|
Chlorosulfuric Acid
Chlorosulfuric acid (IUPAC name: sulfurochloridic acid) is the inorganic compound with the formula HSO3Cl. It is also known as chlorosulfonic acid, being the sulfonic acid of chlorine. It is a distillable, colorless liquid which is hygroscopic and a powerful lachrymator. Commercial samples usually are pale brown or straw colored. Salts and esters of chlorosulfuric acid are known as chlorosulfates. Structure and properties Chlorosulfuric acid is a tetrahedral molecule. The formula is more descriptively written SO2(OH)Cl, but HSO3Cl is traditional. It is an intermediate, chemically and conceptually, between sulfuryl chloride (SO2Cl2) and sulfuric acid (H2SO4). The compound is rarely obtained pure. Upon standing with excess sulfur trioxide, it decomposes to pyrosulfuryl chlorides: :2 ClSO3H + SO3 → H2SO4 + S2O5Cl2 Synthesis The industrial synthesis entails the reaction of hydrogen chloride with a solution of sulfur trioxide in sulfuric acid: :HCl + SO3 → ClSO3H It can al ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfuryl Chloride
Sulfuryl chloride is an inorganic compound with the formula SO2Cl2. At room temperature, it is a colorless liquid with a pungent odor. Sulfuryl chloride is not found in nature, as can be inferred from its rapid hydrolysis. Sulfuryl chloride is commonly confused with thionyl chloride, SOCl2. The properties of these two sulfur oxychlorides are quite different: sulfuryl chloride is a source of chlorine whereas thionyl chloride is a source of chloride ions. An alternative IUPAC name is sulfuroyl dichloride. Structure Sulfur is tetrahedral in SO2Cl2 and the oxidation state of the sulfur atom is +6, as in sulfuric acid. Synthesis SO2Cl2 is prepared by the reaction of sulfur dioxide and chlorine in the presence of a catalyst, such as activated carbon. :SO2 + Cl2 → SO2Cl2 The product can be purified by fractional distillation. Legacy routes Sulfuryl chloride was first prepared in 1838 by the French chemist Henri Victor Regnault. Legacy routes include oxidation of thionyl ch ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Detergent
A detergent is a surfactant or a mixture of surfactants with cleansing properties when in dilute solutions. There are a large variety of detergents, a common family being the alkylbenzene sulfonates, which are soap-like compounds that are more soluble in hard water, because the polar sulfonate (of detergents) is less likely than the polar carboxylate (of soap) to bind to calcium and other ions found in hard water. Definitions The word ''detergent'' is derived from the Latin adjective ''detergens'', from the verb ''detergere'', meaning to wipe or polish off. Detergent is a surfactant or a mixture of surfactants with cleansing properties when in dilute solutions. However, conventionally, detergent is used to mean synthetic cleaning compounds as opposed to ''soap'' (a salt of the natural fatty acid), even though soap is also a detergent in the true sense. In domestic contexts, the term ''detergent'' refers to household cleaning products such as ''laundry detergent'' or '' dish ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Smoke Screen
A smoke screen is smoke released to mask the movement or location of military units such as infantry, tanks, aircraft, or ships. Smoke screens are commonly deployed either by a canister (such as a grenade) or generated by a vehicle (such as a tank or a warship). Whereas smoke screens were originally used to hide movement from enemies' line of sight, modern technology means that they are now also available in new forms; they can screen in the infrared as well as visible spectrum of light to prevent detection by infrared sensors or viewers, and they are also available for vehicles in a super-dense form used to block laser beams of enemy target designators or range finders. Technology Smoke grenades These are canister-type grenades used as a ground-to-ground or ground-to-air signalling device. The body consists of a steel sheet metal cylinder with a few emission holes on the top and/or bottom to allow smoke release when the smoke composition inside the grenade is ignited ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ryan Model 147
