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Europium(III) Nitrate
Europium(III) nitrate is an inorganic compound with the formula . The hexahydrate is a common salt. It forms colorless hygroscopic crystals. Preparation The salt is usually obtained by dissolving europium(III) oxide (Eu2O3) in nitric acid produces europium(III) nitrate. : Eu2O3 + 6 HNO3 → 2 Eu(NO3)3 + 3 H2O Structure Like all trinitates of the lanthanides, dilute (<0.01 M) solutions of consists of the where x = 8 or 9. At higher concentrations, the binding of nitrate to Eu is observed. Complexes Europium(III) nitrate reacts with anions and other Lewis bases to form complexes. For example, with 1,3,5-,[...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Europium(III) Phosphate
Europium(III) phosphate is one of the phosphates of europium, with the chemical formula of EuPO4. Other phosphates include europium(II) phosphate (Eu3(PO4)2) and europium(II,III) phosphate (Eu3Eu(PO4)3). Preparation Europium phosphate can be produced by the sol-gel method of europium(III) oxide. First, europium(III) oxide was dissolved in an equimolar amount of nitric acid, and then an excess of 10% phosphoric acid was added. The process also requires the addition of ammonia to adjust the pH to 4 and form a gel, which is then washed with water and heated to 1200 °C for a day. Properties Europium(III) phosphate is isotypic to CePO4 and crystallizes in the monazite structure type, in the space group ''P''21/n (no. 14, position 2) with the lattice parameters ''a'' = 668.13(10), ''b'' = 686.18(9), ''c'' = 634.91(8) pm and β = 103.96(1)° with four formula units per unit cell. Its heat capacity is 111.5 J·K−1·mol−1 at 298.15 K, and its bulk modulus The ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Europium(III) Arsenate
Europium(III) arsenate is an arsenate salt of europium, with the chemical formula of EuAsO4. It has good thermal stability, with its p''K''sp,c of 22.53±0.03. It is a colorless crystal with a xenotime structure. Preparation Europium(III) arsenate can be prepared by reacting sodium arsenate (Na3AsO4) in a europium(III) chloride (EuCl3) solution:Gabisoniya, Ts. D.; Nanobashvili, E. M.. Synthesis of rare earth metal arsenates. ''Soobshcheniya Akademii Nauk Gruzinskoi SSR'' (1980), 97(2), 345-8. : Na3AsO4 + EuCl3 → 3 NaCl + EuAsO4↓ Reacting europium(III) oxide (Eu2O3) with arsenic pentoxide Arsenic pentoxide is the inorganic compound with the formula As2O5. This glassy, white, deliquescent solid is relatively unstable, consistent with the rarity of the As(V) oxidation state. More common, and far more important commercially, is ars ... (As2O5) can also obtain europium(III) arsenate. :Eu2O3 + As2O5 → 2EuAsO4 References {{Arsenates Europium(III) compounds category:Ar ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Samarium(III) Nitrate
Samarium(III) nitrate is an odorless, white-colored chemical compound with the formula Sm(NO3)3. It forms the hexahydrate, which decomposes at 50°C to the anhydrous form. When further heated to 420°C, it is converted to the oxynitrate, and at 680°C it decomposes to form samarium(III) oxide. Synthesis Samarium(III) nitrate is produced by the reaction of samarium hydroxide and nitric acid: : Uses Samarium(III) nitrate is a lewis acid catalyst that is used to produce a nitrate precursor solution that is used as a nanocatalyst in the solid oxide regenerative fuel cells. The nanocatalyst is made by mixing samarium(III) nitrate hexahydrate, strontium nitrate, and cobalt(II) nitrate hexahydrate. Samarium(III) nitrate is also used for the preparation of samarium doped ceria, which can be used in the fabrication of electrolytes for fuel cells. The samarium doped ceria is produced by mixing cerium(III) nitrate Cerium nitrate refers to a family of nitrates of cerium in the +3 or ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gadolinium(III) Nitrate
Gadolinium(III) nitrate is an inorganic compound of gadolinium. This salt is used as a water-soluble neutron poison in nuclear reactors. Gadolinium nitrate, like all nitrate salts, is an oxidizing agent. The most common form of this substance is hexahydrate Gd(NO3)3•6H2O with molecular weight 451.36 g/mol and CAS Number: 19598-90- Use Gadolinium nitrate was used at the Savannah River Site heavy water nuclear reactors and had to be separated from the heavy water for storage or reuse. The Canadian CANDU reactor, a pressurized heavy water reactor, also uses gadolinium nitrate as a water-soluble neutron poison in heavy water. Gadolinium nitrate is also used as a raw material in the production of other gadolinium compounds, for production of specialty glasses and ceramics and as a phosphor A phosphor is a substance that exhibits the phenomenon of luminescence; it emits light when exposed to some type of radiant energy. The term is used both for fluorescent or phosphorescen ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Europium(II) Nitrate
