Graphene Morphology
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Graphene Morphology
A graphene morphology is any of the structures related to, and formed from, single sheets of graphene. 'Graphene' is typically used to refer to the crystalline monolayer of the naturally occurring material graphite. Due to quantum confinement of electrons within the material at these low dimensions, small differences in graphene morphology can greatly impact the physical and chemical properties of these materials. Commonly studied graphene morphologies include the monolayer sheets, bilayer sheets, graphene nanoribbons and other 3D structures formed from stacking of the monolayer sheets. Monolayer sheets In 2013 researchers developed a production unit that produces continuous monolayer sheets of high-strength monolayer graphene ( HSMG). The process is based on graphene growth on a liquid metal matrix. Bilayer Bilayer graphene displays the anomalous quantum Hall effect, a tunable band gap and potential for excitonic condensation. Bilayer graphene typically can be found either i ...
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Graphene
Graphene () is an allotrope of carbon consisting of a single layer of atoms arranged in a hexagonal lattice nanostructure.
"Carbon nanostructures for electromagnetic shielding applications", Mohammed Arif Poothanari, Sabu Thomas, et al., ''Industrial Applications of Nanomaterials'', 2019. "Carbon nanostructures include various low-dimensional allotropes of carbon including carbon black (CB), carbon fiber, carbon nanotubes (CNTs), fullerene, and graphene."
The name is derived from "graphite" and the suffix -ene, reflecting the fact that the allotrope of carbon contains numerous double bonds. Each atom in a graphene sheet is connecte ...
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Pyrolytic Graphite
Pyrolytic carbon is a material similar to graphite, but with some covalent bonding between its graphene sheets as a result of imperfections in its production. Pyrolytic carbon is man-made and is thought not to be found in nature.Ratner, Buddy D. (2004). Pyrolytic carbon. In Biomaterials science: an introduction to materials in medicine'. Academic Press. p. 171-180. . Google Book Search. Retrieved 7 July 2011. Generally it is produced by heating a hydrocarbon nearly to its decomposition temperature, and permitting the graphite to crystalize (pyrolysis). One method is to heat synthetic fibers in a vacuum. It is used in high temperature applications such as missile nose cones, rocket motors, heat shields, laboratory furnaces, in graphite-reinforced plastic, coating nuclear fuel particles, and in biomedical prostheses. Physical properties Pyrolytic graphite samples usually have a single cleavage plane, similar to mica, because the graphene sheets crystallize in a planar order, as o ...
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Supercapacitors
A supercapacitor (SC), also called an ultracapacitor, is a high-capacity capacitor, with a capacitance value much higher than other capacitors but with lower voltage limits. It bridges the gap between electrolytic capacitors and Rechargeable battery, rechargeable batteries. It typically stores 10 to 100 times more specific energy, energy per unit volume or mass than electrolytic capacitors, can accept and deliver charge much faster than batteries, and tolerates many more charge and discharge cycles than Rechargeable battery, rechargeable batteries. Supercapacitors are used in applications requiring many rapid charge/discharge cycles, rather than long-term compact energy storage — in automobiles, buses, trains, cranes and elevators, where they are used for Regenerative brake, regenerative braking, short-term energy storage, or burst-mode power delivery. Smaller units are used as power backup for static random-access memory (SRAM). Unlike ordinary capacitors, supercapacito ...
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Battery (electricity)
An electric battery is a source of electric power consisting of one or more electrochemical cells with external connections for powering electrical devices. When a battery is supplying power, its positive terminal is the cathode and its negative terminal is the anode. The terminal marked negative is the source of electrons that will flow through an external electric circuit to the positive terminal. When a battery is connected to an external electric load, a redox reaction converts high-energy reactants to lower-energy products, and the free-energy difference is delivered to the external circuit as electrical energy. Historically the term "battery" specifically referred to a device composed of multiple cells; however, the usage has evolved to include devices composed of a single cell. Primary (single-use or "disposable") batteries are used once and discarded, as the electrode materials are irreversibly changed during discharge; a common example is the alkaline battery used ...
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Sheet Resistance
Sheet resistance, is a measure of resistance of thin films that are uniform in thickness. It is commonly used to characterize materials made by semiconductor doping, metal deposition, resistive paste printing, and glass coating. Examples of these processes are: doped semiconductor regions (e.g., silicon or polysilicon), and the resistors that are screen printed onto the substrates of thick-film hybrid microcircuits. The utility of sheet resistance as opposed to resistance or resistivity is that it is directly measured using a four-terminal sensing measurement (also known as a four-point probe measurement) or indirectly by using a non-contact eddy-current-based testing device. Sheet resistance is invariable under scaling of the film contact and therefore can be used to compare the electrical properties of devices that are significantly different in size. Calculations Sheet resistance is applicable to two-dimensional systems in which thin films are considered two-dimensional ...
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Aerogel
Aerogels are a class of synthetic porous ultralight material derived from a gel, in which the liquid component for the gel has been replaced with a gas, without significant collapse of the gel structure. The result is a solid with extremely low density and extremely low thermal conductivity. Aerogels can be made from a variety of chemical compounds. Silica aerogels feel like fragile expanded polystyrene to the touch, while some polymer-based aerogels feel like rigid foams. The first documented example of an aerogel was created by Samuel Stephens Kistler in 1931, as a result of a bet with Charles Learned over who could replace the liquid in "jellies" with gas without causing shrinkage. Aerogels are produced by extracting the liquid component of a gel through supercritical drying or freeze-drying. This allows the liquid to be slowly dried off without causing the solid matrix in the gel to collapse from capillary action, as would happen with conventional evaporation. The first aer ...
