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Cyclopentadienylchromium Tricarbonyl Dimer
Cyclopentadienylchromium tricarbonyl dimer is the organochromium compound with the formula Cp2Cr2(CO)6, where Cp is C5H5. A dark green crystalline solid. It is the subject of research it exists in measureable equilibrium quantities with the monometallic radical CpCr(CO)3. Structure and synthesis The six CO ligands are terminal, and the Cr-Cr bond distance is 3.281 Å, 0.06 Å longer than the related dimolybdenum compound. The compound is prepared by treatment of chromium hexacarbonyl with sodium cyclopentadienide Sodium cyclopentadienide is an organosodium compound with the formula C5H5Na. The compound is often abbreviated as NaCp, where Cp− is the cyclopentadienide anion. Sodium cyclopentadienide is a colorless solid, although samples often are p ... followed by oxidation of the resulting NaCr(CO)3(C5H5). Related compounds * Cyclopentadienylmolybdenum tricarbonyl dimer * Cyclopentadienyltungsten tricarbonyl dimer References {{chromium compounds Organochromium c ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organochromium Compound
Organochromium chemistry is a branch of organometallic chemistry that deals with organic compounds containing a chromium to carbon bond and their reactions. The field is of some relevance to organic synthesis. The relevant oxidation states for organochromium complexes encompass the entire range of possible oxidation states from –4 (d10) in Na4[Cr–IV(CO)4] to +6 (d0) in oxo-alkyl complexes like Cp*CrVI(=O)2Me. History The first organochromium compound was described in 1919 by Franz Hein. He treated phenylmagnesium bromide with chromium(III) chloride to give a new product (after hydrolysis) which he incorrectly identified as pentaphenyl chromium bromide (Ph5CrBr). Years later, in 1957 H.H. Zeiss et al. repeated Hein's experiments and correctly arrived at a cationic bisarene chromium sandwich compound (ArH2Cr+). Bis(benzene)chromium itself was discovered around the same time in 1956 by Ernst Otto Fischer by reaction of chromium(III) chloride, benzene and aluminum chloride. The rela ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Crystal
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macroscopic single crystals are usually identifiable by their geometrical shape, consisting of flat faces with specific, characteristic orientations. The scientific study of crystals and crystal formation is known as crystallography. The process of crystal formation via mechanisms of crystal growth is called crystallization or solidification. The word ''crystal'' derives from the Ancient Greek word (), meaning both "ice" and "rock crystal", from (), "icy cold, frost". Examples of large crystals include snowflakes, diamonds, and table salt. Most inorganic solids are not crystals but polycrystals, i.e. many microscopic crystals fused together into a single solid. Polycrystals include most metals, rocks, ceramics, and ice. A third category of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chromium Hexacarbonyl
Chromium carbonyl, also known as chromium hexacarbonyl, is the chemical compound with the formula Cr( CO)6. At room temperature the solid is stable to air, although it does have a high vapor pressure and sublimes readily. Cr(CO)6 is zerovalent, meaning that Cr has an oxidation state of zero, and it is a homoleptic complex, which means that all the ligands are identical. The complex is octahedral with Cr–C and C–O distances of 1.91 and 1.14 Å, respectively. History The synthesis of Cr(CO)6 was described in a series of papers published in 1926–7. The procedure involves treatment of Cr(III) salts with high pressures of carbon monoxide using phenyl magnesium bromides as a reductant. Reactions Pentacarbonyl derivatives When heated or UV-irradiated in tetrahydrofuran (THF) solution, Cr(CO)6 converts to Cr(CO)5(THF) with loss of one CO ligand. The THF ligand is readily displaced. Often the THF complex is generated and used in situ. UV-irradiation of frozen solutions ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium Cyclopentadienide
Sodium cyclopentadienide is an organosodium compound with the formula C5H5Na. The compound is often abbreviated as NaCp, where Cp− is the cyclopentadienide anion. Sodium cyclopentadienide is a colorless solid, although samples often are pink owing to traces of oxidized impurities. Preparation Sodium cyclopentadienide is commercially available as a solution in THF. It is prepared by treating cyclopentadiene with sodium: : The conversion can be conducted by heating a suspension of molten sodium in dicyclopentadiene.Tarun K. Panda, Michael T. Gamer, Peter W. Roesky "An Improved Synthesis of Sodium and Potassium Cyclopentadienide" Organometallics, 2003, 22, 877–878. In former times, the sodium was provided in the form of "sodium wire" or "sodium sand", a fine dispersion of sodium prepared by melting sodium in refluxing xylene and rapidly stirring. Sodium hydride is a convenient base: : In early work, Grignard reagents were used as bases. With a p''K''a of 15, cyclopen ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Inorganic Syntheses
''Inorganic Syntheses'' is a book series which aims to publish "detailed and foolproof" procedures for the synthesis of inorganic compounds. Although this series of books are edited, they usually are referenced like a journal, without mentioning the names of the checkers (referees) or the editor. A similar format is usually followed for the series ''''. Volumes See also *Organic Syntheses
''Organic Syntheses'' is a peer-reviewed scientific journal that was established in 1921. I ...
