Esperite
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Esperite
Esperite is a rare complex calcium lead zinc silicate (PbCa3Zn4(SiO4)4) related to beryllonite and trimerite that used to be called ''calcium larsenite''. Esperite has a white, greasy appearance in daylight and is much prized for its brilliant yellow green fluorescence under shortwave ultraviolet light. It is found in association with calcite, franklinite, willemite, hardystonite and clinohedrite. It has also been found as prismatic crystals up to 1 mm in length at the El Dragon Mine, Potosi, Bolivia in association with allophane Allophane is an amorphous to poorly crystalline hydrous aluminium silicate clay mineraloid. Its chemical formula is Al2O3·(SiO2)1.3-2·(2.5-3)H2O. Since it has short-range atomic order, it is a mineraloid, rather than a mineral, and can be ident ..., chalcomenite, clinochalcomenite and barite. References Mineral galleries*Pete Dunn, ''Franklin and Sterling Hill, New Jersey: the world's most magnificent mineral deposits'', part 3 p.&nbs ...
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Fluorescence
Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation. It is a form of luminescence. In most cases, the emitted light has a longer wavelength, and therefore a lower photon energy, than the absorbed radiation. A perceptible example of fluorescence occurs when the absorbed radiation is in the ultraviolet region of the electromagnetic spectrum (invisible to the human eye), while the emitted light is in the visible region; this gives the fluorescent substance a distinct color that can only be seen when the substance has been exposed to UV light. Fluorescent materials cease to glow nearly immediately when the radiation source stops, unlike phosphorescent materials, which continue to emit light for some time after. Fluorescence has many practical applications, including mineralogy, gemology, medicine, chemical sensors (fluorescence spectroscopy), fluorescent labelling, dyes, biological detectors, cosmic-ray detection, vacu ...
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Clinohedrite
Clinohedrite is a rare silicate mineral. Its chemical composition is a hydrous calcium-zinc silicate; CaZn(SiO4)·H2O. It crystallizes in the monoclinic system and typically occurs as veinlets and fracture coatings. It is commonly colorless, white to pale amethyst in color. It has perfect cleavage and the crystalline habit has a brilliant luster. It has a Mohs hardness of 5.5 and a specific gravity of 3.28 - 3.33.http://www.handbookofmineralogy.org/pdfs/clinohedrite.pdf Handbook of Mineralogyhttp://www.mindat.org/min-1075.html Mindat Under short wave ultraviolet light it fluoresces a rich orange color. It is frequently associated with minerals such as hardystonite (fluoresces violet blue), esperite (fluoresces bright yellow), calcite (fluoresces orange-red), franklinite (non-fluorescent) and willemite (fluoresces green). Clinohedrite was found primarily at the Franklin zinc mines in New Jersey, the type locality, but has also been reported from the Christmas mine, Gila County, A ...
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Hardystonite
Hardystonite is a rare calcium zinc silicate mineral first described from the Franklin, New Jersey, U.S. zinc deposits. It often contains lead, which was detrimental to the zinc smelting process, so it was not a useful ore mineral. Like many of the famous Franklin minerals, hardystonite responds to short wave ultraviolet (254 nm wavelength) light, emitting a fluorescence from dark purple to bright violet blue. In daylight, it is white to gray to light pink in color, sometimes with a vitreous or greasy luster. It is very rarely found as well formed crystals, and these are usually rectangular in appearance and rock-locked.Dunn, Pete J. Franklin and Sterling Hill, New Jersey: the world's most magnificent mineral deposits. Dr. Pete J. Dunn, 2004. Hardystonite has a chemical composition of Ca2ZnSi2O7. It is frequently found with willemite (fluoresces green), calcite (fluoresces red), and clinohedrite (fluoresces orange). Hardystonite can be found altered to clinohedrite CaZn(S ...
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Potosí
Potosí, known as Villa Imperial de Potosí in the colonial period, is the capital city and a municipality of the Department of Potosí in Bolivia. It is one of the highest cities in the world at a nominal . For centuries, it was the location of the Spanish colonial silver mint. A considerable amount of the city's colonial architecture has been preserved in the historic center of the city, which - along with the globally important Cerro Rico de Potosí - are part of a designated UNESCO World Heritage Site. Potosí lies at the foot of the ''Cerro de Potosí'' —sometimes referred to as the ''Cerro Rico'' ("rich mountain")— a mountain popularly conceived of as being "made of" silver ore that dominates the city. The Cerro Rico is the reason for Potosí's historical importance since it was the major supply of silver for the Spanish Empire until Guanajuato in Mexico surpassed it in the 18th century. The silver was taken by llama and mule train to the Pacific coast, shipped north ...
