Butroxydim
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Butroxydim
Butroxydim is a chemical used as a herbicide. It is a group A herbicide used to kill grass weeds in a range of broadacre crops. Structurally related herbicides against grasses are alloxydim, sethoxydim, clethodim Clethodim is an organic compound. A member of the cyclohexanedione family of herbicides, it is used to control grasses, especially Lolium rigidum ''Lolium rigidum'' is a species of annual grass. Common names by which it is known include annual ..., and cycloxydim. References Hydroxylamines Ketones Imines Herbicides {{agriculture-stub ...
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Sethoxydim
Sethoxydim is a postemergent herbicide for control of grass weeds in a wide variety of horticultural crops. p. 5. Sethoxydim is sold under brand names including Poast, Torpedo, Ultima, Vantage, Conclude, and Rezult. It is manufactured by BASF, TopPro, and Monterey Lawn and Garden. Mode of Action Sethoxydim is a substituted 1,3-cyclohexanedione 1,3-Cyclohexanedione is an organic compound with the formula (CH2)4(CO)2. It is one of three isomeric cyclohexanediones. It is a colorless compound that occurs naturally. It is the substrate for cyclohexanedione hydrolase. The compound exist ... DIM herbicide, a type of Acetyl-CoA carboxylase inhibitor (ACCase herbicide), WSSA/ HRAC Group 1 (formerly in HRAC A). Resistance Resistant crops Maize/corn resistant to ACCase inhibitors has been produced by selection under sethoxydim application. References {{Herbicides DIM herbicides Post-emergent herbicides ...
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Clethodim
Clethodim is an organic compound. A member of the cyclohexanedione family of herbicides, it is used to control grasses, especially Lolium rigidum ''Lolium rigidum'' is a species of annual grass. Common names by which it is known include annual ryegrass, a name also given to Italian ryegrass (''Lolium multiflorum''), rigid ryegrass, stiff darnel, Swiss ryegrass and Wimmera ryegrass. It is .... Although impure samples appear yellowish, the compound is colorlesss. References Hydroxylamines Ketones Imines Herbicides {{agriculture-stub ...
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Hydroxylamines
Hydroxylamine is an inorganic compound with the formula . The material is a white crystalline, hygroscopic compound.Greenwood and Earnshaw. ''Chemistry of the Elements.'' 2nd Edition. Reed Educational and Professional Publishing Ltd. pp. 431–432. 1997. Hydroxylamine is almost always provided and used as an aqueous solution. It is consumed almost exclusively to produce Nylon-6. It is also an intermediate in biological nitrification. The oxidation of to hydroxylamine is a step in biological nitrification. History Hydroxylamine was first prepared as hydroxylammonium chloride in 1865 by the German chemist Wilhelm Clemens Lossen (1838-1906); he reacted tin and hydrochloric acid in the presence of ethyl nitrate. It was first prepared in pure form in 1891 by the Dutch chemist Lobry de Bruyn and by the French chemist Léon Maurice Crismer (1858-1944). The coordination complex , known as Crismer's salt, releases hydroxylamine upon heating. Production Hydroxylamine or its salts can be ...
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Ketones
In organic chemistry, a ketone is a functional group with the structure R–C(=O)–R', where R and R' can be a variety of carbon-containing substituents. Ketones contain a carbonyl group –C(=O)– (which contains a carbon-oxygen double bond C=O). The simplest ketone is acetone (where R and R' is methyl), with the formula . Many ketones are of great importance in biology and in industry. Examples include many sugars (ketoses), many steroids (e.g., testosterone), and the solvent acetone. Nomenclature and etymology The word ''ketone'' is derived from ''Aketon'', an old German word for ''acetone''. According to the rules of IUPAC nomenclature, ketone names are derived by changing the suffix ''-ane'' of the parent alkane to ''-anone''. Typically, the position of the carbonyl group is denoted by a number, but traditional nonsystematic names are still generally used for the most important ketones, for example acetone and benzophenone. These nonsystematic names are considered ret ...
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Imines
In organic chemistry, an imine ( or ) is a functional group or organic compound containing a carbon–nitrogen double bond (). The nitrogen atom can be attached to a hydrogen or an organic group (R). The carbon atom has two additional single bonds. Imines are common in synthetic and naturally occurring compounds and they participate in many reactions. Structure For ketimines and aldimines, respectively, the five core atoms (C2C=NX and C(H)C=NX, X = H or C) are coplanar. Planarity results from the sp2-hybridization of the mutually double-bonded carbon and the nitrogen atoms. The C=N distance is 1.29-1.31 Å for nonconjugated imines and 1.35 Å for conjugated imines. By contrast, C-N distances in amines and nitriles are 1.47 and 1.16 Å, respectively. Rotation about the C=N bond is slow. Using NMR spectroscopy, both E- and Z-isomers of aldimines have been detected. Owing to steric effects, the E isomer is favored. Nomenclature and classification The term "imine" was coined ...
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