Europium is a chemical element with the symbol Eu and atomic number 63. Europium is the most reactive lanthanide by far, having to be stored under an inert fluid to protect it from atmospheric oxygen or moisture. Europium is also the softest lanthanide, as it can be dented with a fingernail and easily cut with a knife. When oxidation is removed a shiny-white metal is visible. Europium was isolated in 1901 and is named after the continent of Europe. Being a typical member of the lanthanide series, europium usually assumes the oxidation state +3, but the oxidation state +2 is also common. All europium compounds with oxidation state +2 are slightly reducing. Europium has no significant biological role and is relatively non-toxic as compared to other heavy metals. Most applications of europium exploit the phosphorescence of europium compounds. Europium is one of the rarest of the rare-earth elements on Earth.Stwertka, Albert. ''A Guide to the Elements'', Oxford University Press, 1996, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Europium(III) Oxide
Europium(III) oxide (Eu2O3), is a chemical compound of europium and oxygen. It is widely used as a red or blue phosphor in television sets and fluorescent lamps, and as an activator for yttrium-based phosphors. It is also an agent for the manufacture of fluorescent glass. Europium fluorescence is used in the anti-counterfeiting phosphors in Euro banknotes. Europium oxide has two common structures: Monoclinic ( mS30, space group ''C''2/''m'', No. 12) and cubic ( cI80, space group ''I''a, No. 206). The cubic structure is similar to that of manganese(III) oxide. It may be formed by ignition of europium Europium is a chemical element with the symbol Eu and atomic number 63. Europium is the most reactive lanthanide by far, having to be stored under an inert fluid to protect it from atmospheric oxygen or moisture. Europium is also the softest lanth ... metal. It can react with acids to form the corresponding europium(III) salts. Gallery File:Tl2O3structure.jpg, Cubic Eu2O3 File:Gd ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Europium Nitrate UV Comparison
Europium is a chemical element with the symbol Eu and atomic number 63. Europium is the most reactive lanthanide by far, having to be stored under an inert fluid to protect it from atmospheric oxygen or moisture. Europium is also the softest lanthanide, as it can be dented with a fingernail and easily cut with a knife. When oxidation is removed a shiny-white metal is visible. Europium was isolated in 1901 and is named after the continent of Europe. Being a typical member of the lanthanide series, europium usually assumes the oxidation state +3, but the oxidation state +2 is also common. All europium compounds with oxidation state +2 are slightly reducing. Europium has no significant biological role and is relatively non-toxic as compared to other heavy metals. Most applications of europium exploit the phosphorescence of europium compounds. Europium is one of the rarest of the rare-earth elements on Earth.Stwertka, Albert. ''A Guide to the Elements'', Oxford University Press, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Europium(III) Oxide
Europium(III) oxide (Eu2O3), is a chemical compound of europium and oxygen. It is widely used as a red or blue phosphor in television sets and fluorescent lamps, and as an activator for yttrium-based phosphors. It is also an agent for the manufacture of fluorescent glass. Europium fluorescence is used in the anti-counterfeiting phosphors in Euro banknotes. Europium oxide has two common structures: Monoclinic ( mS30, space group ''C''2/''m'', No. 12) and cubic ( cI80, space group ''I''a, No. 206). The cubic structure is similar to that of manganese(III) oxide. It may be formed by ignition of europium Europium is a chemical element with the symbol Eu and atomic number 63. Europium is the most reactive lanthanide by far, having to be stored under an inert fluid to protect it from atmospheric oxygen or moisture. Europium is also the softest lanth ... metal. It can react with acids to form the corresponding europium(III) salts. Gallery File:Tl2O3structure.jpg, Cubic Eu2O3 File:Gd ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitric Acid