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Cyclopentadienylmolybdenum Tricarbonyl Dimer
Cyclopentadienylmolybdenum tricarbonyl dimer is the chemical compound with the formula Cp2Mo2(CO)6, where Cp is C5H5. A dark red solid, it has been the subject of much research although it has no practical uses. Structure and synthesis The molecule exists in two rotamers, gauche and anti. The six CO ligands are terminal and the Mo-Mo bond distance is 3.2325 Å. The compound is prepared by treatment of molybdenum hexacarbonyl with sodium cyclopentadienide followed by oxidation of the resulting NaMo(CO)3(C5H5). Other methods have been developed starting with Mo(CO)3(CH3CN)3 instead of Mo(CO)6. Reactions Thermolysis of this compound in hot solution of diglyme (bis(2-methoxyethyl)ether) results in decarbonylation, giving the tetracarbonyl, which has a formal triple bond between the Mo centers (''d''MoMo = 2.448 Å):Cotton, F. A.; Walton, R. A. "Multiple Bonds Between Metal Atoms" Oxford (Oxford): 1993, p 564ff. . :(C5H5)2Mo2(CO)6 → (C5H5)2Mo2(CO)4 + 2 CO The resulting cyclopenta ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cyclopentadienyltungsten Tricarbonyl Dimer
Cyclopentadienyltungsten tricarbonyl dimer is the organotungsten compound with the formula Cp2W2(CO)6, where Cp is C5H5. A dark red crystalline solid, it is the subject of research, although it has no or few practical uses. Structure and synthesis The molecule exists in two rotamers, gauche and anti. The six CO ligands are terminal, and the W-W bond distance is 3.222 Å. The compound is prepared by treatment of tungsten hexacarbonyl with sodium cyclopentadienide followed by oxidation of the resulting NaW(CO)3(C5H5). Related compounds * Cyclopentadienylmolybdenum tricarbonyl dimer * Cyclopentadienylchromium tricarbonyl dimer Cyclopentadienylchromium tricarbonyl dimer is the organochromium compound with the formula Cp2Cr2(CO)6, where Cp is C5H5. A dark green crystalline solid. It is the subject of research it exists in measureable equilibrium quantities with the mono ... References {{tungsten compounds Organotungsten compounds Carbonyl complexes Dimers (chemistry) Half ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organochromium Compounds
Organochromium chemistry is a branch of organometallic chemistry that deals with organic compounds containing a chromium to carbon bond and their reactions. The field is of some relevance to organic synthesis. The relevant oxidation states for organochromium complexes encompass the entire range of possible oxidation states from –4 (d10) in Na4 r–IV(CO)4to +6 (d0) in oxo-alkyl complexes like Cp*CrVI(=O)2Me. History The first organochromium compound was described in 1919 by Franz Hein. He treated phenylmagnesium bromide with chromium(III) chloride to give a new product (after hydrolysis) which he incorrectly identified as pentaphenyl chromium bromide (Ph5CrBr). Years later, in 1957 H.H. Zeiss et al. repeated Hein's experiments and correctly arrived at a cationic bisarene chromium sandwich compound (ArH2Cr+). Bis(benzene)chromium itself was discovered around the same time in 1956 by Ernst Otto Fischer by reaction of chromium(III) chloride, benzene and aluminum chloride. The relate ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carbonyl Complexes
In organic chemistry, a carbonyl group is a functional group composed of a carbon atom double-bonded to an oxygen atom: C=O. It is common to several classes of organic compounds, as part of many larger functional groups. A compound containing a carbonyl group is often referred to as a carbonyl compound. The term carbonyl can also refer to carbon monoxide as a ligand in an inorganic or organometallic complex (a metal carbonyl, e.g. nickel carbonyl). The remainder of this article concerns itself with the organic chemistry definition of carbonyl, where carbon and oxygen share a double bond. Carbonyl compounds In organic chemistry, a carbonyl group characterizes the following types of compounds: Other organic carbonyls are urea and the carbamates, the derivatives of acyl chlorides chloroformates and phosgene, carbonate esters, thioesters, lactones, lactams, hydroxamates, and isocyanates. Examples of inorganic carbonyl compounds are carbon dioxide and carbonyl sulfide. A sp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dimers (chemistry)
Dimer may refer to: * Dimer (chemistry), a chemical structure formed from two similar sub-units ** Protein dimer, a protein quaternary structure ** d-dimer * Dimer model, an item in statistical mechanics, based on ''domino tiling'' * Julius Dimer Julius Dimer (1 August 1871 – 20 October 1945) was a German chess master. At the beginning of his career, he played in several mini tournaments (''Quadrangular'') in Germany; at Altona 1897, Elmshorn 1898, Munich 1900, Kiel 1901, Hamburg 1903, ... (1871–1945), German chess master See also * Dimery (botany), having two parts in a distinct whorl of a plant structure * Di (other), a prefix * Dymer (other) * -mer, a suffix * Oligomer * Peierls transition, sometimes called dimerization {{Disambiguation, surname ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Half Sandwich Compounds
One half ( : halves) is the irreducible fraction resulting from dividing one by two or the fraction resulting from dividing any number by its double. Multiplication by one half is equivalent to division by two, or "halving"; conversely, division by one half is equivalent to multiplication by two, or "doubling". One half often appears in mathematical equations, recipes, measurements, etc. Half can also be said to be one part of something divided into two equal parts. For instance, the area ''S'' of a triangle is computed. :''S'' = × perpendicular height. One half also figures in the formula for calculating figurate numbers, such as triangular numbers and pentagonal numbers: : \frac and in the formula for computing magic constants for magic squares : M_2(n) = \frac \left(n^ + 1\right) The Riemann hypothesis states that every nontrivial complex root of the Riemann zeta function has a real part equal to . One half has two different decimal expansion ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cyclopentadienyl Complexes
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Cyclopentadienyl can refer to *Cyclopentadienyl anion, or cyclopentadienide, **Cyclopentadienyl ligand *Cyclopentadienyl radical, • *Cyclopentadienyl cation, See also *Pentadienyl In organic chemistry, pentadienyl refers to the organic radical, anion, or cation with the formula , where ''z'' = 0, −1, +1, respectively. Organometallic chemistry In organometallic chemistry, the pentadienyl anion is a ligand, the acyclic ana ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
