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Chemical Affinity
In chemical physics and physical chemistry, chemical affinity is the electronic property by which dissimilar chemical species are capable of forming chemical compounds. Chemical affinity can also refer to the tendency of an atom or compound to combine by chemical reaction with atoms or compounds of unlike composition. History Early theories The idea of ''affinity'' is extremely old. Many attempts have been made at identifying its origins. The majority of such attempts, however, except in a general manner, end in futility since "affinities" lie at the basis of all magic, thereby pre-dating science. Physical chemistry, however, was one of the first branches of science to study and formulate a "theory of affinity". The name ''affinitas'' was first used in the sense of chemical relation by German philosopher Albertus Magnus near the year 1250. Later, those as Robert Boyle, John Mayow, Johann Glauber, Isaac Newton, and Georg Stahl put forward ideas on elective affinity in attem ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Physics
Chemical physics is a subdiscipline of chemistry and physics that investigates physicochemical phenomena using techniques from atomic and molecular physics and condensed matter physics; it is the branch of physics that studies chemical processes from the point of view of physics. While at the interface of physics and chemistry, chemical physics is distinct from physical chemistry in that it focuses more on the characteristic elements and theories of physics. Meanwhile, physical chemistry studies the physical nature of chemistry. Nonetheless, the distinction between the two fields is vague, and scientists often practice in both fields during the course of their research. The United States Department of Education defines chemical physics as "A program that focuses on the scientific study of structural phenomena combining the disciplines of physical chemistry and atomic/molecular physics. Includes instruction in heterogeneous structures, alignment and surface phenomena, quantu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Philology
Philology () is the study of language in oral and written historical sources; it is the intersection of textual criticism, literary criticism, history, and linguistics (with especially strong ties to etymology). Philology is also defined as the study of literary texts as well as oral and written records, the establishment of their authenticity and their original form, and the determination of their meaning. A person who pursues this kind of study is known as a philologist. In older usage, especially British, philology is more general, covering comparative and historical linguistics. Classical philology studies classical languages. Classical philology principally originated from the Library of Pergamum and the Library of Alexandria around the fourth century BC, continued by Greeks and Romans throughout the Roman/Byzantine Empire. It was eventually resumed by European scholars of the Renaissance, where it was soon joined by philologies of other European ( Germanic, Celti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Étienne François Geoffroy
Étienne François Geoffroy (13 February 16726 January 1731) was a French physician and chemist, best known for his 1718 affinity tables. He first contemplated a career as an apothecary, but then decided to practice medicine. He is sometimes known as ''Geoffroy the Elder''. Biography Geoffroy was born in Paris. After studying at Montpellier he accompanied Marshal Tallard on his embassy to London in 1698 and thence travelled to the Netherlands and Italy. Returning to Paris he became professor of chemistry at the Jardin du Roi and of pharmacy and medicine at the Collège Royal, and dean of the faculty of medicine. He died in Paris on 6 January 1731. His brother Claude Joseph, known as Geoffroy the younger, was also a chemist. Works His name is best known in connection with his tables of "affinities" (''tables des rapports''), which he presented to the French Academy of Sciences in 1718 and 1720. These were lists, prepared by collating observations on the actions of s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Displacement Reaction
A chemical reaction is a process that leads to the chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the positions of electrons in the forming and breaking of chemical bonds between atoms, with no change to the nuclei (no change to the elements present), and can often be described by a chemical equation. Nuclear chemistry is a sub-discipline of chemistry that involves the chemical reactions of unstable and radioactive elements where both electronic and nuclear changes can occur. The substance (or substances) initially involved in a chemical reaction are called reactants or reagents. Chemical reactions are usually characterized by a chemical change, and they yield one or more products, which usually have properties different from the reactants. Reactions often consist of a sequence of individual sub-steps, the so-called elementary reactions, and the information on the precise course of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Elective Affinities
''Elective Affinities'' (German: ''Die Wahlverwandtschaften''), also translated under the title ''Kindred by Choice'', is the third novel by Johann Wolfgang von Goethe, published in 1809. Situated around the city of Weimar, the book relates the story of Eduard and Charlotte, an aristocratic couple enjoying an idyllic but somewhat mundane life on a secluded estate; although it is the second marriage for both, their relationship deteriorates after they invite Eduard's friend Captain Otto and Charlotte's orphaned niece, Ottilie, to live with them in their mansion. The invitation to Ottilie and the Captain is described as an "experiment", as it indeed is. The house and its surrounding gardens are described as "a chemical retort in which the human elements are brought together for the reader to observe the resulting reaction." As if in a chemical reaction, each of the spouses experiences a strong new attraction, which is reciprocated: Charlotte, who represents reason, to the sensible a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Goethe