The Ryan Model 147 Lightning Bug is a jet-powered drone, or unmanned aerial vehicle, produced and developed by Ryan Aeronautical from the earlier Ryan Firebee target drone series. Beginning in 1962, the Model 147 was introduced as a reconnaissance RPV (Remotely Piloted Vehicle, nomenclature of that era) for a United States Air Force project named Fire Fly. Over the next decade — assisted with secret funding from the recently formed National Reconnaissance Office along with support of the Strategic Air Command and Ryan Aeronautical's own resources — the basic Model 147 design would be developed into a diverse series of variants configured for a wide array of mission-specific roles, with multiple new systems, sensors and payloads used, modified and improved upon during the operational deployment of these drones in Southeast Asia. Missions performed by the Model 147 series RPVs included high- and low-altitude photographic and electronic aerial reconnaissance, surveillance, de ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Contrail
Contrails (; short for "condensation trails") or vapor trails are line-shaped clouds produced by aircraft engine exhaust or changes in air pressure, typically at aircraft cruising altitudes several miles above the Earth's surface. Contrails are composed primarily of water, in the form of ice crystals. The combination of water vapor in aircraft engine exhaust and the low ambient temperatures that exist at high altitudes allows the formation of the trails. Impurities in the engine exhaust from the fuel, including sulfur compounds (0.05% by weight in jet fuel) provide some of the particles that can serve as nucleation sites for water droplet growth in the exhaust. If water droplets form, they might freeze to form ice particles that compose a contrail. Their formation can also be triggered by changes in air pressure in wingtip vortices or in the air over the entire wing surface. Contrails, and other clouds directly resulting from human activity, are collectively named homogenitus. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polytetrafluoroethylene
Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene that has numerous applications. It is one of the best-known and widely applied PFAS. The commonly known brand name of PTFE-based composition is Teflon by Chemours, a spin-off from DuPont, which originally discovered the compound in 1938. Polytetrafluoroethylene is a fluorocarbon solid, as it is a high-molecular-weight polymer consisting wholly of carbon and fluorine. PTFE is hydrophobic: neither water nor water-containing substances wet PTFE, as fluorocarbons exhibit only small London dispersion forces due to the low electric polarizability of fluorine. PTFE has one of the lowest coefficients of friction of any solid. Polytetrafluoroethylene is used as a non-stick coating for pans and other cookware. It is non-reactive, partly because of the strength of carbon–fluorine bonds, so it is often used in containers and pipework for reactive and corrosive chemicals. Where used as a lubricant, PTFE ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Free Radical Polymerization
In polymer chemistry, free-radical polymerization (FRP) is a method of polymerization by which a polymer forms by the successive addition of free-radical building blocks (repeat units). Free radicals can be formed by a number of different mechanisms, usually involving separate initiator molecules. Following its generation, the initiating free radical adds (nonradical) monomer units, thereby growing the polymer chain. Free-radical polymerization is a key synthesis route for obtaining a wide variety of different polymers and materials composites. The relatively non-specific nature of free-radical chemical interactions makes this one of the most versatile forms of polymerization available and allows facile reactions of polymeric free-radical chain ends and other chemicals or substrates. In 2001, 40 billion of the 110 billion pounds of polymers produced in the United States were produced by free-radical polymerization. Free-radical polymerization is a type of chain-growth polymeriz ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Peroxydisulfate
The peroxydisulfate ion, , is an oxyanion, the anion of peroxydisulfuric acid. It is commonly referred to as persulfate, but this term also refers to the peroxomonosulfate ion, . It is also called ''peroxodisulfate''. Approximately 500,000 tons of salts containing this anion are produced annually. Important salts include sodium persulfate (Na2S2O8), potassium persulfate (K2S2O8), and ammonium persulfate ((NH4)2S2O8). These salts are colourless, water-soluble solids that are strong oxidants.: Applications Salts of peroxydisulfate are mainly used to initiate the polymerization of various alkenes, including styrene, acrylonitrile, and fluoroalkenes. Polymerization is initiated by the homolysis of the peroxydisulfate: : 3SO–OSO3sup>2− 2 O4sup>•− Moreover, sodium peroxydisulfate can be used for soil and groundwater remediation, water and wastewater treatment, and etching of copper on circuit boards. It has also been used to produce hair lighteners and bleaches, medical ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Peroxydisulfuric Acid
