Chlorine-37
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Chlorine-37
Chlorine-37 (), is one of the stable isotopes of chlorine, the other being chlorine-35 (). Its atomic nucleus, nucleus contains 17 protons and 20 neutrons for a total of 37 nucleons. Chlorine-37 accounts for 24.23% of natural chlorine, chlorine-35 accounting for 75.77%, giving chlorine atoms in bulk an apparent atomic weight of . Remarkably, solar neutrinos were discovered by an experiment using a radiochemical method based on chlorine-37 transmutation. Neutrino detection One of the historically important radiochemical methods of solar Neutrino detector, neutrino detection is based on inverse electron capture triggered by the absorption of an electron neutrino. Chlorine-37 transmutes into argon-37 via the reaction : + → + . Argon-37 then de-excites itself via electron capture (half-life = 35 d) into chlorine-37 via the reaction : + → + . These last reactions involve Auger electrons of specific energies. The detection of these electrons confirms that a neutrino ...
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Isotopes Of Chlorine
Chlorine (17Cl) has 25 isotopes with mass numbers ranging from 28Cl to 52Cl and 2 isomers (34mCl and 38mCl). There are two stable isotopes, 35Cl (75.77%) and 37Cl (24.23%), giving chlorine a standard atomic weight of 35.45. The longest-lived radioactive isotope is 36Cl, which has a half-life of 301,000 years. All other isotopes have half-lives under 1 hour, many less than one second. The shortest-lived are 29Cl and 30Cl, with half-lives less than 10 picoseconds and 30 nanoseconds, respectively—the half-life of 28Cl is unknown. List of isotopes , - , 28Cl , style="text-align:right" , 17 , style="text-align:right" , 11 , 28.02954(64)# , , p , 27S , 1+# , , , - , 29Cl , style="text-align:right" , 17 , style="text-align:right" , 12 , 29.01413(20) , <10 ps , p , 28S , (1/2+) , , , - , 30Cl , style="text-align:right" , 17 , style="text-align:right" , 13 , 30.00477(21)# , <30 ns , p , ...
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Carbon Tetrachloride
Carbon tetrachloride, also known by many other names (such as tetrachloromethane, also IUPAC nomenclature of inorganic chemistry, recognised by the IUPAC, carbon tet in the cleaning industry, Halon-104 in firefighting, and Refrigerant-10 in HVACR) is an organic compound with the chemical formula CCl4. It is a colourless liquid with a "sweet" smell that can be detected at low levels. It is practically incombustible at lower temperatures. It was formerly widely used in fire extinguishers, as a precursor to refrigerants and as a cleaning agent, but has since been phased out because of environmental and safety concerns. Exposure to high concentrations of carbon tetrachloride (including vapor) can affect the central nervous system and degenerate the liver and kidneys. Prolonged exposure can be fatal. Properties In the carbon tetrachloride molecule, four chlorine atoms are positioned symmetrically as corners in a tetrahedron, tetrahedral configuration joined to a central carbon atom by ...
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Physical Review
''Physical Review'' is a peer-reviewed scientific journal established in 1893 by Edward Nichols. It publishes original research as well as scientific and literature reviews on all aspects of physics. It is published by the American Physical Society (APS). The journal is in its third series, and is split in several sub-journals each covering a particular field of physics. It has a sister journal, ''Physical Review Letters'', which publishes shorter articles of broader interest. History ''Physical Review'' commenced publication in July 1893, organized by Cornell University professor Edward Nichols and helped by the new president of Cornell, J. Gould Schurman. The journal was managed and edited at Cornell in upstate New York from 1893 to 1913 by Nichols, Ernest Merritt, and Frederick Bedell. The 33 volumes published during this time constitute ''Physical Review Series I''. The American Physical Society (APS), founded in 1899, took over its publication in 1913 and star ...
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Isotopic Tracer
Isotopic labeling (or isotopic labelling) is a technique used to track the passage of an isotope (an atom with a detectable variation in neutron count) through a reaction, metabolic pathway, or Cell (biology), cell. The reactant is 'labeled' by replacing specific atoms by their isotope. The reactant is then allowed to undergo the reaction. The position of the isotopes in the product (chemistry), products is measured to determine the sequence the isotopic atom followed in the reaction or the cell's metabolic pathway. The nuclides used in isotopic labeling may be stable nuclides or radionuclides. In the latter case, the labeling is called radiolabeling. In isotopic labeling, there are multiple ways to detect the presence of labeling isotopes; through their mass, vibrational mode, or radioactive decay. Mass spectrometry detects the difference in an isotope's mass, while infrared spectroscopy detects the difference in the isotope's vibrational modes. Nuclear magnetic resonance detects a ...
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Neutrino Detection
A neutrino detector is a physics apparatus which is designed to study neutrinos. Because neutrinos only weakly interact with other particles of matter, neutrino detectors must be very large to detect a significant number of neutrinos. Neutrino detectors are often built underground, to isolate the detector from cosmic rays and other background radiation. The field of neutrino astronomy is still very much in its infancy – the only confirmed extraterrestrial sources are the Sun and the supernova 1987A in the nearby Large Magellanic Cloud. Another likely source (three standard deviations) is the blazar TXS 0506+056 about 3.7 billion light years away. Neutrino observatories will "give astronomers fresh eyes with which to study the universe". Various detection methods have been used. Super Kamiokande is a large volume of water surrounded by phototubes that watch for the Cherenkov radiation emitted when an incoming neutrino creates an electron or muon in the water. The Sudbur ...