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Gyroid
A gyroid is an infinitely connected Triply periodic minimal surface, triply periodic minimal surface discovered by Alan Schoen in 1970. History and properties The gyroid is the unique non-trivial embedded member of the associate family of the Schwarz minimal surface#Schwarz P .28.22Primitive.22.29, Schwarz P and Schwarz minimal surface#Schwarz D .28.22Diamond.22.29, D surfaces. Its angle of association with respect to the D surface is approximately 38.01°. The gyroid is similar to the lidinoid. The gyroid was discovered in 1970 by NASA scientist Alan Schoen. He calculated the angle of association and gave a convincing demonstration of pictures of intricate plastic models, but did not provide a proof of embeddedness. Schoen noted that the gyroid contains neither straight lines nor planar symmetries. Karcher gave a different, more contemporary treatment of the surface in 1989 using conjugate surface construction. In 1996 Große-Brauckmann and Wohlgemuth proved that it is embed ...
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Gyroid
A gyroid is an infinitely connected Triply periodic minimal surface, triply periodic minimal surface discovered by Alan Schoen in 1970. History and properties The gyroid is the unique non-trivial embedded member of the associate family of the Schwarz minimal surface#Schwarz P .28.22Primitive.22.29, Schwarz P and Schwarz minimal surface#Schwarz D .28.22Diamond.22.29, D surfaces. Its angle of association with respect to the D surface is approximately 38.01°. The gyroid is similar to the lidinoid. The gyroid was discovered in 1970 by NASA scientist Alan Schoen. He calculated the angle of association and gave a convincing demonstration of pictures of intricate plastic models, but did not provide a proof of embeddedness. Schoen noted that the gyroid contains neither straight lines nor planar symmetries. Karcher gave a different, more contemporary treatment of the surface in 1989 using conjugate surface construction. In 1996 Große-Brauckmann and Wohlgemuth proved that it is embed ...
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Hydrogen Storage
Hydrogen storage can be accomplished by several existing methods of holding hydrogen for later use. These include mechanical approaches such as using high pressures and low temperatures, or employing chemical compounds that release H2 upon demand. While large amounts of hydrogen are produced by various industries, it is mostly consumed at the site of production, notably for the synthesis of ammonia. For many years hydrogen has been stored as compressed gas or cryogenic liquid, and transported as such in cylinders, tubes, and cryogenic tanks for use in industry or as propellant in space programs. Interest in using hydrogen for on-board storage of energy in zero-emissions vehicles is motivating the development of new methods of storage, more adapted to this new application. The overarching challenge is the very low boiling point of H2: it boils around 20.268 K (−252.882 °C or −423.188 °F). Achieving such low temperatures requires expending significant energy. Es ...
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Sorbent
A sorbent is a material used to absorb or adsorb liquids or gases. Examples include: *A material similar to molecular sieve material, which acts by adsorption (attracting molecules to its surface). It has a large internal surface area and good thermal conductivity. It is typically supplied in pellets of 1 mm to 2 mm diameter and roughly 5 mm length or as grains of the order 1 mm. Occasionally as beads up to 5 mm diameter. They are typically made from aluminium oxide with a porous structure. *Materials used to absorb other materials due to their high affinity for doing so. Examples include: **In composting, dry (brown, high-carbon) materials absorb many odoriferous chemicals, and these chemicals help to decompose these sorbents. **A sponge absorbs many times its own weight in water. **A polypropylene fiber mat may be used to absorb oil. **A cellulose fiber product may be used to absorb oil. **The granular gel material in a baby diaper will absorb several t ...
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Nanoelectronics
Nanoelectronics refers to the use of nanotechnology in electronic components. The term covers a diverse set of devices and materials, with the common characteristic that they are so small that inter-atomic interactions and quantum mechanical properties need to be studied extensively. Some of these candidates include: hybrid molecular/semiconductor electronics, one-dimensional nanotubes/nanowires (e.g. silicon nanowires or carbon nanotubes) or advanced molecular electronics. Nanoelectronic devices have critical dimensions with a size range between 1 nm and 100 nm. Recent silicon MOSFET (metal-oxide-semiconductor field-effect transistor, or MOS transistor) technology generations are already within this regime, including 22 nanometers CMOS (complementary MOS) nodes and succeeding 14 nm, 10 nm and 7 nm FinFET (fin field-effect transistor) generations. Nanoelectronics is sometimes considered as disruptive technology because present candidates are significantly different f ...
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Nanomechanical Resonator
A nanomechanical resonator is a nanoelectromechanical systems ultra-small resonator that oscillates at a specific frequency depending on its mass and stiffness. See also *Quartz crystal microbalance *Atomic force microscopy Atomic force microscopy (AFM) or scanning force microscopy (SFM) is a very-high-resolution type of scanning probe microscopy (SPM), with demonstrated resolution on the order of fractions of a nanometer, more than 1000 times better than the op ... References Further reading * * Nanoelectronics {{Physics-stub ...
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