Carbon Sulfide
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Carbon Sulfide
Carbon sulfide may refer to: * Carbon disulfide * Carbon monosulfide * Carbon subsulfide Carbon subsulfide is an organic, sulfur-containing chemical compound with the formula and structure . This deep red liquid is immiscible with water but soluble in organic solvents. It readily polymerizes at room temperature to form a hard ... * Sulflower {{Short pages monitor ...
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Carbon Disulfide
Carbon disulfide (also spelled as carbon disulphide) is a neurotoxic, colorless, volatile liquid with the formula and structure . The compound is used frequently as a building block in organic chemistry as well as an industrial and chemical non-polar solvent. It has an "ether-like" odor, but commercial samples are typically contaminated with foul-smelling impurities.. It is of comparable toxicity to carbon monoxide. History In 1796, the German chemist Wilhelm August Lampadius (1772–1842) first prepared carbon disulfide by heating pyrite with moist charcoal. He called it "liquid sulfur" (''flüssig Schwefel''). The composition of carbon disulfide was finally determined in 1813 by the team of the Swedish chemist Jöns Jacob Berzelius (1779–1848) and the Swiss-British chemist Alexander Marcet (1770–1822). Their analysis was consistent with an empirical formula of CS2. Occurrence, manufacture, properties Small amounts of carbon disulfide are released by volcanic eruptio ...
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Carbon Monosulfide
Carbon monosulfide is a chemical compound with the formula CS. This diatomic molecule is the sulfur analogue of carbon monoxide, and is unstable as a solid or a liquid, but it has been observed as a gas both in the laboratory and in the interstellar medium. The molecule resembles carbon monoxide with a triple bond between carbon and sulfur. The molecule is not intrinsically unstable, but it tends to polymerize. This tendency reflects the greater stability of C–S single bonds. Polymers with the formula (CS)''n'' have been reported. Also, CS has been observed as a ligand in some transition metal complex A coordination complex consists of a central atom or ion, which is usually metallic and is called the ''coordination centre'', and a surrounding array of bound molecules or ions, that are in turn known as ''ligands'' or complexing agents. Many ...es. References {{Molecules detected in outer space Inorganic carbon compounds Sulfides ...
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Carbon Subsulfide
Carbon subsulfide is an organic, sulfur-containing chemical compound with the formula and structure . This deep red liquid is immiscible with water but soluble in organic solvents. It readily polymerizes at room temperature to form a hard black solid. Synthesis and structure C3S2 was discovered by Béla Lengyel, who assigned it an unsymmetrical structure. Later, infrared and Raman spectroscopy showed that the structure is symmetrical with a D∞h point group symmetry, i.e. S=C=C=C=S. This compound is analogous to carbon suboxide whose structure is O=C=C=C=O. Lengyel first synthesized this compound by passing carbon disulfide (CS2) vapor through an electric arc with carbon electrodes. This treatment produced a black solution that after filtration and evaporation gave a cherry-red liquid. He determined the molecular mass by cryoscopy. Later preparations of C3S2 include thermolysis of a stream of CS2 in a quartz tube heated to 900 to 1100 °C as well as flash vacuum pyr ...
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