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Cryoscopic Constant
In thermodynamics, the cryoscopic constant, , relates molality to freezing point depression (which is a colligative property). It is the ratio of the latter to the former: :\Delta T_f = -i \cdot K_f \cdot b * is the van ‘t Hoff factor, the number of particles the solute splits into or forms when dissolved. * is the molality of the solution. Through cryoscopy, a known constant can be used to calculate an unknown molar mass. The term "cryoscopy" comes from Greek and means "freezing measurement." Freezing point depression is a colligative property, so depends only on the number of solute particles dissolved, not the nature of those particles. Cryoscopy is related to ebullioscopy, which determines the same value from the ebullioscopic constant (of boiling point elevation). The value of , which depends on the nature of the solvent can be found out by the following equation: :K_ = \frac * is the ideal gas constant * is the molar mass In chemistry, the molar mass of a ch ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molality
Molality is a measure of the number of moles of solute in a solution corresponding to 1 kg or 1000 g of solvent. This contrasts with the definition of molarity which is based on a specified volume of solution. A commonly used unit for molality in chemistry is Mole (unit), mol/kilogram, kg. A solution of concentration 1 mol/kg is also sometimes denoted as ''1 molal''. The unit ''mol/kg'' requires that molar mass be expressed in ''kg/mol'', instead of the usual ''g/mol'' or ''kg/kmol''. Definition The molality (''b''), of a Solution (chemistry), solution is defined as the amount of substance (in mole (unit), moles) of solute, ''n''solute, divided by the mass (in kg) of the solvent, ''m''solvent: :b = \frac In the case of solutions with more than one solvent, molality can be defined for the mixed solvent considered as a pure pseudo-solvent. Instead of mole solute per kilogram solvent as in the binary case, units are defined as mole solute per kilogram mixed solvent. Ori ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Freezing Point Depression
Freezing-point depression is a drop in the minimum temperature at which a substance freezing, freezes, caused when a smaller amount of another, non-Volatility (chemistry), volatile substance is added. Examples include adding salt into water (used in ice cream makers and for De-icing#Chemical de-icers, de-icing roads), alcohol in water, ethylene or propylene glycol in water (used in antifreeze in cars), adding copper to molten silver (used to make Solder#Hard_solder, solder that flows at a lower temperature than the silver pieces being joined), or the mixing of two solids such as impurities into a finely powdered drug. In all cases, the substance added/present in smaller amounts is considered the solute, while the original substance present in larger quantity is thought of as the solvent. The resulting liquid solution or solid-solid mixture has a lower freezing point than the pure solvent or solid because the chemical potential of the solvent in the mixture is lower than that of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Colligative Property
In chemistry, colligative properties are those properties of Solution (chemistry), solutions that depend on the ratio of the number of solute particles to the number of solvent Particle, particles in a solution, and not on the nature of the chemical species present. The number ratio can be related to the various units for concentration of a solution such as molarity, molality, normality (chemistry), etc. The assumption that solution properties are independent of nature of solute particles is exact only for ideal solutions, which are solutions that exhibit Thermodynamics, thermodynamic properties analogous to those of an ideal gas, and is approximate for dilute real solutions. In other words, colligative properties are a set of solution properties that can be reasonably approximated by the assumption that the solution is ideal. Only properties which result from the dissolution of a nonvolatile solute in a volatile liquid solvent are considered.KL Kapoor ''Applications of Thermodyna ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Van ‘t Hoff Factor
A van is a type of road vehicle used for transporting goods or people. Depending on the type of van, it can be bigger or smaller than a pickup truck and SUV, and bigger than a common car. There is some varying in the scope of the word across the different English-speaking countries. The smallest vans, microvans, are used for transporting either goods or people in tiny quantities. Mini MPVs, compact MPVs, and MPVs are all small vans usually used for transporting people in small quantities. Larger vans with passenger seats are used for institutional purposes, such as transporting students. Larger vans with only front seats are often used for business purposes, to carry goods and equipment. Specially-equipped vans are used by television stations as mobile studios. Postal services and courier companies use large step vans to deliver packages. Word origin and usage Van meaning a type of vehicle arose as a contraction of the word caravan. The earliest records of a van as a vehicle i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cryoscopy
Freezing-point depression is a drop in the minimum temperature at which a substance freezes, caused when a smaller amount of another, non- volatile substance is added. Examples include adding salt into water (used in ice cream makers and for de-icing roads), alcohol in water, ethylene or propylene glycol in water (used in antifreeze in cars), adding copper to molten silver (used to make solder that flows at a lower temperature than the silver pieces being joined), or the mixing of two solids such as impurities into a finely powdered drug. In all cases, the substance added/present in smaller amounts is considered the solute, while the original substance present in larger quantity is thought of as the solvent. The resulting liquid solution or solid-solid mixture has a lower freezing point than the pure solvent or solid because the chemical potential of the solvent in the mixture is lower than that of the pure solvent, the difference between the two being proportional to the natu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molar Mass
