Gas Blending
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Gas Blending
Gas blending is the process of mixing gases for a specific purpose where the composition of the resulting mixture is specified and controlled. A wide range of applications include scientific and industrial processes, food production and storage and breathing gases. Gas mixtures are usually specified in terms of molar gas fraction (which is closely approximated by volumetric gas fraction for many permanent gases): by percentage, parts per thousand or parts per million. Volumetric gas fraction converts trivially to partial pressure ratio, following Dalton's law of partial pressures. Partial pressure blending at constant temperature is computationally simple, and pressure measurement is relatively inexpensive, but maintaining constant temperature during pressure changes requires significant delays for temperature equalization. Blending by mass fraction is unaffected by temperature variation during the process, but requires accurate measurement of mass or weight, and calculation of ...
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Mole Fraction
In chemistry, the mole fraction or molar fraction (''xi'' or ) is defined as unit of the amount of a constituent (expressed in moles), ''ni'', divided by the total amount of all constituents in a mixture (also expressed in moles), ''n''tot. This expression is given below: :x_i = \frac The sum of all the mole fractions is equal to 1: :\sum_^ n_i = n_\mathrm ; \ \sum_^ x_i = 1. The same concept expressed with a denominator of 100 is the mole percent, molar percentage or molar proportion (mol%). The mole fraction is also called the amount fraction. It is identical to the number fraction, which is defined as the number of molecules of a constituent ''Ni'' divided by the total number of all molecules ''N''tot. The mole fraction is sometimes denoted by the lowercase Greek letter (chi) instead of a Roman ''x''. For mixtures of gases, IUPAC recommends the letter ''y''. The National Institute of Standards and Technology of the United States prefers the term amount-of-substance fraction o ...
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Gas Blending For Scuba Diving
Gas blending for scuba diving (or gas mixing) is the filling of diving cylinders with non-air breathing gases such as nitrox, trimix and heliox. Use of these gases is generally intended to improve overall safety of the planned dive, by reducing the risk of decompression sickness and/or nitrogen narcosis, and may improve ease of breathing. Filling cylinders with a mixture of gases has dangers for both the filler and the diver. During filling there is a risk of fire due to use of oxygen and a risk of explosion due to the use of high-pressure gases. The composition of the mix must be safe for the depth and duration of the planned dive. If the concentration of oxygen is too lean the diver may lose consciousness due to hypoxia and if it is too rich the diver may suffer oxygen toxicity. The concentration of inert gases, such as nitrogen and helium, are planned and checked to avoid nitrogen narcosis and decompression sickness. Methods used include batch mixing by partial pressure o ...
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Saturation Diving
Saturation diving is diving for periods long enough to bring all tissues into equilibrium with the partial pressures of the inert components of the breathing gas used. It is a diving mode that reduces the number of decompressions divers working at great depths must undergo by only decompressing divers once at the end of the diving operation, which may last days to weeks, having them remain under pressure for the whole period. A diver breathing pressurized gas accumulates dissolved inert gas used in the breathing mixture to dilute the oxygen to a non-toxic level in his or her tissues, which can cause decompression sickness ("the bends") if permitted to come out of solution within the body tissues; hence, returning to the surface safely requires lengthy decompression so that the inert gases can be eliminated via the lungs. Once the dissolved gases in a diver's tissues reach the saturation point, however, decompression time does not increase with further exposure, as no more inert g ...
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Bailout Cylinder
A bailout bottle (BoB) or, more formally, bailout cylinder is a scuba cylinder carried by an underwater diver for use as an emergency supply of breathing gas in the event of a primary gas supply failure. A bailout cylinder may be carried by a scuba diver in addition to the primary scuba set, or by a surface supplied diver using either free-flow or demand systems. The bailout gas is not intended for use during the dive except in an emergency, and would be considered a fully redundant breathing gas supply if used correctly. The term may refer to just the cylinder, or the bailout set or emergency gas supply (EGS), which is the cylinder with the gas delivery system attached. The bailout set or bailout system is the combination of the emergency gas cylinder with the gas delivery system to the diver, which includes a diving regulator with either a demand valve, a bailout block, or a bailout valve (BOV). In solo diving, a buddy bottle is a bailout cylinder carried as a substitute for an ...
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Gas Cylinder
A gas cylinder is a pressure vessel for storage and containment of gases at above atmospheric pressure. High-pressure gas cylinders are also called ''bottles''. Inside the cylinder the stored contents may be in a state of compressed gas, vapor over liquid, supercritical fluid, or dissolved in a substrate material, depending on the physical characteristics of the contents. A typical gas cylinder design is elongated, standing upright on a flattened bottom end, with the valve and fitting at the top for connecting to the receiving apparatus. The term ''cylinder'' in this context is not to be confused with ''tank'', the latter being an open-top or vented container that stores liquids under gravity, though the term scuba tank is commonly used to refer to a cylinder used for breathing gas supply to an underwater breathing apparatus. Nomenclature In the United States, "bottled gas" typically refers to liquefied petroleum gas. "Bottled gas" is sometimes used in medical supply, espe ...
