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Carboborate
The borate carbonates are mixed anion compounds containing both borate and carbonate A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate g ... ions. Compared to mixed anion compounds containing halides, these are quite rare. They are hard to make, requiring higher temperatures, which are likely to decompose carbonate to carbon dioxide. The reason for the difficulty of formation is that when entering a crystal lattice, the anions have to be correctly located, and correctly oriented. They are also known as carbonatoborates or borocarbonates. Although these compounds have been termed carboborate, that word also refers to the C=B=C5− anion, or CB11H12− anion. This last anion should be called 1-carba-closo-dodecaborate or monocarba-closo-dodecaborate. Some borate carbonates have additional ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Canavesite
Canavesite, Mg2(HBO3)(CO3)∙5H2O, is a rare carboborate mineral from the abandoned Brosso mine in Italy. Canavesite is a secondary mineral that occurs due to the weathering of ludwigite-magnetite skarn on the surface of mine walls. The physical properties consist of milky-white rosette-like aggregates of elongated transparent fibers shown in figure one.Chao, G.Y., Fliesher, Mandarino, J.A. (1979) New Mineral Names*.,American Mineralogist, 64, 652–659. It has the crystal symmetry of a monoclinic with a diffraction symbol of ''2/mP-/-''. History Giussani & Vighi saw and described boron mineralization in 1964 in a pyrite mine, Brosso, in Italy. They noticed secondary minerals forming between szaibelyite and ludwigite at the point where they come into contact with each other inside magnetite skarns. Years later in 1972 a few members from the Gruppo Mineralogico Lombardo found the first sample of a new unknown mineral around the same location. Since then canavesite has been trad ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mixed Anion Compounds
Mixed anion compounds, heteroanionic materials or mixed anion materials are chemical compounds containing cations and more than one kind of anion. The compounds contain a single phase, rather than just a mixture. Use in materials science By having more than one anion, many more compounds can be made, and properties tuned to desirable values. In terms of optics, properties include laser damage threshold, refractive index, birefringence, absorption particularly in the ultraviolet or near infrared, non-linearity. Mechanical properties can include ability to grow a large crystal, ability to form a thin layer, strength, or brittleness. Thermal properties can include melting point, thermal stability, phase transition temperatures, Thermal expansion coefficient. For electrical properties, electric conductivity, band gap, superconducting transition temperature piezoelectricity, pyroelectricity, ferromagnetism, dielectric constant, charge-density wave transition can be adjusted. Pro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Borates
A borate is any of several boron oxyanions, negative ions consisting of boron and oxygen, such as orthoborate , metaborate , or tetraborate ; or any salt with such anions, such as sodium metaborate, and disodium tetraborate . The name also refers to certain functional groups in molecules consisting of boron and oxygen, and esters with such groups, such as triethyl orthoborate . Natural occurrence Borate ions occur, alone or with other anions, in many borate and borosilicate minerals such as borax, boracite, ulexite (boronatrocalcite) and colemanite. Borates also occur in seawater, where they make an important contribution to the absorption of low frequency sound in seawater. Borates also occur in plants, including almost all fruits. Anions The main borate anions are: * tetrahydroxyborate , found in sodium tetrahydroxyborate . * orthoborate , found in trisodium orthoborate * perborate , as in sodium perborate * metaborate or , found in sodium metaborate * diborate , f ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mereheadite
Mereheadite is a rare oxychloride that can be found with Mendipite at Merehead quarry, Cranmore, Somerset, in the United Kingdom. Most specimens are associated with calcite, mendipite or hydrous cerussite in the Manganese pods on vein two at torr works quarry (merehead quarry). This mineral is associated with symesite which is also light yellow to orange. Symesite is found in small blotches on the calcites or mendipites; Mereheadite does not, as it is most often found in veins Veins are blood vessels in humans and most other animals that carry blood towards the heart. Most veins carry deoxygenated blood from the tissues back to the heart; exceptions are the pulmonary and umbilical veins, both of which carry oxygenated b .... References Halide minerals Monoclinic minerals Minerals in space group 15 {{Halide-mineral-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Borate
A borate is any of several boron oxyanions, negative ions consisting of boron and oxygen, such as orthoborate , metaborate , or tetraborate ; or any salt with such anions, such as sodium metaborate, and disodium tetraborate . The name also refers to certain functional groups in molecules consisting of boron and oxygen, and esters with such groups, such as triethyl orthoborate . Natural occurrence Borate ions occur, alone or with other anions, in many borate and borosilicate minerals such as borax, boracite, ulexite (boronatrocalcite) and colemanite. Borates also occur in seawater, where they make an important contribution to the absorption of low frequency sound in seawater. Borates also occur in plants, including almost all fruits. Anions The main borate anions are: * tetrahydroxyborate , found in sodium tetrahydroxyborate . * orthoborate , found in trisodium orthoborate * perborate , as in sodium perborate * metaborate or , found in sodium metaborate * diborate , f ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
