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Depolymerisation
Depolymerization (or depolymerisation) is the process of converting a polymer into a monomer or a mixture of monomers. This process is driven by an increase in entropy. Ceiling temperature The tendency of polymers to depolymerize is indicated by their ceiling temperature. At this temperature, the enthalpy of polymerization matches the entropy gained by converting a large molecule into monomers. Above the ceiling temperature, the rate of depolymerization is greater than the rate of polymerization, which inhibits the formation of the given polymer. Applications Depolymerization is a very common process. Digestion of food involves depolymerization of macromolecules, such as proteins. It is relevant to polymer recycling. Sometimes the depolymerization is well behaved, and clean monomers can be reclaimed and reused for making new plastic. In other cases, such as polyethylene, depolymerization gives a mixture of products. These products are, for polyethylene, ethylene, propylen ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermal Depolymerization
Thermal depolymerization (TDP) is the process of converting a polymer into a monomer or a mixture of monomers, by predominantly thermal means. It may be catalysed or un-catalysed and is distinct from other forms of depolymerisation which may rely on the use of chemicals or biological action. This process is associated with an increase in entropy. For most polymers thermal depolymerisation is chaotic process, giving a mixture of volatile compounds. Materials may be depolymerised in this way during waste management, with the volatile components produced being burnt as a form of synthetic fuel in a waste-to-energy process. For other polymers thermal depolymerisation is an ordered process giving a single product, or limited range of products, these transformations are usually more valuable and form the basis of some plastic recycling technologies. Disordered depolymerisation For most polymeric materials thermal depolymerisation proceeds in a disordered manner, with random chain scissi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Condensed Tannins Depolymerisation
Condensed tannins (proanthocyanidins, polyflavonoid tannins, catechol-type tannins, pyrocatecollic type tannins, non-hydrolyzable tannins or flavolans) are polymers formed by the condensation of flavans. They do not contain sugar residues. They are called proanthocyanidins as they yield anthocyanidins when depolymerized under oxidative conditions. Different types of condensed tannins exist, such as the procyanidins, propelargonidins, prodelphinidins, profisetinidins, proteracacinidins, proguibourtinidins or prorobinetidins. All of the above are formed from flavan-3-ols, but flavan-3,4-diols, called (leucoanthocyanidin) also form condensed tannin oligomers, e.g. leuco-fisetinidin form profisetinidin, and flavan-4-ols form condensed tannins, e.g. 3',4',5,7-flavan-4-ol form proluteolinidin (luteoforolor). One particular type of condensed tannin, found in grape, are procyanidins, which are polymers of 2 to 50 (or more) catechin units joined by carbon-carbon bonds. These are not susc ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Plastic Recycling
Plastic recycling is the reprocessing of plastic waste into new products. When performed correctly, this can reduce dependence on landfill, conserve resources and protect the environment from plastic pollution and greenhouse gas emissions. Although recycling rates are increasing, they lag behind those of other recoverable materials, such as aluminium, glass and paper. Since the beginning of plastic production in the 20th century, until 2015, the world has produced some 6.3 billion tonnes of plastic waste, only 9% of which has been recycled, and only ~1% has been recycled more than once. Additionally, 12% was incinerated and the remaining 79% disposed of to landfill or to the environment including the sea. Recycling is necessary because almost all plastic is non-biodegradable and thus builds-up in the environment, where it can cause harm. For example, approximately 8 million tons of waste plastic enter the Earth's oceans every year, causing damage to the aquatic ecosystem and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polymer Degradation
Polymer degradation is the reduction in the physical properties of a polymer, such as strength, caused by changes in its chemical composition. Polymers and particularly plastics are subject to degradation at all stages of their product life cycle, including during their initial processing, use, disposal into the environment and recycling. The rate of this degradation varies significantly; biodegradation can take decades, whereas some industrial processes can completely decompose a polymer in hours. Technologies have been developed to both inhibit or promote degradation. For instance, polymer stabilizers ensure plastic items are produced with the desired properties, extend their useful lifespans, and facilitate their recycling. Conversely, biodegradable additives accelerate the degradation of plastic waste by improving its biodegradability. Some forms of plastic recycling can involve the complete degradation of a polymer back into monomers or other chemicals. In general, the effec ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Depolymerization Of Polystyrene Via Radical Elimination Mechanism