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Saturation Diving
Saturation diving is diving for periods long enough to bring all tissues into equilibrium with the partial pressures of the inert components of the breathing gas used. It is a diving mode that reduces the number of decompressions divers working at great depths must undergo by only decompressing divers once at the end of the diving operation, which may last days to weeks, having them remain under pressure for the whole period. A diver breathing pressurized gas accumulates dissolved inert gas used in the breathing mixture to dilute the oxygen to a non-toxic level in his or her tissues, which can cause decompression sickness ("the bends") if permitted to come out of solution within the body tissues; hence, returning to the surface safely requires lengthy decompression so that the inert gases can be eliminated via the lungs. Once the dissolved gases in a diver's tissues reach the saturation point, however, decompression time does not increase with further exposure, as no more inert g ...
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Surface Supplied Diving
Surface-supplied diving is diving using equipment supplied with breathing gas using a diver's umbilical from the surface, either from the shore or from a diving support vessel, sometimes indirectly via a diving bell. This is different from scuba diving, where the diver's breathing equipment is completely self-contained and there is no link to the surface. The primary advantages of conventional surface supplied diving are lower risk of drowning and considerably larger breathing gas supply than scuba, allowing longer working periods and safer decompression. Disadvantages are the absolute limitation on diver mobility imposed by the length of the umbilical, encumbrance by the umbilical, and high logistical and equipment costs compared with scuba. The disadvantages restrict use of this mode of diving to applications where the diver operates within a small area, which is common in commercial diving work. The copper helmeted free-flow standard diving dress is the version which made com ...
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Work Of Breathing
Work of breathing (WOB) is the energy expended to inhale and exhale a breathing gas. It is usually expressed as work per unit volume, for example, joules/litre, or as a work rate (power), such as joules/min or equivalent units, as it is not particularly useful without a reference to volume or time. It can be calculated in terms of the pulmonary pressure multiplied by the change in pulmonary volume, or in terms of the oxygen consumption attributable to breathing. In a normal resting state the work of breathing constitutes about 5% of the total body oxygen consumption. It can increase considerably due to illness or constraints on gas flow imposed by breathing apparatus, ambient pressure, or breathing gas composition. Mechanism of breathing The normal relaxed state of the lung and chest is partially empty. Further exhalation requires muscular work. Inhalation is an active process requiring work. Some of this work is to overcome frictional resistance to flow, and part is used to defo ...
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Nitrogen Narcosis
Narcosis while diving (also known as nitrogen narcosis, inert gas narcosis, raptures of the deep, Martini effect) is a reversible alteration in consciousness that occurs while diving at depth. It is caused by the anesthetic effect of certain gases at high pressure. The Greek word (narkōsis), "the act of making numb", is derived from (narkē), "numbness, torpor", a term used by Homer and Hippocrates. Narcosis produces a state similar to drunkenness (alcohol intoxication), or nitrous oxide inhalation. It can occur during shallow dives, but does not usually become noticeable at depths less than . Except for helium and probably neon, all gases that can be breathed have a narcotic effect, although widely varying in degree. The effect is consistently greater for gases with a higher lipid solubility, and although the mechanism of this phenomenon is still not fully clear, there is good evidence that the two properties are mechanistically related. As depth increases, the mental im ...
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Decompression Sickness
Decompression sickness (abbreviated DCS; also called divers' disease, the bends, aerobullosis, and caisson disease) is a medical condition caused by dissolved gases emerging from solution as bubbles inside the body tissues during decompression. DCS most commonly occurs during or soon after a decompression ascent from underwater diving, but can also result from other causes of depressurisation, such as emerging from a caisson, decompression from saturation, flying in an unpressurised aircraft at high altitude, and extravehicular activity from spacecraft. DCS and arterial gas embolism are collectively referred to as decompression illness. Since bubbles can form in or migrate to any part of the body, DCS can produce many symptoms, and its effects may vary from joint pain and rashes to paralysis and death. DCS often causes air bubbles to settle in major joints like knees or elbows, causing individuals to bend over in excruciating pain, hence its common name, the bends. Individu ...
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Heliox
Heliox is a breathing gas mixture of helium (He) and oxygen (O2). It is used as a medical treatment for patients with difficulty breathing because mixture generates less resistance than atmospheric air when passing through the airways of the lungs, and thus requires less effort by a patient to breathe in and out of the lungs. It is also used as a breathing gas diluent for deep ambient pressure diving as it is not narcotic at high pressure, and for its low work of breathing. Heliox has been used medically since the 1930s, and although the medical community adopted it initially to alleviate symptoms of upper airway obstruction, its range of medical uses has since expanded greatly, mostly because of the low density of the gas. Heliox is also used in saturation diving and sometimes during the deep phase of technical dives. Medical uses In medicine heliox may refer to a mixture of 21% O2 (the same as air) and 79% He, although other combinations are available (70/30 and 60/40). Hel ...
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