Equivalent Spherical Diameter
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Equivalent Spherical Diameter
The equivalent spherical diameter of an irregularly shaped object is the diameter of a sphere of equivalent geometric, optical, electrical, aerodynamic or hydrodynamic behavior to that of the particle under investigation. The particle size of a perfectly smooth, spherical object can be accurately defined by a single parameter, the particle diameter. However, real-life particles are likely to have irregular shapes and surface irregularities, and their size cannot be fully characterized by a single parameter. The concept of equivalent spherical diameter has been introduced in the field of particle size analysis to enable the representation of the particle size distribution in a simplified, homogenized way. Here, the real-life particle is matched with an imaginary sphere which has the same properties according to a defined principle, enabling the real-life particle to be defined by the diameter of the imaginary sphere.   The principle used to match the real-life particle and the ima ...
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Diameter
In geometry, a diameter of a circle is any straight line segment that passes through the center of the circle and whose endpoints lie on the circle. It can also be defined as the longest chord of the circle. Both definitions are also valid for the diameter of a sphere. In more modern usage, the length d of a diameter is also called the diameter. In this sense one speaks of diameter rather than diameter (which refers to the line segment itself), because all diameters of a circle or sphere have the same length, this being twice the radius r. :d = 2r \qquad\text\qquad r = \frac. For a convex shape in the plane, the diameter is defined to be the largest distance that can be formed between two opposite parallel lines tangent to its boundary, and the is often defined to be the smallest such distance. Both quantities can be calculated efficiently using rotating calipers. For a curve of constant width such as the Reuleaux triangle, the width and diameter are the same because all ...
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Dynamic Light Scattering
Dynamic light scattering (DLS) is a technique in physics that can be used to determine the size distribution profile of small particles in suspension or polymers in solution. In the scope of DLS, temporal fluctuations are usually analyzed using the intensity or photon auto-correlation function (also known as photon correlation spectroscopy or quasi-elastic light scattering). In the time domain analysis, the autocorrelation function (ACF) usually decays starting from zero delay time, and faster dynamics due to smaller particles lead to faster decorrelation of scattered intensity trace. It has been shown that the intensity ACF is the Fourier transform of the power spectrum, and therefore the DLS measurements can be equally well performed in the spectral domain. DLS can also be used to probe the behavior of complex fluids such as concentrated polymer solutions. Setup A monochromatic light source, usually a laser, is shot through a polarizer and into a sample. The scattered light then ...
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Shape Factor (other)
Shape factor refers to a value that is affected by an object's shape but is independent of its dimensions. It may refer to one of number of values in physics, engineering, image analysis, or statistics. In physics: *Shape factor, or shaping factor, a performance measure for filters such as band-pass filters *Shape factor of crystallites, a term in the Scherrer equation used in X-ray diffraction *The view factor in the field of radiative heat transfer In engineering: * Shape factor (boundary layer flow) *Structural indices derived from falling weight deflectometer data In image analysis: * Shape factor (image analysis and microscopy) including: **The compactness measure of a shape In statistics: *The shape parameter In probability theory and statistics, a shape parameter (also known as form parameter) is a kind of numerical parameter of a parametric family of probability distributionsEveritt B.S. (2002) Cambridge Dictionary of Statistics. 2nd Edition. CUP. t ...
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Index Of Sphericity
Index (or its plural form indices) may refer to: Arts, entertainment, and media Fictional entities * Index (''A Certain Magical Index''), a character in the light novel series ''A Certain Magical Index'' * The Index, an item on a Halo megastructure in the ''Halo'' series of video games Periodicals and news portals * ''Index Magazine'', a publication for art and culture * Index.hr, a Croatian online newspaper * index.hu, a Hungarian-language news and community portal * ''The Index'' (Kalamazoo College), a student newspaper * ''The Index'', an 1860s European propaganda journal created by Henry Hotze to support the Confederate States of America * ''Truman State University Index'', a student newspaper Other arts, entertainment and media * The Index (band) * ''Indexed'', a Web cartoon by Jessica Hagy * ''Index'', album by Ana Mena Business enterprises and events * Index (retailer), a former UK catalogue retailer * INDEX, a market research fair in Lucknow, India * Index Corpora ...
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Hydraulic Diameter
The hydraulic diameter, , is a commonly used term when handling flow in non-circular tubes and channels. Using this term, one can calculate many things in the same way as for a round tube. When the cross-section is uniform along the tube or channel length, it is defined as : D_\text = \frac, where : is the cross-sectional area of the flow, : is the wetted perimeter of the cross-section. More intuitively, the hydraulic diameter can be understood as a function of the hydraulic radius , which is defined as the cross-sectional area of the channel divided by the wetted perimeter. Here, the wetted perimeter includes all surfaces acted upon by shear stress from the fluid. : R_\text = \frac, : D_\text = 4R_\text, Note that for the case of a circular pipe, : D_\text =\frac=2R The need for the hydraulic diameter arises due to the use of a single dimension in case of dimensionless quantity such as Reynolds number, which prefer a single variable for flow analysis rather than the set of ...