Depolymerization (or depolymerisation) is the process of converting a polymer into a monomer or a mixture of monomers. This process is driven by an increase in entropy. Ceiling temperature The tendency of polymers to depolymerize is indicated by their ceiling temperature. At this temperature, the enthalpy of polymerization matches the entropy gained by converting a large molecule into monomers. Above the ceiling temperature, the rate of depolymerization is greater than the rate of polymerization, which inhibits the formation of the given polymer. Applications Depolymerization is a very common process. Digestion of food involves depolymerization of macromolecules, such as proteins. It is relevant to polymer recycling. Sometimes the depolymerization is well behaved, and clean monomers can be reclaimed and reused for making new plastic. In other cases, such as polyethylene, depolymerization gives a mixture of products. These products are, for polyethylene, ethylene, propylene ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thiolysis
Thiolysis is a reaction with a thiol (R-SH) that cleaves one compound into two. Thiolysis involves the addition of coenzyme A to one of the products. This reaction is similar to hydrolysis, which involves water instead of a thiol. This reaction is seen in β-oxidation of fatty acids. The depolymerisation of condensed tannin Condensed tannins (proanthocyanidins, polyflavonoid tannins, catechol-type tannins, pyrocatecollic type tannins, non-hydrolyzable tannins or flavolans) are polymers formed by the condensation of flavans. They do not contain sugar residues. They ...s with the use of benzyl mercaptan as nucleophile is also called thiolysis. References Substitution reactions Tannins {{Reaction-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polymer
A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic and natural polymers play essential and ubiquitous roles in everyday life. Polymers range from familiar synthetic plastics such as polystyrene to natural biopolymers such as DNA and proteins that are fundamental to biological structure and function. Polymers, both natural and synthetic, are created via polymerization of many small molecules, known as monomers. Their consequently large molecular mass, relative to small molecule compounds, produces unique physical properties including toughness, high elasticity, viscoelasticity, and a tendency to form amorphous and semicrystalline structures rather than crystals. The term "polymer" derives from the Greek word πολύς (''polus'', meaning "many, much") and μέρος (''meros'' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polymerisation
In polymer chemistry, polymerization (American English), or polymerisation (British English), is a process of reacting monomer molecules together in a chemical reaction to form polymer chains or three-dimensional networks. There are many forms of polymerization and different systems exist to categorize them. In chemical compounds, polymerization can occur via a variety of reaction mechanisms that vary in complexity due to the functional groups present in the reactants and their inherent steric effects. In more straightforward polymerizations, alkenes form polymers through relatively simple radical reactions; in contrast, reactions involving substitution at a carbonyl group require more complex synthesis due to the way in which reactants polymerize. Alkanes can also be polymerized, but only with the help of strong acids. As alkenes can polymerize in somewhat straightforward radical reactions, they form useful compounds such as polyethylene and polyvinyl chloride (PVC), whi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pure And Applied Chemistry
''Pure and Applied Chemistry'' is the official journal for the International Union of Pure and Applied Chemistry (IUPAC). It is published monthly by Walter de Gruyter Walter de Gruyter GmbH, known as De Gruyter (), is a German scholarly publishing house specializing in academic literature. History The roots of the company go back to 1749 when Frederick the Great granted the Königliche Realschule in Be ... and contains recommendations and reports, and lectures from symposia. References Chemistry journals Publications established in 1960 De Gruyter academic journals {{chem-journal-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lignin
Lignin is a class of complex organic polymers that form key structural materials in the support tissues of most plants. Lignins are particularly important in the formation of cell walls, especially in wood and bark, because they lend rigidity and do not rot easily. Chemically, lignins are polymers made by cross-linking phenolic precursors. History Lignin was first mentioned in 1813 by the Swiss botanist A. P. de Candolle, who described it as a fibrous, tasteless material, insoluble in water and alcohol but soluble in weak alkaline solutions, and which can be precipitated from solution using acid. He named the substance “lignine”, which is derived from the Latin word '' lignum'', meaning wood. It is one of the most abundant organic polymers on Earth, exceeded only by cellulose. Lignin constitutes 30% of non-fossil organic carbon on Earth, and 20 to 35% of the dry mass of wood. Lignin is present in red algae, which suggest that the common ancestor of plants and red algae ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Acid Catalyst
In acid catalysis and base catalysis, a chemical reaction is catalyzed by an acid or a base. By Brønsted–Lowry acid–base theory, the acid is the proton (hydrogen ion, H+) donor and the base is the proton acceptor. Typical reactions catalyzed by proton transfer are esterifications and aldol reactions. In these reactions, the conjugate acid of the carbonyl group is a better electrophile than the neutral carbonyl group itself. Depending on the chemical species that act as the acid or base, catalytic mechanisms can be classified as either specific catalysis and general catalysis. Many enzymes operate by general catalysis. Applications and examples Brønsted acids Acid catalysis is mainly used for organic chemical reactions. Many acids can function as sources for the protons. Acid used for acid catalysis include hydrofluoric acid (in the alkylation process), phosphoric acid, toluenesulfonic acid, polystyrene sulfonate, heteropoly acids, zeolites. Strong acids catalyze the hy ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