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Beta Decay
In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which a beta particle (fast energetic electron or positron) is emitted from an atomic nucleus, transforming the original nuclide to an isobar of that nuclide. For example, beta decay of a neutron transforms it into a proton by the emission of an electron accompanied by an antineutrino; or, conversely a proton is converted into a neutron by the emission of a positron with a neutrino in so-called ''positron emission''. Neither the beta particle nor its associated (anti-)neutrino exist within the nucleus prior to beta decay, but are created in the decay process. By this process, unstable atoms obtain a more stable ratio of protons to neutrons. The probability of a nuclide decaying due to beta and other forms of decay is determined by its nuclear binding energy. The binding energies of all existing nuclides form what is called the nuclear band or valley of stability. For either electron or positron em ...
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Parts Per Thousand
In science and engineering, the parts-per notation is a set of pseudo-units to describe small values of miscellaneous dimensionless quantities, e.g. mole fraction or mass fraction. Since these fractions are quantity-per-quantity measures, they are pure numbers with no associated units of measurement. Commonly used are parts-per-million (ppm, ), parts-per-billion (ppb, ), parts-per-trillion (ppt, ) and parts-per-quadrillion (ppq, ). This notation is not part of the International System of Units (SI) system and its meaning is ambiguous. Overview Parts-per notation is often used describing dilute solutions in chemistry, for instance, the relative abundance of dissolved minerals or pollutants in water. The quantity "1 ppm" can be used for a mass fraction if a water-borne pollutant is present at one-millionth of a gram per gram of sample solution. When working with aqueous solutions, it is common to assume that the density of water is 1.00 g/mL. Therefore, it is common to equate ...
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Organochlorine Compound
An organochloride, organochlorine compound, chlorocarbon, or chlorinated hydrocarbon is an organic compound containing at least one covalent bond, covalently bonded atom of chlorine. The chloroalkane class (alkanes with one or more hydrogens substituted by chlorine) provides common examples. The wide structural variety and divergent chemical properties of organochlorides lead to a broad range of names, applications, and properties. Organochlorine compounds have wide use in many applications, though some are of profound environmental concern, with 2,3,7,8-Tetrachlorodibenzodioxin, TCDD being one of the most notorious. Physical and chemical properties Chlorination reaction, Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular dam ...
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Standard Reference Material
Certified reference materials (CRMs) are 'controls' or standards used to check the quality and metrological traceability of products, to validate analytical measurement methods, or for the calibration of instruments. A certified reference material is a particular form of measurement standard. Reference materials are particularly important for analytical chemistry and clinical analysis. Since most analytical instrumentation is comparative, it requires a sample of known composition (reference material) for accurate calibration. These reference materials are produced under stringent manufacturing procedures and differ from laboratory reagents in their certification and the traceability of the data provided. Quality management systems involving laboratory accreditation under national and international accreditation/certification standards such as ISO/IEC 17025 require metrological traceability to Certified Reference Materials (where possible) when using reference materials for cali ...
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NIST
The National Institute of Standards and Technology (NIST) is an agency of the United States Department of Commerce whose mission is to promote American innovation and industrial competitiveness. NIST's activities are organized into physical science laboratory programs that include nanoscale science and technology, engineering, information technology, neutron research, material measurement, and physical measurement. From 1901 to 1988, the agency was named the National Bureau of Standards. History Background The Articles of Confederation, ratified by the colonies in 1781, provided: The United States in Congress assembled shall also have the sole and exclusive right and power of regulating the alloy and value of coin struck by their own authority, or by that of the respective states—fixing the standards of weights and measures throughout the United States. Article 1, section 8, of the Constitution of the United States, ratified in 1789, granted these powers to the new Congre ...
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World Scientific
World Scientific Publishing is an academic publisher of scientific, technical, and medical books and journals headquartered in Singapore. The company was founded in 1981. It publishes about 600 books annually, along with 135 journals in various fields. In 1995, World Scientific co-founded the London-based Imperial College Press together with the Imperial College of Science, Technology and Medicine. Company structure The company head office is in Singapore. The Chairman and Editor-in-Chief is Dr Phua Kok Khoo, while the Managing Director is Doreen Liu. The company was co-founded by them in 1981. Imperial College Press In 1995 the company co-founded Imperial College Press, specializing in engineering, medicine and information technology, with Imperial College London. In 2006, World Scientific assumed full ownership of Imperial College Press, under a license granted by the university. Finally, in August 2016, ICP was fully incorporated into World Scientific under the new imprint ...
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Tetrachloroethylene
Tetrachloroethylene, also known under the systematic name tetrachloroethene, or perchloroethylene, and many other names (and abbreviations such as "perc" or "PERC", and "PCE"), is a chlorocarbon with the formula Cl2C=CCl2 . It is a colorless liquid widely used for dry cleaning of fabrics, hence it is sometimes called "dry-cleaning fluid". It also has its uses as an effective automotive brake cleaner. It has a sweet odor detectable by most people at a concentration of 1 part per million (1 ppm). Worldwide production was about in 1985.M. Rossberg et al. "Chlorinated Hydrocarbons" in ''Ullmann's Encyclopedia of Industrial Chemistry'', 2006, Wiley-VCH, Weinheim. Production British physicist and chemist Michael Faraday first synthesized tetrachloroethylene in 1821 by thermal decomposition of hexachloroethane. :C2Cl6 → C2Cl4 + Cl2 Most tetrachloroethylene is produced by high temperature chlorinolysis of light hydrocarbons. The method is related to Faraday's discovery since hexachl ...
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