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Decamethylcyclopentasiloxane
Decamethylcyclopentasiloxane, also known as D5 and D5, is an organosilicon compound with the formula . It is a colorless and odorless liquid that is slightly volatile. Use The compound is classified as a cyclomethicone. Such fluids are commonly used in cosmetics, such as deodorants, sunblocks, hair sprays and skin care products. It is becoming more common in hair conditioners, as it makes the hair easier to brush without breakage. It is also used as part of silicone-based personal lubricants. D5 is considered an emollient. In Canada, among the volume used in consumer products approximately 70% were for antiperspirants and 20% for hair care products. 10,000–100,000 tonnes per year of D5 is manufactured and/or imported in the European Economic Area. Atmospheric emissions of D5 in the Northern Hemisphere were estimated to 30,000 tonnes per year. Production and polymerization Commercially D5 is produced from dimethyldichlorosilane. Hydrolysis of the dichloride produces a mixt ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cyclomethicone
A siloxane is a functional group in organosilicon chemistry with the Si−O−Si linkage. The parent siloxanes include the oligomeric and polymeric hydrides with the formulae H(OSiH2)''n''OH and (OSiH2)n. Siloxanes also include branched compounds, the defining feature of which is that each pair of silicon centres is separated by one oxygen (O2-) atom. The siloxane functional group forms the backbone of silicones, the premier example of which is polydimethylsiloxane (PDMS). The functional group R3SiO− (where the three Rs may be different) is called siloxy. Siloxanes are manmade and have many commercial and industrial applications because of the compounds’ hydrophobicity, low thermal conductivity, and high flexibility. Structure Siloxanes generally adopt structures expected for linked tetrahedral ("''sp''3-like") centers. The Silicon-oxygen bond, Si−O bond length is 1.64 Å (vs Si–C distance of 1.92 Å) and the Silicon–oxygen bond#Bond angles, Si-O-Si angl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Octamethylcyclotetrasiloxane
Octamethylcyclotetrasiloxane, also called D4, is an organosilicon compound with the formula . It is a colorless viscous liquid. It is a common cyclomethicone. It is widely used in cosmetics. Production and polymerization Commercially D4 is produced from dimethyldichlorosilane. Hydrolysis of the dichloride produces a mixture of cyclic dimethylsiloxanes and polydimethylsiloxane. From this mixture, the cyclic siloxanes including D4 can be removed by distillation. In the presence of a strong base such as KOH, the polymer/ring mixture is equilibrated, allowing complete conversion to the more volatile cyclic siloxanes: : D4 and D5 are also precursors to the polymer. The catalyst is again KOH. Occurrence It is among the most important of all the cyclic siloxanes, with a global production volume of 136 million kilograms in 1993. 100,000–1,000,000 tonnes per year of D4 is manufactured and/or imported in the European Economic Area. Safety and environmental considerations D4 is of l ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Structural Formula
The structural formula of a chemical compound is a graphic representation of the molecular structure (determined by structural chemistry methods), showing how the atoms are possibly arranged in the real three-dimensional space. The chemical bonding within the molecule is also shown, either explicitly or implicitly. Unlike other chemical formula types, which have a limited number of symbols and are capable of only limited descriptive power, structural formulas provide a more complete geometric representation of the molecular structure. For example, many chemical compounds exist in different isomeric forms, which have different enantiomeric structures but the same molecular formula. There are multiple types of ways to draw these structural formulas such as: Lewis Structures, condensed formulas, skeletal formulas, Newman projections, Cyclohexane conformations, Haworth projections, and Fischer projections. Several systematic chemical naming formats, as in chemical databases, are used ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Skincare
Skin care is a range of practices that support skin integrity, enhance its appearance, and relieve skin conditions. They can include nutrition, avoidance of excessive sun exposure, and appropriate use of emollients. Practices that enhance appearance include the use of cosmetics, botulinum, exfoliation, fillers, laser resurfacing, microdermabrasion, peels, retinol therapy, and ultrasonic skin treatment. Skin care is a routine daily procedure in many settings, such as skin that is either too dry or too moist, and prevention of dermatitis and prevention of skin injuries. Skin care is a part of the treatment of wound healing, radiation therapy and some medications. Background Skin care is at the interface of cosmetics and dermatology.''Random House Webster's Unabridged Dictionary.'' Random House, Inc. 2001. Page 537. The US Federal Food, Drug, and Cosmetic Act defines cosmetics as products intended to cleanse or beautify (for instance, shampoos and lipstick). A separate categor ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Potassium Hydroxide
Potassium hydroxide is an inorganic compound with the formula K OH, and is commonly called caustic potash. Along with sodium hydroxide (NaOH), KOH is a prototypical strong base. It has many industrial and niche applications, most of which exploit its caustic nature and its reactivity toward acids. An estimated 700,000 to 800,000 tonnes were produced in 2005. KOH is noteworthy as the precursor to most soft and liquid soaps, as well as numerous potassium-containing chemicals. It is a white solid that is dangerously corrosive. Properties and structure KOH exhibits high thermal stability. Because of this high stability and relatively low melting point, it is often melt-cast as pellets or rods, forms that have low surface area and convenient handling properties. These pellets become tacky in air because KOH is hygroscopic. Most commercial samples are ca. 90% pure, the remainder being water and carbonates. Its dissolution in water is strongly exothermic. Concentrated aqueous solut ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrolysis
