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Ferrous Metals
In chemistry, the adjective Ferrous indicates a compound that contains iron(II), meaning iron in its +2 oxidation state, possibly as the divalent cation Fe2+. It is opposed to "ferric" or iron(III), meaning iron in its +3 oxidation state, such as the trivalent cation Fe3+.ferrous entry in the online dictionary. Accessed on 2008-04-19. This usage has been largely replaced by the nomenclature, which calls for the oxidation state being indicated by Roman numerals in parentheses, such as |
Iron(II) Oxide
Iron(II) oxide or ferrous oxide is the inorganic compound with the formula FeO. Its mineral form is known as wüstite. One of several iron oxides, it is a black-colored powder that is sometimes confused with rust, the latter of which consists of hydrated iron(III) oxide (ferric oxide). Iron(II) oxide also refers to a family of related non-stoichiometric compounds, which are typically iron deficient with compositions ranging from Fe0.84O to Fe0.95O. Preparation FeO can be prepared by the thermal decomposition of iron(II) oxalate. :FeC2O4 → FeO + CO2 + CO The procedure is conducted under an inert atmosphere to avoid the formation of iron(III) oxide (Fe2O3). A similar procedure can also be used for the synthesis of manganous oxide and stannous oxide. Stoichiometric FeO can be prepared by heating Fe0.95O with metallic iron at 770 °C and 36 kbar.Wells A.F. (1984) ''Structural Inorganic Chemistry'' 5th edition Oxford University Press Reactions FeO is therm ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pourbaix Diagram Of Iron
In electrochemistry, and more generally in solution chemistry, a Pourbaix diagram, also known as a potential/pH diagram, EH–pH diagram or a pE/pH diagram, is a plot of possible thermodynamically stable phases (''i.e.'', at chemical equilibrium) of an aqueous electrochemical system. Boundaries (50 %/50 %) between the predominant chemical species (aqueous ions in solution, or solid phases) are represented by lines. As such a Pourbaix diagram can be read much like a standard phase diagram with a different set of axes. Similarly to phase diagrams, they do not allow for reaction rate or kinetic effects. Beside potential and pH, the equilibrium concentrations are also dependent upon, e.g., temperature, pressure, and concentration. Pourbaix diagrams are commonly given at room temperature, atmospheric pressure, and molar concentrations of 10−6 and changing any of these parameters will yield a different diagram. The diagrams are named after Marcel Pourbaix (1904–1998), the Russian-bor ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vivianite
Vivianite () is a hydrated iron phosphate mineral found in a number of geological environments. Small amounts of manganese Mn2+, magnesium Mg and calcium Ca may substitute for iron Fe2+ in the structure.Gaines et al (1997) Dana’s New Mineralogy Eighth Edition. Wiley Pure vivianite is colorless, but the mineral oxidizes very easily, changing the color, and it is usually found as deep blue to deep bluish green prismatic to flattened crystals. Vivianite crystals are often found inside fossil shells, such as those of bivalves and gastropods, or attached to fossil bone. It was named by Abraham Gottlob Werner in 1817, the year of his death, after either John Henry Vivian (1785–1855), a Welsh-Cornish politician, mine owner and mineralogist living in Truro, Cornwall, England, or after Jeffrey G. Vivian, an English mineralogist. Vivianite was discovered at Wheal Kind, in St Agnes, Cornwall. Vivianite group Vivianite group minerals have the general formula A3(XO4)2·8H2O, where ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Humboldtine
Humboldtine is a rarely occurring mineral from the mineral class of "organic compounds" with the chemical composition FeC2O4•2H2O and is therefore a water-containing iron(II) oxalate or the iron salt of oxalic acid. Humboldtine crystallizes in the monoclinic crystal system, but only rarely develops well-formed, tabular to prismatic crystals with a resin-like sheen on the surfaces. It is mostly found in the form of botryoidal or fibrous to earthy aggregates and crusty coatings from dull yellow to brownish yellow or amber yellow in color. It can be transparent to opaque. It can form from hematite in oxalic acid. With a Mohs hardness of 1.5 to 2, humboldtine is one of the softest minerals and can be scratched with a fingernail. Etymology and history Humboldtine was first discovered by August Breithaupt in a weathered brown coal deposit near the municipality of Korozluky in Okres Most in the Czech Republic and described in 1821 by Mariano Eduardo de Rivero y Ustariz (1798-1857), ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ferrous Oxalate
Ferrous oxalate, or iron(II) oxalate, is an inorganic compound with the formula FeC2O4 where is typically 2. These are orange compounds, poorly soluble in water. Structure The dihydrate FeC2O4 is a coordination polymer, consisting of chains of oxalate-bridged ferrous centers, each with two aquo ligands. When heated, it dehydrates and decomposes into a mixture of iron oxides and pyrophoric iron metal, with release of carbon dioxide, carbon monoxide, and water. Natural occurrence Anhydrous iron(II) oxalate is as yet (2020) unknown among minerals. However, the dihydrate is known, as humboldtine. A related, though much more complex mineral is stepanovite, Na g(H2O)6Fe(C2O4)3]·3H2O - an example of trioxalatoferrate(II). See also A number of other iron oxalates are known * Iron(III) oxalate * Potassium ferrioxalate Potassium ferrioxalate, also called potassium trisoxalatoferrate or potassium tris(oxalato)ferrate(III) is a chemical compound with the formula []. It often occurs ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iron(II) Nitrate