Nitric acid is the inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but older samples tend to be yellow cast due to decomposition into oxides of nitrogen. Most commercially available nitric acid has a concentration of 68% in water. When the solution contains more than 86% , it is referred to as ''fuming nitric acid''. Depending on the amount of nitrogen dioxide present, fuming nitric acid is further characterized as red fuming nitric acid at concentrations above 86%, or white fuming nitric acid at concentrations above 95%. Nitric acid is the primary reagent used for nitration – the addition of a nitro group, typically to an organic molecule. While some resulting nitro compounds are shock- and thermally-sensitive explosives, a few are stable enough to be used in munitions and demolition, while others are still more stable and used as pigments in inks and dyes. Nitric acid is also commonly used as a strong oxidizing agen ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Aquo Complex
In chemistry, metal aquo complexes are coordination compounds containing metal ions with only water as a ligand. These complexes are the predominant species in aqueous solutions of many metal salts, such as metal nitrates, sulfates, and perchlorates. They have the general stoichiometry . Their behavior underpins many aspects of environmental, biological, and industrial chemistry. This article focuses on complexes where water is the only ligand ("homoleptic aquo complexes"), but of course many complexes are known to consist of a mix of aquo and other ligands. Stoichiometry and structure Hexa-aquo complexes Most aquo complexes are mono-nuclear, with the general formula , with or 3; they have an octahedral structure. The water molecules function as Lewis bases, donating a pair of electrons to the metal ion and forming a dative covalent bond with it. Typical examples are listed in the following table. : Tutton's salts are crystalline compounds with the generic formula (where ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lewis Base
A Lewis acid (named for the American physical chemist Gilbert N. Lewis) is a chemical species that contains an empty orbital which is capable of accepting an electron pair from a Lewis base to form a Lewis adduct. A Lewis base, then, is any species that has a filled orbital containing an electron pair which is not involved in bonding but may form a dative bond with a Lewis acid to form a Lewis adduct. For example, NH3 is a Lewis base, because it can donate its lone pair of electrons. Trimethylborane (Me3B) is a Lewis acid as it is capable of accepting a lone pair. In a Lewis adduct, the Lewis acid and base share an electron pair furnished by the Lewis base, forming a dative bond. In the context of a specific chemical reaction between NH3 and Me3B, a lone pair from NH3 will form a dative bond with the empty orbital of Me3B to form an adduct NH3•BMe3. The terminology refers to the contributions of Gilbert N. Lewis. From p. 142: "We are inclined to think of substances as pos ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Trimesic Acid
Trimesic acid, also known as benzene-1,3,5-tricarboxylic acid, is an organic compound with the formula C6H3(CO2H)3. It is one of three isomers of benzenetricarboxylic acid. A colorless solid, trimesic acid has some commercial value as a precursor to some plasticizers. Trimesic acid can be combined with ''para''-hydroxypyridine to make a water-based gel, stable up to 95 °C. Trimesic acid crystallizes from water in a hydrogen-bonded hydrated network with wide unidimensional empty channels. See also * Trimellitic acid (1,2,4-benzenetricarboxylic acid) * Hemimellitic acid Hemimellitic acid (benzene-1,2,3-tricarboxylic acid) is an organic compound with the molecular formula C6H3(СО2Н)3. Like the other isomers of benzenetricarboxylic acid, hemimellitic acid is a colorless solid. It is prepared by oxidation of 1, ... (1,2,3-benzenetricarboxylic acid) References Benzoic acids Tricarboxylic acids {{organic-compound-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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