Electrochemical Dualism
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Electrochemical Dualism
Electrochemical dualism is an obsolete scientific theory in chemistry relevant between around 1800 and around 1830 and pioneered by Jöns Jacob Berzelius.''Jöns Jacob Berzelius'', Richard A. Pizzi, Today's Chemist At Work, 2004, page 58 The theory held that all molecules are salts composed of basic and acidic oxides. The compound potassium sulphate for example was viewed as a salt of K2O and SO3. Berzelius based his theory on investigations he conducted in collaboration with Wilhelm Hisinger on certain salts with the newly discovered voltaic pile. They observed that many compounds could be decomposed by an electric current in an acidic component at the positive pole and a basic component at the negative pole. The theory was ultimately challenged and made redundant by radical theory Radical theory is an obsolete scientific theory in chemistry describing the structure of organic compounds. The theory was pioneered by Justus von Liebig, Friedrich Wöhler and Auguste Laurent around 18 ...
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Obsolete Scientific Theory
This list catalogs well-accepted theories in science and pre-scientific natural philosophy and natural history which have since been superseded by scientific theories. Many discarded explanations were once supported by a scientific consensus, but replaced after more empirical information became available that identified flaws and prompted new theories which better explain the available data. Pre-modern explanations originated before the scientific method, with varying degrees of empirical support. Some theories are discarded in their entirety, such as the replacement of the phlogiston theory by energy and thermodynamics. Some theories known to be incomplete or in some ways incorrect are still used. For example, Newtonian classical mechanics is accurate enough for practical calculations at everyday distances and velocities, and it is still taught in schools. The more complicated relativistic mechanics must be used for long distances and velocities nearing the speed of light, and ...
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Chemistry
Chemistry is the science, scientific study of the properties and behavior of matter. It is a natural science that covers the Chemical element, elements that make up matter to the chemical compound, compounds made of atoms, molecules and ions: their composition, structure, properties, behavior and the changes they undergo during a Chemical reaction, reaction with other Chemical substance, substances. Chemistry also addresses the nature of chemical bonds in chemical compounds. In the scope of its subject, chemistry occupies an intermediate position between physics and biology. It is sometimes called the central science because it provides a foundation for understanding both Basic research, basic and Applied science, applied scientific disciplines at a fundamental level. For example, chemistry explains aspects of plant growth (botany), the formation of igneous rocks (geology), how atmospheric ozone is formed and how environmental pollutants are degraded (ecology), the properties ...
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Jöns Jacob Berzelius
Baron Jöns Jacob Berzelius (; by himself and his contemporaries named only Jacob Berzelius, 20 August 1779 – 7 August 1848) was a Swedish chemist. Berzelius is considered, along with Robert Boyle, John Dalton, and Antoine Lavoisier, to be one of the founders of modern chemistry. Berzelius became a member of the Royal Swedish Academy of Sciences in 1808 and served from 1818 as its principal functionary. He is known in Sweden as the "Father of Swedish Chemistry". Berzelius Day is celebrated on 20 August in honour of him. Although Berzelius began his career as a physician, his enduring contributions were in the fields of electrochemistry, chemical bonding and stoichiometry. In particular, he is noted for his determination of atomic weights and his experiments that led to a more complete understanding of the principles of stoichiometry, which is the branch of chemistry pertaining to the quantitative relationships between elements in chemical compounds and chemical reactions and ...
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Potassium Sulphate
Potassium sulfate (US) or potassium sulphate (UK), also called sulphate of potash (SOP), arcanite, or archaically potash of sulfur, is the inorganic compound with formula K2SO4, a white water-soluble solid. It is commonly used in fertilizers, providing both potassium and sulfur. History Potassium sulfate (K2SO4) has been known since early in the 14th century. It was studied by Glauber, Boyle, and Tachenius. In the 17th century, it was named ''arcanuni'' or ''sal duplicatum'', as it was a combination of an acid salt with an alkaline salt. It was also known as ''vitriolic tartar'' and ''Glaser's salt'' or ''sal polychrestum Glaseri'' after the pharmaceutical chemist Christopher Glaser who prepared it and used medicinally. Known as ''arcanum duplicatum'' ("double secret") or ''panacea duplicata'' in pre-modern medicine, it was prepared from the residue (''caput mortuum'') left over from the production of aqua fortis (nitric acid, HNO3) from nitre (potassium nitrate, KNO3) and oil ...