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Stokes Radius
The Stokes radius or Stokes–Einstein radius of a solute is the radius of a hard sphere that diffuses at the same rate as that solute. Named after George Gabriel Stokes, it is closely related to solute mobility, factoring in not only size but also solvent effects. A smaller ion with stronger hydration, for example, may have a greater Stokes radius than a larger ion with weaker hydration. This is because the smaller ion drags a greater number of water molecules with it as it moves through the solution. Stokes radius is sometimes used synonymously with effective hydrated radius in solution. Hydrodynamic radius, ''R''''H'', can refer to the Stokes radius of a polymer or other macromolecule. Spherical case According to Stokes’ law, a perfect sphere traveling through a viscous liquid feels a drag force proportional to the frictional coefficient f: F_\text = fs = (6 \pi \eta a)s where \eta is the liquid's viscosity, s is the sphere's drift speed, and a is its radius. Because ...
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Stokes' Law
In 1851, George Gabriel Stokes derived an expression, now known as Stokes' law, for the frictional force – also called drag force – exerted on spherical objects with very small Reynolds numbers in a viscous fluid. Stokes' law is derived by solving the Stokes flow limit for small Reynolds numbers of the Navier–Stokes equations.Batchelor (1967), p. 233. Statement of the law The force of viscosity on a small sphere moving through a viscous fluid is given by: :F_ = 6 \pi \mu R v where: * ''F''d is the frictional force – known as Stokes' drag – acting on the interface between the fluid and the particle * ''μ'' is the dynamic viscosity (some authors use the symbol ''η'') * ''R'' is the radius of the spherical object * ''v'' is the flow velocity relative to the object. In SI units, ''F''d is given in newtons (= kg m s−2), ''μ'' in Pa·s (= kg m−1 s−1), ''R'' in meters, and ''v'' in m/s. Stokes' law makes the following assumptions for the behavior of a particle i ...
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Soil Texture
Soil texture is a classification instrument used both in the field and laboratory to determine soil classes based on their physical texture. Soil texture can be determined using qualitative methods such as texture by feel, and quantitative methods such as the hydrometer method based on Stokes' law. Soil texture has agricultural applications such as determining crop suitability and to predict the response of the soil to environmental and management conditions such as drought or calcium (lime) requirements. Soil texture focuses on the particles that are less than two millimeters in diameter which include sand, silt, and clay. The USDA soil taxonomy and WRB soil classification systems use 12 textural classes whereas the UK-ADAS system uses 11.''Soil Science Division Staff. 2017. Soil survey sand. C. Ditzler, K. Scheffe, and H.C. Monger (eds.). USDA Handbook 18. Government Printing Office, Washington, D.C.'' These classifications are based on the percentages of sand, silt, and clay ...
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Viscosity
The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the internal frictional force between adjacent layers of fluid that are in relative motion. For instance, when a viscous fluid is forced through a tube, it flows more quickly near the tube's axis than near its walls. Experiments show that some stress (such as a pressure difference between the two ends of the tube) is needed to sustain the flow. This is because a force is required to overcome the friction between the layers of the fluid which are in relative motion. For a tube with a constant rate of flow, the strength of the compensating force is proportional to the fluid's viscosity. In general, viscosity depends on a fluid's state, such as its temperature, pressure, and rate of deformation. However, the dependence on some of these properties is ...
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Absolute Temperature
Thermodynamic temperature is a quantity defined in thermodynamics as distinct from kinetic theory or statistical mechanics. Historically, thermodynamic temperature was defined by Kelvin in terms of a macroscopic relation between thermodynamic work and heat transfer as defined in thermodynamics, but the kelvin was redefined by international agreement in 2019 in terms of phenomena that are now understood as manifestations of the kinetic energy of free motion of microscopic particles such as atoms, molecules, and electrons. From the thermodynamic viewpoint, for historical reasons, because of how it is defined and measured, this microscopic kinetic definition is regarded as an "empirical" temperature. It was adopted because in practice it can generally be measured more precisely than can Kelvin's thermodynamic temperature. A thermodynamic temperature reading of zero is of particular importance for the third law of thermodynamics. By convention, it is reported on the ''Kelvin scale'' ...
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Boltzmann's Constant
The Boltzmann constant ( or ) is the proportionality factor that relates the average relative kinetic energy of particles in a gas with the thermodynamic temperature of the gas. It occurs in the definitions of the kelvin and the gas constant, and in Planck's law of black-body radiation and Boltzmann's entropy formula, and is used in calculating thermal noise in resistors. The Boltzmann constant has dimensions of energy divided by temperature, the same as entropy. It is named after the Austrian scientist Ludwig Boltzmann. As part of the 2019 redefinition of SI base units, the Boltzmann constant is one of the seven " defining constants" that have been given exact definitions. They are used in various combinations to define the seven SI base units. The Boltzmann constant is defined to be exactly . Roles of the Boltzmann constant Macroscopically, the ideal gas law states that, for an ideal gas, the product of pressure and volume is proportional to the product of amount of ...
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Einstein Relation (kinetic Theory)
In physics (specifically, the kinetic theory of gases), the Einstein relation is a previously unexpected connection revealed independently by William Sutherland in 1904, Albert Einstein in 1905, and by Marian Smoluchowski in 1906 in their works on Brownian motion. The more general form of the equation is D = \mu \, k_\text T, where * is the diffusion coefficient; * is the "mobility", or the ratio of the particle's terminal drift velocity to an applied force, ; * is the Boltzmann constant; * is the absolute temperature. This equation is an early example of a fluctuation-dissipation relation. Two frequently used important special forms of the relation are: * Einstein–Smoluchowski equation, for diffusion of charged particles: D = \frac * Stokes–Einstein equation, for diffusion of spherical particles through a liquid with low Reynolds number: D = \frac Here * is the electrical charge of a particle; * is the electrical mobility of the charged particle; * is the dyna ...
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