Curium(III) Chloride
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Curium(III) Chloride
Curium(III) chloride is the chemical compound with the formula CmCl3. Structure Curium(III) chloride has a 9 coordinate tricapped trigonal prismatic geometry. Preparation Curium(III) chloride can be prepared by the reaction of curium nitride with cadmium chloride Cadmium chloride is a white crystalline compound of cadmium and chloride, with the formula CdCl2. This salt is a hygroscopic solid that is highly soluble in water and slightly soluble in alcohol. The crystal structure of cadmium chloride (describe .... References {{inorganic-compound-stub Curium compounds Nuclear materials Chlorides Actinide halides ...
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Tricapped Trigonal Prismatic Molecular Geometry
In chemistry, the tricapped trigonal prismatic molecular geometry describes the shape of compounds where nine atoms, groups of atoms, or ligands are arranged around a central atom, defining the vertices of a triaugmented triangular prism (a trigonal prism In chemistry, octahedral molecular geometry, also called square bipyramidal, describes the shape of compounds with six atoms or groups of atoms or ligands symmetrically arranged around a central atom, defining the vertices of an octahedron. The oc ... with an extra atom attached to each of its three rectangular faces). It is very similar to the capped square antiprismatic molecular geometry, and there is some dispute over the specific geometry exhibited by certain molecules. Examples * is usually considered to have a tricapped trigonal prismatic geometry, although its geometry is sometimes described as capped square antiprismatic instead. * (Ln = La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy) * {{MolecularGeometry Ste ...
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Cadmium Chloride
Cadmium chloride is a white crystalline compound of cadmium and chloride, with the formula CdCl2. This salt is a hygroscopic solid that is highly soluble in water and slightly soluble in alcohol. The crystal structure of cadmium chloride (described below), is a reference for describing other crystal structures. Also known are CdCl2•H2O and CdCl2•5H2O. Structure Cadmium chloride forms a layered structure consisting of octahedral Cd2+ centers linked with chloride ligands. Cadmium iodide, CdI2, has a similar structure, but the iodide ions are arranged in a HCP lattice, whereas in CdCl2 the chloride ions are arranged in a CCP lattice.N. N. Greenwood, A. Earnshaw, ''Chemistry of the Elements'', 2nd ed., Butterworth-Heinemann, Oxford, UK, 1997. Chemical properties Cadmium chloride dissolves well in water and other polar solvents. It is a mild Lewis acid. :CdCl2 + 2 Cl− → dCl4sup>2− Solutions of equimolar cadmium chloride and potassium chloride give potassium cadmium trichlo ...
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Curium Compounds
Curium compounds are compounds containing the element curium (Cm). Curium usually forms compounds in the +3 oxidation state, although compounds with curium in the +4, +5 and +6 oxidation states are also known. Oxides Curium readily reacts with oxygen forming mostly Cm2O3 and CmO2 oxides,Delta T2Cm2O3 + O2. Or, Cm2O3 can be obtained by reducing CmO2 with molecular hydrogen: : 2CmO2 + H2 -> Cm2O3 + H2O Also, a number of ternary oxides of the type M(II)CmO3 are known, where M stands for a divalent metal, such as barium. Thermal oxidation of trace quantities of curium hydride (CmH2–3) has been reported to give a volatile form of CmO2 and the volatile trioxide CmO3, one of two known examples of the very rare +6 state for curium. Another observed species was reported to behave similar to a supposed plutonium tetroxide and was tentatively characterized as CmO4, with curium in the extremely rare +8 state; but new experiments seem to indicate that CmO4 does not exist, and have cast do ...
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Nuclear Materials
Nuclear material refers to the metals uranium, plutonium, and thorium, in any form, according to the IAEA. This is differentiated further into "source material", consisting of natural and depleted uranium, and "special fissionable material", consisting of enriched uranium (U-235), uranium-233, and plutonium-239. Uranium ore concentrates are considered to be a "source material", although these are not subject to safeguards under the Nuclear Non-Proliferation Treaty. According to the Nuclear Regulatory Commission(NRC), there are four different types of regulated nuclear materials: special nuclear material, source material, byproduct material and radium. Special nuclear materials have plutonium, uranium-233 or uranium with U233 or U235 that has a content found more than in nature. Source material is thorium or uranium that has a U235 content equal to or less than what is in nature. Byproduct material is radioactive material that is not source or special nuclear material. It can be a ...
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Chlorides
The chloride ion is the anion (negatively charged ion) Cl−. It is formed when the element chlorine (a halogen) gains an electron or when a compound such as hydrogen chloride is dissolved in water or other polar solvents. Chloride salts such as sodium chloride are often very soluble in water.Green, John, and Sadru Damji. "Chapter 3." ''Chemistry''. Camberwell, Vic.: IBID, 2001. Print. It is an essential electrolyte located in all body fluids responsible for maintaining acid/base balance, transmitting nerve impulses and regulating liquid flow in and out of cells. Less frequently, the word ''chloride'' may also form part of the "common" name of chemical compounds in which one or more chlorine atoms are covalently bonded. For example, methyl chloride, with the standard name chloromethane (see IUPAC books) is an organic compound with a covalent C−Cl bond in which the chlorine is not an anion. Electronic properties A chloride ion (diameter 167  pm) is much larger than ...
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