Copper Carbonate
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Copper Carbonate
Copper carbonate may refer to : ;Copper (II) compounds and minerals * Copper(II) carbonate proper, (neutral copper carbonate): a rarely seen moisture-sensitive compound. * Basic copper carbonate (the "copper carbonate" of commerce), actually a copper carbonate hydroxide; which may be either ** ()2: the green mineral malachite, verdigris, the pigment "green verditer" or "mountain green" ** ()2()2: the blue mineral azurite, and the pigment "blue verditer" or "mountain blue" **Lapis armenus, a precious stone, a basic copper carbonate from Armenia *Marklite, a hydrated copper carbonate mineral ;Copper (I) compounds * Copper(I) carbonate, Cu2CO3 {{chemistry index ...
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Malachite
Malachite is a copper carbonate hydroxide mineral, with the formula Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fractures and deep, underground spaces, where the water table and hydrothermal fluids provide the means for chemical precipitation. Individual crystals are rare, but occur as slender to acicular prisms. Pseudomorphs after more tabular or blocky azurite crystals also occur. Etymology and history The stone's name derives (via la, molochītis, frm, melochite, and Middle English ''melochites'') from Greek Μολοχίτης λίθος ''molochites lithos'', "mallow-green stone", from μολόχη ''molochē'', variant of μαλάχη ''malāchē'', "mallow". The mineral was given this name due to its resemblance to the leaves of the mallow plant. Malachite was mined from deposits near the Isthmus of Suez and the Sinai as early as 4000 BCE. It wa ...
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Copper(II) Carbonate
Copper(II) carbonate or cupric carbonate is a chemical compound with formula . At ambient temperatures, it is an ionic solid (a salt) consisting of copper(II) cations and carbonate anions . This compound is rarely encountered because it is difficult to prepare and readily reacts with water moisture from the air. The terms "copper carbonate", "copper(II) carbonate", and "cupric carbonate" almost always refer (even in chemistry texts) to a basic copper carbonate (or copper(II) carbonate hydroxide), such as ()2 (which occurs naturally as the mineral malachite) or ()2()2 (azurite). For this reason, the qualifier neutral may be used instead of "basic" to refer specifically to . Preparation Reactions that may be expected to yield , such as mixing solutions of copper(II) sulfate and sodium carbonate in ambient conditions, yield instead a basic carbonate and , due to the great affinity of the ion for the hydroxide anion . Thermal decomposition of the basic carbonate at atmospheri ...
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Basic Copper Carbonate
Basic copper carbonate is a chemical compound, more properly called copper(II) carbonate hydroxide. It is an ionic compound (a salt) consisting of the ions copper(II) , carbonate , and hydroxide . The name most commonly refers to the compound with formula ()2. It is a green crystalline solid that occurs in nature as the mineral malachite. It has been used since antiquity as a pigment, and it is still used as such in artist paints, sometimes called verditer, green bice, or mountain green. Sometimes the name is used for ()2()2, a blue crystalline solid also known as the mineral azurite. It too has been used as pigment, sometimes under the name mountain blue or blue verditer. Both malachite and azurite can be found in the verdigris patina that is found on weathered brass, bronze, and copper. The composition of the patina can vary, in a maritime environment depending on the environment a basic chloride may be present, in an urban environment basic sulfates may be present. This com ...
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Verdigris
Verdigris is the common name for blue-green, copper-based pigments that form a patina on copper, bronze, and brass. The technical literature is ambiguous as to its chemical composition. Some sources refer to "neutral verdigris" as copper(II) acetate monohydrate () and to "blue verdigris" as . Another source describes it as a basic copper carbonate (()2), and, when near the sea, basic copper chloride (Cu2(OH)3Cl). Still other sources describe verdigris as .(Cu(OH)2)n where n varies from 0 to 3. The alchemical symbol for verdigris is 🜨 (unicode U+1F728). Etymology The name ''verdigris'' comes from the Middle English ''vertegrez'', from the Old French ''verte grez'', meaning ''vert d'aigre'', "green ade by action ofvinegar". The modern French writing of this word is ''vert-de-gris'' ("green of grey"), sounding like the older name ''verdet gris'' ("grey greenish"), itself a deformation of ''verte grez''. It was used as a pigment in paintings and other art objects (as green col ...
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Azurite
Azurite is a soft, deep-blue copper mineral produced by weathering of copper ore deposits. During the early 19th century, it was also known as chessylite, after the Type locality (geology), type locality at Chessy, Rhône, Chessy-les-Mines near Lyon, France. The mineral, a basic carbonate with the chemical formula Cu3(CO3)2(OH)2, has been known since ancient times, and was mentioned in Pliny the Elder's ''Natural History (Pliny), Natural History'' under the Greek name (κυανός: "deep blue," root of English ''cyan'') and the Latin name ''caeruleum''. Since antiquity, azurite's exceptionally deep and clear blue has been associated with low-humidity desert and winter skies. The modern English name of the mineral reflects this association, since both ''azurite'' and ''Azure (color), azure'' are derived via Arabic language, Arabic from the Persian language, Persian (لاژورد), an area known for its deposits of another deep-blue stone, lapis lazuli ("stone of azure"). Minera ...
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Lapis Armenus
Lapis armenus, also known as Armenian stone or lapis stellatus, in natural history, is a variety of precious stone, resembling lapis lazuli, except that it is softer, and instead of veins of pyrite, is intermixed with green. "The Armenian stone" is so similar to ''lapis lazuli'' that it has often not been distinguished from it; ''Webster's Revised Unabridged Dictionary'' for instance treats the two terms as synonyms. The ''Dictionary of Traded Goods and Commodities 1550-1820'' defines ''lapis armenus'' as Armenian stone, or azurite, a naturally occurring basic carbonate, originally from Armenia, but later from Germany, from which was prepared. It was often found in association with another copper carbonate, malachite from which was prepared... Probably because they were both blue, blue bice was sometimes misinterpreted to mean . Chemically however lapis lazuli is not at all similar. Herman Boerhaave believed it rather to rank among semi-metals, and supposed it was composed of ...
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Marklite
Marklite is a hydrated copper carbonate mineral named after Gregor Markl, a German mineralogist at the University of Tübingen. Markl found the type specimen of marklite in the dumps of the Friedrich-Christian mine in the Black Forest Mountains in southwestern Germany. Markl specializes in crustal petrology and geochemistry and has studied the hydrothermal ore deposits of the Black Forest area. Jakub Plášil of the Institute of Physics at the Academy of Sciences of the Czech Republic and colleagues identified its structure. Marklite crystals are long, thin blades that reach 0.2 mm in length. The mineral is chemically similar to georgeite, claraite, cuproartinite, azurite, and malachite. Localities Germany Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated betwe ...: Friedrich-Christi ...
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