Johann Wolfgang von Goethe (28 August 1749 – 22 March 1832) was a German poet, playwright, novelist, scientist, statesman, theatre director, and critic. His works include plays, poetry, literature, and aesthetic criticism, as well as treatises on botany, anatomy, and colour. He is widely regarded as the greatest and most influential writer in the German language, his work having a profound and wide-ranging influence on Western literary, political, and philosophical thought from the late 18th century to the present day.. Goethe took up residence in Weimar in November 1775 following the success of his first novel, '' The Sorrows of Young Werther'' (1774). He was ennobled by the Duke of Saxe-Weimar, Karl August, in 1782. Goethe was an early participant in the '' Sturm und Drang'' literary movement. During his first ten years in Weimar, Goethe became a member of the Duke's privy council (1776–1785), sat on the war and highway commissions, oversaw the reopening of si ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Théophile De Donder
Théophile Ernest de Donder (; 19 August 1872 – 11 May 1957) was a Belgian mathematician and physicist famous for his work (published in 1923) in developing correlations between the Newtonian concept of chemical affinity and the Gibbsian concept of free energy. Education He received his doctorate in physics and mathematics from the Université Libre de Bruxelles in 1899, for a thesis entitled ''Sur la Théorie des Invariants Intégraux'' (''On the Theory of Integral Invariants''). Career He was professor between 1911 and 1942, at the Université Libre de Bruxelles. Initially he continued the work of Henri Poincaré and Élie Cartan. From 1914 on, he was influenced by the work of Albert Einstein and was an enthusiastic proponent of the theory of relativity. He gained significant reputation in 1923, when he developed his definition of chemical affinity. He pointed out a connection between the chemical affinity and the Gibbs free energy. He is considered the father of thermodyn ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamic Free Energy
The thermodynamic free energy is a concept useful in the thermodynamics of chemical or thermal processes in engineering and science. The change in the free energy is the maximum amount of work that a thermodynamic system can perform in a process at constant temperature, and its sign indicates whether the process is thermodynamically favorable or forbidden. Since free energy usually contains potential energy, it is not absolute but depends on the choice of a zero point. Therefore, only relative free energy values, or changes in free energy, are physically meaningful. The free energy is a thermodynamic state function, like the internal energy, enthalpy, and entropy. The free energy is the portion of any first-law energy that is available to perform thermodynamic work at constant temperature, ''i.e.'', work mediated by thermal energy. Free energy is subject to irreversible loss in the course of such work. Since first-law energy is always conserved, it is evident that free energy ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Merle Randall
Merle Randall (January 29, 1888 – March 17, 1950) was an American physical chemist famous for his work with Gilbert N. Lewis, over a period of 25 years, in measuring reaction heat of chemical compounds and determining their corresponding free energy. Together, their 1923 textbook ''"Thermodynamics and the Free Energy of Chemical Substances"'' became a classic work in the field of chemical thermodynamics. In 1932, Merle Randall authored two scientific papers with Mikkel Frandsen: ''“The Standard Electrode Potential of Iron and the Activity Coefficient of Ferrous Chloride,”'' and ''“Determination of the Free Energy of Ferrous Hydroxide from Measurements of Electromotive Force.”'' Education Randall completed his Ph.D. at the Massachusetts Institute of Technology in 1912 with a dissertation on ''“Studies in Free Energy”''.Randall, Merle (1912). ''Studies in Free Energy''. Ph.D. Thesis/dissertation — Massachusetts Institute of Technology. Related Based on work by J ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gilbert N
Gilbert may refer to: People and fictional characters *Gilbert (given name), including a list of people and fictional characters *Gilbert (surname), including a list of people Places Australia * Gilbert River (Queensland) * Gilbert River (South Australia) Kiribati * Gilbert Islands, a chain of atolls and islands in the Pacific Ocean United States * Gilbert, Arizona, a town * Gilbert, Arkansas, a town * Gilbert, Florida, the airport of Winterhaven * Gilbert, Iowa, a city * Gilbert, Louisiana, a village * Gilbert, Michigan, and unincorporated community * Gilbert, Minnesota, a city * Gilbert, Nevada, ghost town * Gilbert, Ohio, an unincorporated community * Gilbert, Pennsylvania, an unincorporated community * Gilbert, South Carolina, a town * Gilbert, West Virginia, a town * Gilbert, Wisconsin, an unincorporated community * Mount Gilbert (other), various mountains * Gilbert River (Oregon) Outer space * Gilbert (lunar crater) * Gilbert (Martian crater) Arts ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Traité Élémentaire De Chimie
''Traité élémentaire de chimie'' (''Elementary Treatise on Chemistry'') is a textbook written by Antoine Lavoisier published in 1789 and translated into English by Robert Kerr in 1790 under the title ''Elements of Chemistry in a New Systematic Order containing All the Modern Discoveries''. It is considered to be the first modern chemical textbook. The book defines an element as a single substance that can't be broken down by chemical analysis and from which all chemical compounds are formed, publishing his discovery that fermentation produces carbon dioxide (carbonic gas) and spirit of wine, saying that it is "more appropriately called by the Arabic word alcohol since it is formed from cider or fermented sugar as well as wine", and publishing the first chemical equation "grape must = carbonic acid + alcohol", calling this reaction "one of the most extraordinary in chemistry", noting "In these experiments, we have to assume that there is a true balance or equation between the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Antoine Lavoisier
Antoine-Laurent de Lavoisier ( , ; ; 26 August 17438 May 1794), CNRS ( Centre National de la Recherche Scientifique) also Antoine Lavoisier after the , was a and who was central to the 18th-century [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