Hydrolysis (; ) is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution reaction, substitution, elimination reaction, elimination, and solvation reactions in which water is the nucleophile. Biological hydrolysis is the cleavage of biomolecules where a water molecule is consumed to effect the separation of a larger molecule into component parts. When a carbohydrate is broken into its component sugar molecules by hydrolysis (e.g., sucrose being broken down into glucose and fructose), this is recognized as saccharification. Hydrolysis reactions can be the reverse of a condensation reaction in which two molecules join into a larger one and eject a water molecule. Thus hydrolysis adds water to break down, whereas condensation builds up by removing water. Types Usually hydrolysis is a chemical process in which a molecule of water is added to a substance. Sometimes this addition causes both the substance and w ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dimethyldichlorosilane
Dimethyldichlorosilane is a tetrahedral, organosilicon compound with the formula Si(CH3)2Cl2. At room temperature it is a colorless liquid that readily reacts with water to form both linear and cyclic Si-O chains. Dimethyldichlorosilane is made on an industrial scale as the principal precursor to dimethylsilicone and polysilane compounds. History The first organosilicon compounds were reported in 1863 by Charles Friedel and James Crafts who synthesized tetraethylsilane from diethylzinc and silicon tetrachloride.Silicon: Organosilicon Chemistry. Encyclopedia of Inorganic Chemistry Online, 2nd ed.; Wiley: New Jersey, 2005. However, major progress in organosilicon chemistry did not occur until Frederick Kipping and his students began experimenting with diorganodichlorosilanes (R2SiCl2) that were prepared by reacting silicon tetrachloride with Grignard reagents. Unfortunately, this method suffered from many experimental problems. In the 1930s, the demand for silicones increased ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Environmental Science & Technology
''Environmental Science & Technology'' is a biweekly peer-reviewed scientific journal published since 1967 by the American Chemical Society. It covers research in environmental science and environmental technology, including environmental policy. ''Environmental Science & Technology'' has a sister journal, ''Environmental Science & Technology Letters'', which publishes short communications. The editor-in-chief of ''Environmental Science & Technology'' is Prof. Julie Zimmerman (Yale University). Previous editors have been: David Sedlak (University of California, Berkeley, 2014 - 2020), James J. Morgan (California Institute of Technology; founding editor, 1967-1975), Russell F. Christman (University of North Carolina, 1975-1987), William H. Glaze (University of North Carolina, 1987-2003) and Jerald L. Schnoor (University of Iowa, 2002-2014). Abstracting and indexing According to the ''Journal Citation Reports'', the journal has a 2021 impact factor of 11.357. The journal is abstra ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Northern Hemisphere
The Northern Hemisphere is the half of Earth that is north of the Equator. For other planets in the Solar System, north is defined as being in the same celestial hemisphere relative to the invariable plane of the solar system as Earth's North Pole. Owing to Earth's axial tilt of 23.439281°, winter in the Northern Hemisphere lasts from the December solstice (typically December 21 UTC) to the March equinox (typically March 20 UTC), while summer lasts from the June solstice through to the September equinox (typically on 23 September UTC). The dates vary each year due to the difference between the calendar year and the astronomical year. Within the Northern Hemisphere, oceanic currents can change the weather patterns that affect many factors within the north coast. Such events include El Niño–Southern Oscillation. Trade winds blow from east to west just above the equator. The winds pull surface water with them, creating currents, which flow westward due to the Coriolis e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
ECHA
The European Chemicals Agency (ECHA; ) is an agency of the European Union which manages the technical and administrative aspects of the implementation of the European Union regulation called Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH). ECHA is the driving force among regulatory authorities in implementing the EU's chemicals legislation. ECHA has to ascertain that companies comply with the legislation, advances the safe use of chemicals, provides information on chemicals and addresses chemicals of concern. It is located in Helsinki, Finland. ECHA is an independent and mature regulatory agency established by REACH. It is not a subsidiary entity of the European Commission. The agency, currently headed by Acting Executive Director Shay O’Malley, started working on 1 June 2007. Establishment The ECHA was created by European Union regulation dating from 18 December 2006 to manage the then-new legislation to regulate the manufacture and use of chemic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
European Economic Area
The European Economic Area (EEA) was established via the ''Agreement on the European Economic Area'', an international agreement which enables the extension of the European Union's single market to member states of the European Free Trade Association. The EEA links the EU member states and three EFTA states (Iceland, Liechtenstein, and Norway) into an internal market governed by the same basic rules. These rules aim to enable free movement of persons, goods, services, and capital within the European single market, including the freedom to choose residence in any country within this area. The EEA was established on 1 January 1994 upon entry into force of the EEA Agreement. The contracting parties are the EU, its member states, and Iceland, Liechtenstein, and Norway. The EEA Treaty is a commercial treaty and differs from the EU Treaties in certain key respects. According to Article 1 its purpose is to "promote a continuous and balanced strengthening of trade and economic relati ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Donald Mackay (scientist)
Donald Mackay, (born 30 October 1936) is a Canadian scientist and engineer specializing in environmental chemistry. He was a member of the faculty of Chemical Engineering and Applied Chemistry at the University of Toronto and the founding director of the Canadian Environmental Modelling Centre at Trent University. He has developed several multimedia fugacity models. Mackay has stressed that principles of good practice also need to be adopted for chemical assessments, especially in a regulatory context. In 2004, he was invested as an Officer of the Order of Canada for having "greatly contributed to the quality and our stewardship of the global environment". In 2004, he was also invested into the Order of Ontario The Order of Ontario () is the most prestigious official Award, honour in the Provinces and territories of Canada, Canadian province of Ontario. Instituted in 1986 by Lieutenant Governor of Ontario, Lieutenant Governor Lincoln Alexander, on the A ... for "his outsta ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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