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Monoclinic Minerals
In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic system. They form a parallelogram prism. Hence two pairs of vectors are perpendicular (meet at right angles), while the third pair makes an angle other than 90°. Bravais lattices Two monoclinic Bravais lattices exist: the primitive monoclinic and the base-centered monoclinic. For the base-centered monoclinic lattice, the primitive cell has the shape of an oblique rhombic prism;See , row mC, column Primitive, where the cell parameters are given as a1 = a2, α = β it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. Note that the length a of the primitive cell below equals \frac \sqrt of the conventional cell above. Crystal classes The table below org ...
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Nesosilicates
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually considered a silicate mineral. Silica is found in nature as the mineral quartz, and its polymorphs. On Earth, a wide variety of silicate minerals occur in an even wider range of combinations as a result of the processes that have been forming and re-working the crust for billions of years. These processes include partial melting, crystallization, fractionation, metamorphism, weathering, and diagenesis. Living organisms also contribute to this geologic cycle. For example, a type of plankton known as diatoms construct their exoskeletons ("frustules") from silica extracted from seawater. The frustules of dead diatoms are a major constituent of deep ocean sediment, and of diatomaceous earth. General structure A silicate mineral is generally an ...
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Zinc Minerals
Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic table. In some respects, zinc is chemically similar to magnesium: both elements exhibit only one normal oxidation state (+2), and the Zn2+ and Mg2+ ions are of similar size.The elements are from different metal groups. See periodic table. Zinc is the 24th most abundant element in Earth's crust and has five stable isotopes. The most common zinc ore is sphalerite (zinc blende), a zinc sulfide mineral. The largest workable lodes are in Australia, Asia, and the United States. Zinc is refined by froth flotation of the ore, roasting, and final extraction using electricity ( electrowinning). Zinc is an essential trace element for humans, animals, plants and for microorganisms and is necessary for prenatal and postnatal development. It is the seco ...
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Lead Minerals
Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, lead is a shiny gray with a hint of blue. It tarnishes to a dull gray color when exposed to air. Lead has the highest atomic number of any stable element and three of its isotopes are endpoints of major nuclear decay chains of heavier elements. Lead is toxic, even in small amounts, especially to children. Lead is a relatively unreactive post-transition metal. Its weak metallic character is illustrated by its amphoteric nature; lead and lead oxides react with acids and bases, and it tends to form covalent bonds. Compounds of lead are usually found in the +2 oxidation state rather than the +4 state common with lighter members of the carbon group. Exceptions are mostly limited to organolead compounds. Like the lighter members of the group, le ...
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Calcium Minerals
Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to its heavier homologues strontium and barium. It is the fifth most abundant element in Earth's crust, and the third most abundant metal, after iron and aluminium. The most common calcium compound on Earth is calcium carbonate, found in limestone and the fossilised remnants of early sea life; gypsum, anhydrite, fluorite, and apatite are also sources of calcium. The name derives from Latin ''calx'' "lime", which was obtained from heating limestone. Some calcium compounds were known to the ancients, though their chemistry was unknown until the seventeenth century. Pure calcium was isolated in 1808 via electrolysis of its oxide by Humphry Davy, who named the element. Calcium compounds are widely used in many industries: in foods and pharmace ...
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Barite
Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate ( Ba S O4). Baryte is generally white or colorless, and is the main source of the element barium. The ''baryte group'' consists of baryte, celestine (strontium sulfate), anglesite (lead sulfate), and anhydrite (calcium sulfate). Baryte and celestine form a solid solution (Ba,Sr)SO4. Names and history The radiating form, sometimes referred to as ''Bologna Stone'', attained some notoriety among alchemists for specimens found in the 17th century near Bologna by Vincenzo Casciarolo. These became phosphorescent upon being calcined. Carl Scheele determined that baryte contained a new element in 1774, but could not isolate barium, only barium oxide. Johan Gottlieb Gahn also isolated barium oxide two years later in similar studies. Barium was first isolated by electrolysis of molten barium salts in 1808 by Sir Humphry Davy in England. The American Petroleum Institute specification API 13/ISO 13500, which gover ...
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