Cobalt Oxide
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Cobalt Oxide
Cobalt oxide is a family of chemical compounds consisting of cobalt and oxygen atoms. Compounds in the cobalt oxide family include: *Cobalt(II) oxide (cobaltous oxide), CoO *Cobalt(III) oxide (cobaltic oxide), Co2O3 *Cobalt(II,III) oxide Cobalt(II,III) oxide is an inorganic compound with the formula Co3O4. It is one of two well characterized cobalt oxides. It is a black antiferromagnetic solid. As a mixed valence compound, its formula is sometimes written as CoIICoIII2O4 and ..., Co3O4 See also * Cobalt oxide nanoparticle {{Chemistry index ...
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Chemical Compounds
A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element is therefore not a compound. A compound can be transformed into a different substance by a chemical reaction, which may involve interactions with other substances. In this process, bonds between atoms may be broken and/or new bonds formed. There are four major types of compounds, distinguished by how the constituent atoms are bonded together. Molecular compounds are held together by covalent bonds; ionic compounds are held together by ionic bonds; intermetallic compounds are held together by metallic bonds; coordination complexes are held together by coordinate covalent bonds. Non-stoichiometric compounds form a disputed marginal case. A chemical formula specifies the number of atoms of each element in a compound molecule, using the sta ...
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Cobalt
Cobalt is a chemical element with the symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, produced by reductive smelting, is a hard, lustrous, silver-gray metal. Cobalt-based blue pigments ( cobalt blue) have been used since ancient times for jewelry and paints, and to impart a distinctive blue tint to glass, but the color was for a long time thought to be due to the known metal bismuth. Miners had long used the name ''kobold ore'' (German for ''goblin ore'') for some of the blue-pigment-producing minerals; they were so named because they were poor in known metals, and gave poisonous arsenic-containing fumes when smelted. In 1735, such ores were found to be reducible to a new metal (the first discovered since ancient times), and this was ultimately named for the ''kobold''. Today, some cobalt is produced specifically from one of ...
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Oxygen
Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well as with other compounds. Oxygen is Earth's most abundant element, and after hydrogen and helium, it is the third-most abundant element in the universe. At standard temperature and pressure, two atoms of the element bind to form dioxygen, a colorless and odorless diatomic gas with the formula . Diatomic oxygen gas currently constitutes 20.95% of the Earth's atmosphere, though this has changed considerably over long periods of time. Oxygen makes up almost half of the Earth's crust in the form of oxides.Atkins, P.; Jones, L.; Laverman, L. (2016).''Chemical Principles'', 7th edition. Freeman. Many major classes of organic molecules in living organisms contain oxygen atoms, such as proteins, nucleic acids, carbohydrates, and fats, as ...
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Cobalt(II) Oxide
Cobalt(II) oxide is an inorganic compound that has been described as an olive-green or gray solid. It is used extensively in the ceramics industry as an additive to create blue colored glazes and enamels as well as in the chemical industry for producing cobalt(II) salts. A related material is cobalt(II,III) oxide, a black solid with the formula Co3O4. Structure and properties CoO crystals adopt the periclase (rock salt) structure with a lattice constant of 4.2615 Å. It is antiferromagnetic below 16 °C. Preparation Cobalt(II) oxide is prepared by oxidation of cobalt powder with air or by thermal decomposition of cobalt(II) nitrate or the carbonate. Cobalt(II,III) oxide decomposes to cobalt(II) oxide at 950 °C: :2 Co3O4 → 6 CoO + O2 It may also be prepared by precipitating the hydroxide, followed by thermal dehydration: : CoX2 + 2 KOH → Co(OH)2 + 2 KX : Co(OH)2 → CoO + H2O Reactions As can be expected, cobalt(II) oxide reacts with mineral acids to form the ...
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Cobalt(III) Oxide
Cobalt(III) oxide is the inorganic compound with the formula of Co2O3. Although only two oxides of cobalt are well characterized, CoO and Co3O4, procedures claiming to give Co2O3 have been described. Thus treatment of Co(II) salts such as cobalt(II) sulfate with an aqueous solution of sodium hypochlorite (also known as bleach) gives a black solid: :2CoSO4 + 4NaOH + NaOCl → Co2O3 + 2Na2SO4 + NaCl Some formulations of the catalyst hopcalite contain "Co2O3". Some studies have been unable to synthesize the compound, and report that it is theoretically unstable. It is soluble in cold diluted sulfuric acid and produces Co2 O4sub>3, which is blue in aqueous solution. : Co2O3 + 3H2SO4 → Co2 O4sub>3 + 3H2O Colbalt(III) ion is a strong oxidizer in acidic solution, its standard electrode potential is +1.84V in this situation. See also *Cobalt Oxide Nanoparticles In materials and electric battery research, cobalt oxide nanoparticles usually refers to particles of cobalt( ...
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Cobalt(II,III) Oxide
Cobalt(II,III) oxide is an inorganic compound with the formula Co3O4. It is one of two well characterized cobalt oxides. It is a black antiferromagnetic solid. As a mixed valence compound, its formula is sometimes written as CoIICoIII2O4 and sometimes as CoO•Co2O3. Structure Co3O4 adopts the normal spinel structure, with Co2+ ions in tetrahedral interstices and Co3+ ions in the octahedral interstices of the cubic close-packed lattice of oxide anions. Synthesis Cobalt(II) oxide, CoO, converts to Co3O4 upon heating at around 600–700 °C in air. Above 900 °C, CoO is stable. These reaction are described by the following equilibrium: :2 Co3O4 6 CoO + O2 Applications Cobalt(II,III) oxide is used as a blue coloring agent for pottery enamel and glass, as an alternative to cobalt(II) oxide.Frank Hamer, Janet Hamer (2004)''The Potter's Dictionary of Materials and Techniques'' University of Pennsylvania Press; 437 pp. Cobalt(II,III) oxide is used as an elect ...
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