In chemistry, the molar mass of a chemical compound is defined as the mass of a sample of that compound divided by the amount of substance which is the number of moles in that sample, measured in moles. The molar mass is a bulk, not molecular, property of a substance. The molar mass is an ''average'' of many instances of the compound, which often vary in mass due to the presence of isotopes. Most commonly, the molar mass is computed from the standard atomic weights and is thus a terrestrial average and a function of the relative abundance of the isotopes of the constituent atoms on Earth. The molar mass is appropriate for converting between the mass of a substance and the amount of a substance for bulk quantities. The molecular mass and formula mass are commonly used as a synonym of molar mass, particularly for molecular compounds; however, the most authoritative sources define it differently. The difference is that molecular mass is the mass of one specific particle or molecul ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Greek Language
Greek ( el, label=Modern Greek, Ελληνικά, Elliniká, ; grc, Ἑλληνική, Hellēnikḗ) is an independent branch of the Indo-European family of languages, native to Greece, Cyprus, southern Italy (Calabria and Salento), southern Albania, and other regions of the Balkans, the Black Sea coast, Asia Minor, and the Eastern Mediterranean. It has the longest documented history of any Indo-European language, spanning at least 3,400 years of written records. Its writing system is the Greek alphabet, which has been used for approximately 2,800 years; previously, Greek was recorded in writing systems such as Linear B and the Cypriot syllabary. The alphabet arose from the Phoenician script and was in turn the basis of the Latin, Cyrillic, Armenian, Coptic, Gothic, and many other writing systems. The Greek language holds a very important place in the history of the Western world. Beginning with the epics of Homer, ancient Greek literature includes many works of lasting impo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ebullioscopy
An ebullioscope (from the Latin ''ēbullīre'' (to boil) + -scope) is an instrument for measuring the boiling point of a liquid. This can be used for determining the alcoholic strength of a mixture, or for determining the molecular weight of a non-volatile solute based on the boiling-point elevation. The procedure is known as ebullioscopy. The first ebullioscope was invented in 1838 by Honoré Brossard-Vidal, and was used for measuring alcoholic content. The advantage of this method was that the boiling point is relatively insensitive to other components such as sugars. Older alcoholimeters were based on measuring the density, which is more sensitive to the presence of other solutes. A famous ebullioscope variant was built by Pierre Marie Edouard Malligand, patented in 1876 The device is used by winemakers still to this day to measure the alcohol contents of wines, using the "Malligand degree" (M°) as a unit of measure.{{Citation needed, date=September 2022 A later version was ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ebullioscopic Constant
In thermodynamics, the ebullioscopic constant relates molality to boiling point elevation. It is the ratio of the latter to the former: :\Delta T = iK_\text b * is the van 't Hoff factor, the number of particles the solute splits into or forms when dissolved. * is the molality of the solution. A formula to compute the ebullioscopic constant is: :K_\text = \frac * is the ideal gas constant. * is boiling point of the solvent. * is the molar mass of the solvent. * is the molar enthalpy of vaporization. Through the procedure called ebullioscopy, a known constant can be used to calculate an unknown molar mass. The term ''ebullioscopy'' comes from the Latin language and means "boiling measurement". This is related to cryoscopy, which determines the same value from the cryoscopic constant (of freezing point depression). This property of elevation of boiling point is a colligative property. It means that the property, in this case , depends on the number of particles dissolved int ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Boiling Point Elevation
Boiling-point elevation describes the phenomenon that the boiling point of a liquid (a solvent) will be higher when another compound is added, meaning that a solution has a higher boiling point than a pure solvent. This happens whenever a non-volatile solute, such as a salt, is added to a pure solvent, such as water. The boiling point can be measured accurately using an ebullioscope. Explanation The ''boiling point elevation'' is a colligative property, which means that it is dependent on the presence of dissolved particles and their number, but not their identity. It is an effect of the dilution of the solvent in the presence of a solute. It is a phenomenon that happens for all solutes in all solutions, even in ideal solutions, and does not depend on any specific solute–solvent interactions. The boiling point elevation happens both when the solute is an electrolyte, such as various salts, and a nonelectrolyte. In thermodynamic terms, the origin of the boiling point elevation is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ideal Gas Constant
The molar gas constant (also known as the gas constant, universal gas constant, or ideal gas constant) is denoted by the symbol or . It is the molar equivalent to the Boltzmann constant, expressed in units of energy per temperature increment per amount of substance, i.e. the pressure–volume product, rather than energy per temperature increment per ''particle''. The constant is also a combination of the constants from Boyle's law, Charles's law, Avogadro's law, and Gay-Lussac's law. It is a physical constant that is featured in many fundamental equations in the physical sciences, such as the ideal gas law, the Arrhenius equation, and the Nernst equation. The gas constant is the constant of proportionality that relates the energy scale in physics to the temperature scale and the scale used for amount of substance. Thus, the value of the gas constant ultimately derives from historical decisions and accidents in the setting of units of energy, temperature and amount of substance ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Freezing Point
The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depends on pressure and is usually specified at a standard pressure such as 1 atmosphere or 100 kPa. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point. Because of the ability of substances to supercool, the freezing point can easily appear to be below its actual value. When the "characteristic freezing point" of a substance is determined, in fact, the actual methodology is almost always "the principle of observing the disappearance rather than the formation of ice, that is, the melting point." Examples For most substances, melting and freezing points are approximately equal. For example, the melting point ''and'' freezing point of mercury is . Ho ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