Peroxydisulfuric acid is an inorganic compound with a chemical formula . Also called Marshall's acid after Professor Hugh Marshall, who discovered it in 1891. Structure and bonding This oxoacid features sulfur in its +6 oxidation state and a peroxide group. Sulfur adopts the usual tetrahedral geometry. Synthesis The acid is prepared by the reaction of chlorosulfuric acid with hydrogen peroxide: :2ClSO3H + H2O2 → H2S2O8 + 2 HCl Another method is the electrolysis of moderately concentrated sulfuric acid (60-70%) with platinum electrodes at high current density and voltage: :H2SO4 + H2O → H3O+ + HSO4− (dissociation of sulfuric acid) :2HSO4− → H2S2O8 + 2e− (E0 = +2.4V) (bisulfate oxidation) :2H2SO4 → H2S2O8 + H2 (overall reaction) :3H2O → O3 + 6H+ (ozone produced as a side product) Uses Peroxydisulfuric acid is a precursor to several salts including sodium peroxydisulfate, potassium peroxydisulfate, and ammonium peroxydisulfate. These salts are used to initiat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrogen Peroxide
Hydrogen peroxide is a chemical compound with the formula . In its pure form, it is a very pale blue liquid that is slightly more viscous than water. It is used as an oxidizer, bleaching agent, and antiseptic, usually as a dilute solution (3%–6% by weight) in water for consumer use, and in higher concentrations for industrial use. Concentrated hydrogen peroxide, or " high-test peroxide", decomposes explosively when heated and has been used as a propellant in rocketry. Hydrogen peroxide is a reactive oxygen species and the simplest peroxide, a compound having an oxygen–oxygen single bond. It decomposes slowly when exposed to light, and rapidly in the presence of organic or reactive compounds. It is typically stored with a stabilizer in a weakly acidic solution in a dark bottle to block light. Hydrogen peroxide is found in biological systems including the human body. Enzymes that use or decompose hydrogen peroxide are classified as peroxidases. Properties The boiling poi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ammonia
Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous waste, particularly among aquatic organisms, and it contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to 45% of the world's food and fertilizers. Around 70% of ammonia is used to make fertilisers in various forms and composition, such as urea and Diammonium phosphate. Ammonia in pure form is also applied directly into the soil. Ammonia, either directly or indirectly, is also a building block for the synthesis of many pharmaceutical products and is used in many commercial cleaning products. It is mainly collected by downward displacement of both air and water. Although common in nature—both terrestrially and in the outer planets of the Solar System—and in wide use, ammonia is both caust ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Benzoic Acid
Benzoic acid is a white (or colorless) solid organic compound with the formula , whose structure consists of a benzene ring () with a carboxyl () substituent. It is the simplest aromatic carboxylic acid. The name is derived from gum benzoin, which was for a long time its only source. Benzoic acid occurs naturally in many plants and serves as an intermediate in the biosynthesis of many secondary metabolites. Salts of benzoic acid are used as food preservatives. Benzoic acid is an important precursor for the industrial synthesis of many other organic substances. The salts and esters of benzoic acid are known as benzoates . History Benzoic acid was discovered in the sixteenth century. The dry distillation of gum benzoin was first described by Nostradamus (1556), and then by Alexius Pedemontanus (1560) and Blaise de Vigenère (1596). Justus von Liebig and Friedrich Wöhler determined the composition of benzoic acid. These latter also investigated how hippuric acid is related ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
-3D-balls.png "Click for more on -> Ammonia")