 2,000 to 3,000 tons per day of petroleum coke and some produce even more. Schematic flow diagram and description The flow diagram and description in ...
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Petroleum Coke
Petroleum coke, abbreviated coke or petcoke, is a final carbon-rich solid material that derives from oil refining, and is one type of the group of fuels referred to as cokes. Petcoke is the coke that, in particular, derives from a final cracking process—a thermo-based chemical engineering process that splits long chain hydrocarbons of petroleum into shorter chains—that takes place in units termed coker units. (Other types of coke are derived from coal.) Stated succinctly, coke is the "carbonization product of high-boiling hydrocarbon fractions obtained in petroleum processing (heavy residues)". Petcoke is also produced in the production of synthetic crude oil (syncrude) from bitumen extracted from Canada’s oil sands and from Venezuela's Orinoco oil sands. In petroleum coker units, residual oils from other distillation processes used in petroleum refining are treated at a high temperature and pressure leaving the petcoke after driving off gases and volatiles, and separa ...
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Coke (fuel)
Coke is a grey, hard, and porous coal-based fuel with a high carbon content and few impurities, made by heating coal or oil in the absence of air—a destructive distillation process. It is an important industrial product, used mainly in iron ore smelting, but also as a fuel in stoves and forges when air pollution is a concern. The unqualified term "coke" usually refers to the product derived from low-ash and low-sulphur bituminous coal by a process called coking. A similar product called petroleum coke, or pet coke, is obtained from crude oil in oil refineries. Coke may also be formed naturally by geologic processes.B. Kwiecińska and H. I. Petersen (2004): "Graphite, semi-graphite, natural coke, and natural char classification — ICCP system". ''International Journal of Coal Geology'', volume 57, issue 2, pages 99-116. History China Historical sources dating to the 4th century describe the production of coke in ancient China. The Chinese first used coke for heating ...
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