Iron(II) nitrate is the nitrate salt of iron(II). It is commonly encountered as the green hexahydrate, Fe(NO3)2·6H2O, which is a metal aquo complex, however it is not commercially available unlike iron(III) nitrate due to its instability to air. The salt is soluble in water serves as a ready source of ferrous ions. Structure No structure of any salt Fe(NO3)2·xH2O has been determined by X-ray crystallography. Nonetheless, the nature of the aquo complex e(H2O)6sup>2+ is well known and relatively insensitive to the anion. The Fe-O distances are longer for e(H2O)6sup>2+ (2.13 Å) than for the ferric analogue e(H2O)6sup>3+ (1.99 Å). Both e(H2O)6sup>n+ complexes are high spin, which results in pale colors, paramagnetism, and weak Fe-O bonds. Production Iron(II) nitrate can be produced in multiple ways such as the reaction of iron metal with cold dilute nitric acid: :3Fe + 8HNO3 + 12H2O → 3Fe(NO3)2(H2O)6 + 2NO If this reaction is conducted below -10 °C, nonahyd ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iron(II) Chloride
Iron(II) chloride, also known as ferrous chloride, is the chemical compound of formula FeCl2. It is a paramagnetic solid with a high melting point. The compound is white, but typical samples are often off-white. FeCl2 crystallizes from water as the greenish tetrahydrate, which is the form that is most commonly encountered in commerce and the laboratory. There is also a dihydrate. The compound is highly soluble in water, giving pale green solutions. Production Hydrated forms of ferrous chloride are generated by treatment of wastes from steel production with hydrochloric acid. Such solutions are designated "spent acid," or "pickle liquor" especially when the hydrochloric acid is not completely consumed: :Fe + 2 HCl → FeCl2 + H2 The spent acid requires treatment if it is disposed. Ferrous chloride is used in the manufacturing of ferric chloride. Ferrous chloride can also be used to regenerate hydrochloric acid. It is also a byproduct from titanium production, since so ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rust
Rust is an iron oxide, a usually reddish-brown oxide formed by the reaction of iron and oxygen in the catalytic presence of water or air moisture. Rust consists of hydrous iron(III) oxides (Fe2O3·nH2O) and iron(III) oxide-hydroxide (FeO(OH), Fe(OH)3), and is typically associated with the corrosion of refined iron. Given sufficient time, any iron mass, in the presence of water and oxygen, could eventually convert entirely to rust. Surface rust is commonly flaky and friable, and provides no passivational protection to the underlying iron, unlike the formation of patina on copper surfaces. ''Rusting'' is the common term for corrosion of elemental iron and its alloys such as steel. Many other metals undergo similar corrosion, but the resulting oxides are not commonly called "rust". Several forms of rust are distinguishable both visually and by spectroscopy, and form under different circumstances. Other forms of rust include the result of reactions between iron and chloride ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ferruginous
The adjective ferruginous may mean: * Containing iron, applied to water, oil, and other non-metals * Having rust on the surface * With the rust (color) See also * Ferrous, containing iron (for metals and alloys) or iron(II) cations * Ferric, containing iron(III) cations * Ferrate, anions containing iron * Ferruginous body, a nodule indicative of asbestos inhalation * Ferruginea (other) Ferruginea, a Latin word meaning "ferruginous" or "rusty", may refer to: * Substantia ferruginea, an underlying patch of deeply pigmented nerve cells that give the locus ceruleus its bluish-gray color * a ''Magnolia grandiflora ''Magnolia gran ... * List of birds described as ferruginous {{disambiguation ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Metal
A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typically ductile (can be drawn into wires) and malleable (they can be hammered into thin sheets). These properties are the result of the ''metallic bond'' between the atoms or molecules of the metal. A metal may be a chemical element such as iron; an alloy such as stainless steel; or a molecular compound such as polymeric sulfur nitride. In physics, a metal is generally regarded as any substance capable of conducting electricity at a temperature of absolute zero. Many elements and compounds that are not normally classified as metals become metallic under high pressures. For example, the nonmetal iodine gradually becomes a metal at a pressure of between 40 and 170 thousand times atmospheric pressure. Equally, some materials regarded as metals ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Non-ferrous
In metallurgy, non-ferrous metals are metals or alloys that do not contain iron (allotropes of iron, ferrite, and so on) in appreciable amounts. Generally more costly than ferrous metals, non-ferrous metals are used because of desirable properties such as low weight (e.g. aluminium), higher conductivity (e.g. copper), non-magnetic properties or resistance to corrosion (e.g. zinc). Some non-ferrous materials are also used in the iron and steel industries. For example, bauxite is used as flux for blast furnaces, while others such as wolframite, pyrolusite, and chromite are used in making ferrous alloys. Important non-ferrous metals include aluminium, copper, lead, tin, titanium, and zinc, and alloys such as brass. Precious metals such as gold, silver, and platinum and exotic or rare metals such as mercury, tungsten, beryllium, bismuth, cerium, cadmium, niobium, indium, gallium, germanium, lithium, selenium, tantalum, tellurium, vanadium, and zirconium are also non-ferrous. They ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alloy
An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, opacity (optics), opacity, and lustre (mineralogy), luster, but may have properties that differ from those of the pure metals, such as increased strength or hardness. In some cases, an alloy may reduce the overall cost of the material while preserving important properties. In other cases, the mixture imparts synergistic properties to the constituent metal elements such as corrosion resistance or mechanical strength. Alloys are defined by a metallic bonding character. The alloy constituents are usually measured by mass percentage for practical applications, and in Atomic ratio, atomic fraction for basic science studies. Alloys are usually classified as substitutional or interstitial alloys, depending on the atomic arrangement that forms the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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