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Wilhelm Hisinger
Wilhelm Hisinger (23 December 1766 – 28 June 1852) was a Swedish physicist and chemist who in 1807, working in coordination with Jöns Jakob Berzelius, noted that in electrolysis any given substance always went to the same pole, and that substances attracted to the same pole had other properties in common. This showed that there was at least a qualitative correlation between the chemical and electrical natures of bodies. Career In 1803, in separate laboratories, Martin Heinrich Klaproth in one, and Berzelius and Hisinger in another, the element Cerium was discovered, which was named after the newly discovered asteroid, Ceres. It was discovered nearly simultaneously by both laboratories, though it was later shown that Berzelius and Hisinger's cerium was actually a mixture of cerium, lanthanum and so-called didymium. The element was first isolated by Carl Gustaf Mosander in 1838. Hisinger was elected a member of the Royal Swedish Academy of Sciences in 1804. Death and legacy ...
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Voltaic Pile
upright=1.2, Schematic diagram of a copper–zinc voltaic pile. The copper and zinc discs were separated by cardboard or felt spacers soaked in salt water (the electrolyte). Volta's original piles contained an additional zinc disk at the bottom, and an additional copper disk at the top. These were later shown to be unnecessary file:VoltaBattery.JPG, upA voltaic pile on display in the ''Tempio Voltiano'' (the Volta Temple) near Volta's home in Como, Italy The voltaic pile was the first electrical battery that could continuously provide an electric current to a circuit. It was invented by Italian chemist Alessandro Volta, who published his experiments in 1799. The voltaic pile then enabled a rapid series of other discoveries including the electrical decomposition (electrolysis) of water into oxygen and hydrogen by William Nicholson and Anthony Carlisle (1800) and the discovery or isolation of the chemical elements sodium (1807), potassium (1807), calcium (1808), boron (1808), b ...
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Radical Theory
Radical theory is an obsolete scientific theory in chemistry describing the structure of organic compounds. The theory was pioneered by Justus von Liebig, Friedrich Wöhler and Auguste Laurent around 1830 and is not related to the modern understanding of free radicals. In this theory, organic compounds were thought to exist as combinations of radicals that could be exchanged in chemical reactions just as chemical elements could be interchanged in inorganic compounds. Preamble The term radical was already in use when radical theory was developed. Louis-Bernard Guyton de Morveau introduced the phrase "radical" in 1785 and the phrase was employed by Antoine Lavoisier in 1789 in his Traité Élémentaire de Chimie. A radical was identified as the root base of certain acids (The Latin word "radix" meaning "root"). The combination of a radical with oxygen would result in an acid. For example the radical of acetic acid was called "acetic" and that of muriatic acid (hydrochloric acid) was c ...
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Obsolete Scientific Theories
This list catalogs well-accepted theories in science and pre-scientific natural philosophy and natural history which have since been superseded by scientific theories. Many discarded explanations were once supported by a scientific consensus, but replaced after more empirical information became available that identified flaws and prompted new theories which better explain the available data. Pre-modern explanations originated before the scientific method, with varying degrees of empirical support. Some theories are discarded in their entirety, such as the replacement of the phlogiston theory by energy and thermodynamics. Some theories known to be incomplete or in some ways incorrect are still used. For example, Newtonian classical mechanics is accurate enough for practical calculations at everyday distances and velocities, and it is still taught in schools. The more complicated relativistic mechanics must be used for long distances and velocities nearing the speed of light, and ...
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